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1. 发明授权

US4318883A Process for combating micro-organisms, and novel phthalocyanine compounds 失效
标题翻译：抗微生物和新型酞菁化合物的方法
公开(公告)号：US4318883A
公开(公告)日：1982-03-09
申请号：US121955
申请日：1980-02-15
申请人： Rudolf Polony , Gerhard Reinert , Gerd Holzle , Andre Pugin , Rodolphe Vonderwahl
发明人： Rudolf Polony , Gerhard Reinert , Gerd Holzle , Andre Pugin , Rodolphe Vonderwahl
IPC分类号： C07D487/22 , A01N43/90 , A01N47/28 , A01N47/42 , A01N55/02 , A61K31/40 , A61K31/44 , A61K31/495 , A61K31/53 , A61K31/535 , A61L2/18 , A61P31/04 , A61P31/12 , C02F1/50 , C09B47/04 , C09B47/24 , C09B47/26 , C11D3/00 , C11D3/48 , D06M16/00 , A61L2/08
CPC分类号： C11D3/48 , A01N43/90 , A01N47/28 , A01N47/42 , C09B47/045 , C09B47/26 , C11D3/0063 , D06M16/00 , Y02W10/37
摘要： A process for combating micro-organisms in or on organic or inorganic substrates and for protecting the said substrates against attack by micro-organisms, which comprises treating the substrates with a water-soluble phthalocyanine derivative, in the presence of oxygen and water and while irradiating with light in the infra-red and/or visible range, antimicrobical agents containing water-soluble phthalocyanine compounds as well as new phthalocyanine compounds are described.
摘要翻译：一种在有机或无机基质中或其上或与有机或无机基质上或在其上保护微生物以防止微生物侵袭的方法，其包括在氧和水的存在下用水溶性酞菁衍生物处理底物，同时照射在红外和/或可见光范围内，描述了含有水溶性酞菁化合物的抗微生物剂以及新的酞菁化合物。

2. 发明授权

US4497741A Water-soluble zinc and aluminium phthalocyanines 失效
标题翻译：水溶性锌和铝酞菁
公开(公告)号：US4497741A
公开(公告)日：1985-02-05
申请号：US445784
申请日：1982-12-01
申请人： Gerd Holzle , Mirella Miotto , Gerhard Reinert , Rudolf Polony
发明人： Gerd Holzle , Mirella Miotto , Gerhard Reinert , Rudolf Polony
IPC分类号： A01N43/90 , A01N47/40 , A01N55/02 , C07D487/22 , C07F3/06 , C07F5/06 , C11D3/00 , C11D3/39 , C11D3/395 , C11D7/54 , D06L3/04 , D06L3/06 , D06M16/00 , C09B47/04
CPC分类号： C07D487/22 , A01N43/90 , A01N47/40 , C11D3/0063 , C11D3/3932 , D06M16/00 , Y02W10/37
摘要： The invention relates to novel zinc and aluminium phthalocyanine compounds of the formula ##STR1## wherein MePc is the zinc or aluminium phthalocyanine ring system, M is hydrogen or a salt-forming cation, P.sub.1 is hydrogen or a group of the formula --NH--CN or NH--SO.sub.2 R.sub.3 or the salts thereof, wherein R.sub.3 is alkyl, aryl or a heterocyclic ring system, R.sub.2 is a neutral, non-solubilizing substituent, n is 1 to 4 and each of m and q is 0 to 3 and p is 0 to 4. These compounds are prepared by starting from the corresponding sulfohalides. The novel compounds are used as photoactivators, especially for bleaching and removing stains from textiles and for combating microorganisms in or on organic or inorganic substrates. The invention also relates to bleaching, detergent and soaking and microbicidal compositions which contain the novel phthalocyanine compounds.
摘要翻译：本发明涉及新型的具有式“IMAGE”的锌和铝酞菁化合物，其中MePc是锌或铝酞菁环体系，M是氢或成盐阳离子，P1是氢或式-NH-CN 或NH-SO 2 R 3或其盐，其中R 3是烷基，芳基或杂环体系，R 2是中性的，不溶解的取代基，n是1至4，m和q各自为0至3，p为0 这些化合物通过从相应的磺酰卤开始制备。新型化合物用作光活化剂，特别是用于漂白和去除纺织品中的污渍并且在有机或无机基材中或在有机或无机基材上对抗微生物。本发明还涉及含有新型酞菁化合物的漂白剂，洗涤剂和浸泡和杀菌组合物。

