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1. 发明授权

US06573316B1 Stabilized water-soluble polymer powders on the basis of polyoxy alkylene glycol carboxylates and method for producing same 有权
标题翻译：基于聚氧化亚烷基二醇羧酸酯的稳定的水溶性聚合物粉末及其制备方法
公开(公告)号：US06573316B1
公开(公告)日：2003-06-03
申请号：US09720922
申请日：2000-12-28
申请人： Gerhard Albrecht , Josef Weichmann , Konrad Wutz , Manfred Bichler , Alfred Kern
发明人： Gerhard Albrecht , Josef Weichmann , Konrad Wutz , Manfred Bichler , Alfred Kern
IPC分类号： C08K534
CPC分类号： C08G65/3322 , C08J3/21 , C08J2371/02 , C08J2387/00 , C08K5/005 , C08L71/02
摘要： Stabilized, water-soluble polymer powders based on polyoxyalkylene glycol carboxylates are described, wherein the powders comprise from 0.01 to 10% by weight of a stabilizer selected from the group consisting of phenols, amines, phosphites, thioethers, and also thioacids, and where the stabilizer was added in liquid or dissolved form to the aqueous polymer solution prior to its conversion into the powder form. The polymer powders thus protected against autoignition and oxidative degradation have unexpectedly high thermooxidative stability, even on exposure to high temperatures and oxidizing action (air, oxygen).
摘要翻译：描述了基于聚氧亚烷基二醇羧酸酯的稳定的水溶性聚合物粉末，其中粉末包含0.01至10重量％的选自酚，胺，亚磷酸酯，硫醚和硫代酸的稳定剂，并且其中稳定剂在其转化成粉末形式之前以液体或溶解形式加入到聚合物水溶液中。因此，即使暴露于高温和氧化作用（空气，氧气），因此防止自燃和氧化降解的聚合物粉末具有出乎意料的高的热氧化稳定性。

2. 发明授权

US6150437A Flow improving agents for binder suspensions containing cement 失效
标题翻译：含水泥粘合剂悬浮液的流动改进剂
公开(公告)号：US6150437A
公开(公告)日：2000-11-21
申请号：US478331
申请日：1995-06-07
申请人： Konrad Wutz , Alfred Kern , Josef Weichmann
发明人： Konrad Wutz , Alfred Kern , Josef Weichmann
IPC分类号： C04B24/16 , C04B24/26 , C04B24/32 , C04B28/02 , C08F8/00 , C08L89/00 , C04B24/30 , C08L51/08
CPC分类号： C04B24/161 , C04B24/32 , C04B28/02 , C08F8/00 , C08L89/005 , C04B2111/62
摘要： Flow improving agents for binder suspensions containing cement are described, which consist of:a) Graft polymers which have been prepared by radical grafting of a polyalkylene oxide of the general formula (I) with an ethylenically unsaturated mono- or dicarboxylic acid or the anhydride thereof, and then by derivatizing with a primary or secondary amine and/or alcohol, and also ofb) Casein.These flow improving agents have the advantage that the ability to flow is considerably improved in comparison, for example, with casein alone, and the improved ability to flow is preserved over a longer period of time.
摘要翻译：描述了含有水泥的粘合剂悬浮液的流动改进剂，其由以下组成：a）通过使通式（I）的聚环氧烷通过烯键式不饱和单或二羧酸或其酸酐进行自由基接枝而制备的接枝聚合物然后通过用伯胺或仲胺和/或醇衍生化，以及b）酪蛋白。这些流动改进剂的优点在于，例如，仅使用酪蛋白，流动的能力在很长一段时间内被保持，从而显着改善了流动能力。

3. 发明授权

US5739212A Water-soluble graft polymers 失效
标题翻译：水溶性接枝聚合物
公开(公告)号：US5739212A
公开(公告)日：1998-04-14
申请号：US545546
申请日：1995-10-19
申请人： Konrad Wutz , Josef Weichmann , Alfred Kern , Hans-Gunter Rosenbauer
发明人： Konrad Wutz , Josef Weichmann , Alfred Kern , Hans-Gunter Rosenbauer
IPC分类号： B01F17/00 , C04B24/16 , C04B24/26 , C04B24/32 , C08F8/00 , C08F283/06 , C09K8/24 , C08G63/91
CPC分类号： C04B24/267 , B01F17/0028 , C04B24/166 , C08F283/06 , C08F8/00 , C09K8/24 , C04B2103/408
摘要： Water-soluble graft polymers are described which have been produced by a) radical grafting of a polyalkylene oxide of the general formula I ##STR1## in which R.sup.1 =--H, --C.sub.n H.sub.2n+1, --C.sub.6 H.sub.4 --C.sub.n H.sub.2n+1, ##STR2## --(CH--R.sup.2).sub.m NHR.sup.2, --(CH--R.sup.2).sub.m OH, --(CH--R.sup.2).sub.m --COOH, --CO--R.sup.5 R.sup.2 =--H, --CH.sub.3, --C.sub.2 H.sub.5 R.sup.3 =--H, --C.sub.n H.sub.2n+1, --C.sub.m H.sub.2m --SO.sub.3 Na, --(CH--R.sup.2).sub.m NHR.sup.2, --(CH--R.sup.2).sub.m OH, --(CH--R.sup.2).sub.m --COOH, --CO--R.sup.5 R.sup.4 =--H, --(CH--R.sup.2).sub.m --COOH, --CO--R.sup.5 R.sup.5 =--C.sub.m H.sub.2m+1, --C.sub.6 H.sub.5, --(CH--R.sup.2).sub.m --COOH, --C.sub.6 H.sub.4 --COOH n denotes 1-18, m denotes 1-5, x denotes 2-200, y denotes 0 or 1 with an ethylenically unsaturated mono or dicarboxylic acid or their anhydride and subsequently b) derivatising with a primary or secondary amine and/or alcohol. These graft polymers are suitable as dispersants for inorganic binding agents containing water such as e.g. cement, gypsum, anhydrite.
摘要翻译：描述了通过以下方法制备的水溶性接枝聚合物：a）通式I的聚环氧烷的自由基接枝，其中R1 = -H，-CnH2n + 1，-C6H4-CnH2n + 1，＆lt; IMAGE＆gt; - （CH-R2）mNHR2， - （CH-R2）mOH， - （CH-R2）m -COOH，-CO-R5R2 = -H，-CH3，-C2H5 R3 = -H，-CnH2n + （CH-R2）mOH， - （CH-R2）mOH， - （CH-R2）m-COOH，-CO-R5 R4 = -H， - （CH-R2）m -COOH， -CO-R5 R5 = -CmH2m + 1，-C6H5， - （CH-R2）m-COOH，-C6H4-COOH n表示1-18，m表示1-5，x表示2-200，y表示0或 1与烯键式不饱和单或二羧酸或其酸酐反应，随后b）用伯或仲胺和/或醇衍生。这些接枝聚合物适合作为含水的无机结合剂的分散剂，例如水。水泥，石膏，无水石膏。