3. 发明授权

US4566874A Water-soluble zinc and aluminium phthalocyanines and use thereof as photoactivators 失效
标题翻译：水溶性锌和铝酞菁及其作为光活化剂的用途
公开(公告)号：US4566874A
公开(公告)日：1986-01-28
申请号：US678314
申请日：1984-12-05
申请人： Gerd Holzle , Mirella Miotto , Gerhard Reinert , Rudolf Polony
发明人： Gerd Holzle , Mirella Miotto , Gerhard Reinert , Rudolf Polony
IPC分类号： A01N43/90 , A01N47/40 , C07D487/22 , C11D3/00 , D06M16/00 , D06L3/04
CPC分类号： C07D487/22 , A01N43/90 , A01N47/40 , C11D3/0063 , D06M16/00
摘要： The invention relates to novel zinc and aluminium phthalocyanine compounds of the formula ##STR1## wherein MePc is the zinc or aluminium phthalocyanine ring system, M is hydrogen or a salt-forming cation, R.sub.1 is hydrogen or a group of the formula --NH--CN or NH--SO.sub.2 R.sub.3 or the salts thereof, wherein R.sub.3 is alkyl, aryl or a heterocyclic ring system, R.sub.2 is a neutral, non-solubilizing substituent, n is 1 to 4 and each of m and q is 0 to 3 and p is 0 to 4. These compounds are prepared by starting from the corresponding sulfohalides. The novel compounds are used as photoactivators, especially for bleaching and removing stains from textiles and for combating microorganisms in or on organic or inorganic substrates. The invention also relates to bleaching, detergent and soaking and microbicidal compositions which contain the novel phthalocyanine compounds.
摘要翻译：本发明涉及新型的具有式“IMAGE”的锌和铝酞菁化合物，其中MePc是锌或铝酞菁环体系，M是氢或成盐阳离子，R1是氢或式-NH-CN 或NH-SO 2 R 3或其盐，其中R 3是烷基，芳基或杂环体系，R 2是中性的，不溶解的取代基，n是1至4，m和q各自为0至3，p为0 这些化合物通过从相应的磺酰卤开始制备。新型化合物用作光活化剂，特别是用于漂白和去除纺织品中的污渍并且在有机或无机基材中或在有机或无机基材上对抗微生物。本发明还涉及含有新型酞菁化合物的漂白剂，洗涤剂和浸泡和杀菌组合物。