4. 发明申请

US20100210761A1 LIQUID ADMIXTURE COMPOSITION 有权
标题翻译：液体混合物组合物
公开(公告)号：US20100210761A1
公开(公告)日：2010-08-19
申请号：US12663018
申请日：2008-08-12
申请人： Herbert Hommer , Frank Dierschke , Anja Trieflinger , Konrad Wutz , Manfred Bichler
发明人： Herbert Hommer , Frank Dierschke , Anja Trieflinger , Konrad Wutz , Manfred Bichler
IPC分类号： C04B24/24 , C08K3/00 , C08K5/09 , C08K5/10 , C08K5/55 , C08K5/053
CPC分类号： C04B40/0039 , C04B28/14 , C04B2103/40 , C04B2103/408 , C04B2103/50 , C04B24/085 , C04B24/267 , C04B24/32 , C04B24/003 , C04B24/165 , C04B24/42 , C04B24/16 , C04B24/2647 , C04B24/38
摘要： An admixture comprises an aqueous composition of a) a copolymeric dispersing component, b) an antifoaming agent component, c) a surfactant component, and d) water. The components may be a blend or physically or chemically attached and result in a stable liquid system that can be used as a dispersing agent for a calcium sulfate compound containing construction chemicals composition.
摘要翻译：混合物包含a）共聚分散组分的水性组合物，b）消泡剂组分，c）表面活性剂组分，和d）水。组分可以是混合物或物理或化学连接的，并且产生稳定的液体体系，其可以用作含有建筑化学成分的硫酸钙化合物的分散剂。

5. 发明申请

US20060281885A1 Polyether-containing copolymer 审中-公开
标题翻译：含聚醚共聚物
公开(公告)号：US20060281885A1
公开(公告)日：2006-12-14
申请号：US11152678
申请日：2005-06-14
申请人： Manfred Bichler , Herbert Hommer , Konrad Wutz
发明人： Manfred Bichler , Herbert Hommer , Konrad Wutz
IPC分类号： C08F20/06
CPC分类号： C08F216/1416 , C08F220/06
摘要： This invention relates to copolymers consisting of two monomer components whereby component a) is an olefinic unsaturated monocarboxylic acid comonomer or an ester or a salt thereof of an olefinic unsaturated sulfuric acid comonomer or a salt thereof, and component b) is an ether comonomer of the general formula R1—O—R2. The copolymer shall comprise the said components a) and b) in amounts of from 30 to 90 mol-% and from 70 to 10 mol-%, respectively, whereby the said comonomer component a) is selected from the group consisting of acrylic acid, methacrylic acid, crotonic acid, isocrotonic acid, allylsulfonic acid, vinylsulfonic acid and a salt thereof or an alkyl or hydroxyalkyl ester. The invention also claims a composition comprising a hydraulic binder such as cement, gypsum, lime and anhydrite and the said copolymer. According to the invention the copolymer can be used as superplasticizer or dispersant for non-hardened (wet) and a hydraulic binder containing compositions.
摘要翻译：本发明涉及由两种单体组分组成的共聚物，其中组分a）是烯属不饱和单羧酸共聚单体或其烯属不饱和硫酸共聚单体或其盐的酯或其盐，组分b）是通式R 1 -OR 2 2。共聚物应分别含有30至90mol％和70至10mol％的所述组分a）和b），由此所述共聚单体组分a）选自丙烯酸，甲基丙烯酸，巴豆酸，异巴豆酸，烯丙基磺酸，乙烯基磺酸及其盐或烷基或羟烷基酯。本发明还要求一种包含水泥粘合剂如水泥，石膏，石灰和无水石膏的组合物和所述共聚物。根据本发明，共聚物可以用作非硬化（湿）和含水硬性粘合剂的组合物的超增塑剂或分散剂。

6. 发明授权

US08344084B2 Liquid admixture composition 有权
公开(公告)号：US08344084B2
公开(公告)日：2013-01-01
申请号：US12887924
申请日：2010-09-22
申请人： Manfred Bichler , Herbert Hommer , Frank Dierschke , Anja Trieflinger , Konrad Wutz
发明人： Manfred Bichler , Herbert Hommer , Frank Dierschke , Anja Trieflinger , Konrad Wutz
IPC分类号： C08F28/02 , C08F22/10 , C08K5/09 , C08K5/10
CPC分类号： C04B28/14 , C04B28/16 , C04B40/0039 , C04B2103/40 , C04B2103/408 , C04B2103/50 , C04B24/16 , C04B24/2647 , C04B24/38 , C04B24/085 , C04B24/267 , C04B24/32 , C04B24/003 , C04B24/165 , C04B24/42 , C04B7/02 , C04B14/06 , C04B22/142 , C04B24/383
摘要： An admixture comprises an aqueous composition of a) a copolymeric dispersing component, b) an antifoaming agent component, c) a surfactant component, and d) water. The components may be a blend or physically or chemically attached and result in a stable liquid system that can be used as a dispersing agent for a calcium sulfate compound containing construction chemicals composition.

7. 发明申请

US20070255032A1 Polyether-containing copolymer 有权
标题翻译：含聚醚共聚物
公开(公告)号：US20070255032A1
公开(公告)日：2007-11-01
申请号：US11827722
申请日：2007-07-13
申请人： Manfred Bichler , Herbert Hommer , Konrad Wutz
发明人： Manfred Bichler , Herbert Hommer , Konrad Wutz
IPC分类号： C08F28/02 , C08F22/10
CPC分类号： C08F220/26 , C04B24/2647 , C04B2103/308 , C04B2103/32 , C08F216/1416 , C08F220/06
摘要： Copolymers include two monomer components, a) an olefinic unsaturated monocarboxylic acid comonomer or an ester or a salt thereof of an olefinic unsaturated sulfuric acid comonomer or a salt thereof, and b) an ether comonomer of the general formula (I) Components a) and b) are present in amounts of from 30 to 90 mol-% and from 70 to 10 mol-%, respectively, and comonomer component a) is selected from the group consisting of acrylic acid, methacrylic acid, crotonic acid, isocrotonic acid, allylsulfonic acid, vinylsulfonic acid and a salt thereof or an alkyl or hydroxyalkyl ester. Compositions including a hydraulic binder such as cement, gypsum, lime and anhydrite and the copolymer are also disclosed. The copolymer can be used as superplasticizer or dispersant for non-hardened (wet) and a hydraulic binder containing compositions.
摘要翻译：共聚物包括两种单体组分：a）烯属不饱和单羧酸共聚单体或其烯属不饱和硫酸共聚单体或其盐的酯或其盐，和b）通式（I）的醚共聚单体组分a）和 b）分别以30至90mol％和70至10mol％的量存在，共聚单体组分a）选自丙烯酸，甲基丙烯酸，巴豆酸，异巴豆酸，烯丙基磺酸酸，乙烯基磺酸及其盐或烷基或羟烷基酯。还公开了包括水泥粘合剂如水泥，石膏，石灰和无水石膏的组合物和共聚物。该共聚物可用作非硬化（湿）和含水硬性粘合剂的组合物的超增塑剂或分散剂。

8. 发明申请

US20110015327A1 LIQUID ADMIXTURE COMPOSITION 有权
标题翻译：液体混合物组合物
公开(公告)号：US20110015327A1
公开(公告)日：2011-01-20
申请号：US12887924
申请日：2010-09-22
申请人： Manfred BICHLER , Herbert Hommer , Frank Dierschke , Anja Trieflinger , Konrad Wutz
发明人： Manfred BICHLER , Herbert Hommer , Frank Dierschke , Anja Trieflinger , Konrad Wutz
IPC分类号： C08K3/30
CPC分类号： C04B28/14 , C04B28/16 , C04B40/0039 , C04B2103/40 , C04B2103/408 , C04B2103/50 , C04B24/16 , C04B24/2647 , C04B24/38 , C04B24/085 , C04B24/267 , C04B24/32 , C04B24/003 , C04B24/165 , C04B24/42 , C04B7/02 , C04B14/06 , C04B22/142 , C04B24/383
摘要： An admixture comprises an aqueous composition of a) a copolymeric dispersing component, b) an antifoaming agent component, c) a surfactant component, and d) water. The components may be a blend or physically or chemically attached and result in a stable liquid system that can be used as a dispersing agent for a calcium sulfate compound containing construction chemicals composition.
摘要翻译：混合物包含a）共聚分散组分的水性组合物，b）消泡剂组分，c）表面活性剂组分，和d）水。组分可以是混合物或物理或化学连接的，并且产生稳定的液体体系，其可以用作含有建筑化学成分的硫酸钙化合物的分散剂。

9. 发明授权

US07855260B2 Polyether-containing copolymer 有权
标题翻译：含聚醚共聚物
公开(公告)号：US07855260B2
公开(公告)日：2010-12-21
申请号：US11827722
申请日：2007-07-13
申请人： Manfred Bichler , Herbert Hommer , Konrad Wutz
发明人： Manfred Bichler , Herbert Hommer , Konrad Wutz
IPC分类号： C08F28/02 , C08F22/10
CPC分类号： C08F220/26 , C04B24/2647 , C04B2103/308 , C04B2103/32 , C08F216/1416 , C08F220/06
摘要： Copolymers include two monomer components, a) an olefinic unsaturated monocarboxylic acid comonomer or an ester or a salt thereof of an olefinic unsaturated sulfuric acid comonomer or a salt thereof, and b) an ether comonomer of the general formula (I) Components a) and b) are present in amounts of from 30 to 90 mol-% and from 70 to 10 mol-%, respectively, and comonomer component a) is selected from the group consisting of acrylic acid, methacrylic acid, crotonic acid, isocrotonic acid, allylsulfonic acid, vinylsulfonic acid and a salt thereof or an alkyl or hydroxyalkyl ester. Compositions including a hydraulic binder such as cement, gypsum, lime and anhydrite and the copolymer are also disclosed. The copolymer can be used as superplasticizer or dispersant for non-hardened (wet) and a hydraulic binder containing compositions.
摘要翻译：共聚物包括两种单体组分：a）烯属不饱和单羧酸共聚单体或其烯属不饱和硫酸共聚单体或其盐的酯或其盐，和b）通式（I）的醚共聚单体组分a）和 b）分别以30至90mol％和70至10mol％的量存在，共聚单体组分a）选自丙烯酸，甲基丙烯酸，巴豆酸，异巴豆酸，烯丙基磺酸酸，乙烯基磺酸及其盐或烷基或羟烷基酯。还公开了包括水泥粘合剂如水泥，石膏，石灰和无水石膏的组合物和共聚物。该共聚物可用作非硬化（湿）和含水硬性粘合剂的组合物的超增塑剂或分散剂。

10. 发明授权

US08349979B2 Liquid admixture composition 有权
标题翻译：液体混合物组成
公开(公告)号：US08349979B2
公开(公告)日：2013-01-08
申请号：US12663018
申请日：2008-08-12
申请人： Herbert Hommer , Frank Dierschke , Anja Trieflinger , Konrad Wutz , Manfred Bichler
发明人： Herbert Hommer , Frank Dierschke , Anja Trieflinger , Konrad Wutz , Manfred Bichler
IPC分类号： C08F28/02 , C08F22/10 , C08K5/09 , C08K5/10
CPC分类号： C04B40/0039 , C04B28/14 , C04B2103/40 , C04B2103/408 , C04B2103/50 , C04B24/085 , C04B24/267 , C04B24/32 , C04B24/003 , C04B24/165 , C04B24/42 , C04B24/16 , C04B24/2647 , C04B24/38
摘要： An admixture comprises an aqueous composition of a) a copolymeric dispersing component, b) an antifoaming agent component, c) a surfactant component, and d) water. The components may be a blend or physically or chemically attached and result in a stable liquid system that can be used as a dispersing agent for a calcium sulfate compound containing construction chemicals composition.
摘要翻译：混合物包含a）共聚分散组分的水性组合物，b）消泡剂组分，c）表面活性剂组分，和d）水。组分可以是混合物或物理或化学连接的，并且产生稳定的液体体系，其可以用作含有建筑化学成分的硫酸钙化合物的分散剂。

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