4. 发明授权

US4456452A Process for bleaching textiles and for combating microorganisms with sulphonated phthalocyanine carrying halogen or pseudohalogen substituents as photoactivator 失效
标题翻译：漂白纺织品和用携带卤素或假卤素取代基的磺化酞菁作为光活化剂对抗微生物的方法
公开(公告)号：US4456452A
公开(公告)日：1984-06-26
申请号：US479401
申请日：1983-03-28
申请人： Gerd Holzle , Gerhard Reinert , Rudolf Polony
发明人： Gerd Holzle , Gerhard Reinert , Rudolf Polony
IPC分类号： C02F1/30 , A01N43/90 , A01N55/02 , C07D487/22 , C09B47/04 , C11D3/00 , C11D7/54 , D06L3/00 , D06L3/04 , D06L3/12 , D06M13/02 , D06M13/244 , D06M13/248 , D06M13/262 , D06M13/322 , D06M13/342 , D06M13/345 , D06M13/35 , D06M13/352 , D06M13/50 , D06M13/503 , D06M23/00 , C11D3/39
CPC分类号： C09B47/045 , C11D3/0063 , Y02W10/37
摘要： A process is proposed for bleaching textiles or removing stains from textiles and for combating micro-organisms in or on organic or inorganic substrates, or for protecting the latter against attack by micro-organisms, by treating the textiles or the substrates to be freed of or protected from micro-organisms with a water-soluble zinc phthalocyanine or aluminium phthalocyanine, in the presence of water and under irradiation with light, in which process a sulfonated zinc phthalocyanine or aluminium phthalocyanine which is further substituted by neutral groups which do not confer solubility in water, for example by halogen atoms or pseudo-halogens, or a mixture of these phthalocyanine compounds, is used as the water-soluble zinc phthalocyanine or aluminium phthalocyanine.Bleaching, washing and soaking agents or agents having an antimicrobial action, for carrying out the process, are also proposed, which, in addition to the active ingredient, contain, if appropriate, inorganic salts, water and also, in the case of washing agents, customary washing-agent constituents. Novel sulfonated zinc phthalocyanine and aluminium phthalocyanine compounds and their preparation are furthermore described.
摘要翻译：提出了一种方法，用于漂白纺织品或从织物上除去污渍并在有机或无机基材中或其上或与有机或无机基材上的微生物相抗衡，或通过处理纺织品或基材以免去或在水和光照射下用水溶性锌酞菁或铝酞菁保护免受微生物的侵害，其中进一步被中性基团取代的磺化锌酞菁或铝酞菁，其不被赋予溶解度水，例如卤素原子或假卤素，或这些酞菁化合物的混合物，被用作水溶性锌酞菁或铝酞菁。还提出了用于进行该方法的具有抗微生物作用的漂白，洗涤和浸泡剂或试剂，除了活性成分之外，还可以含有无机盐，水以及在洗涤剂的情况下，习惯洗涤剂成分。还描述了新型磺化锌酞菁和铝酞菁化合物及其制备。

5. 发明授权

US4530924A Phthalocyanine compounds and anti-microbial use 失效
标题翻译：酞菁化合物和抗菌剂使用
公开(公告)号：US4530924A
公开(公告)日：1985-07-23
申请号：US316582
申请日：1981-10-30
申请人： Rudolf Polony , Gerhard Reinert , Gerd Holzle , Andre Pugin , Rodolphe Vonderwahl
发明人： Rudolf Polony , Gerhard Reinert , Gerd Holzle , Andre Pugin , Rodolphe Vonderwahl
IPC分类号： C07D487/22 , A01N43/90 , A01N47/28 , A01N47/42 , A01N55/02 , A61K31/40 , A61K31/44 , A61K31/495 , A61K31/53 , A61K31/535 , A61L2/18 , A61P31/04 , A61P31/12 , C02F1/50 , C09B47/04 , C09B47/24 , C09B47/26 , C11D3/00 , C11D3/48 , D06M16/00 , A01N43/38
CPC分类号： C11D3/48 , A01N43/90 , A01N47/28 , A01N47/42 , C09B47/045 , C09B47/26 , C11D3/0063 , D06M16/00 , Y02W10/37
摘要： A process for combating micro-organisms in or on organic or inorganic substrates and for protecting the said substrates against attack by micro-organisms, which comprises treating the substrates with a water-soluble phthalocyanine derivative, in the presence of oxygen and water and while irradiating with light in the infra-red and/or visible range, antimicrobical agents containing water-soluble phthalocyanine compounds as well as new phthalocyanine compounds are described.
摘要翻译：一种在有机或无机基质中或其上或与有机或无机基质上或在其上保护微生物以防止微生物侵袭的方法，其包括在氧和水的存在下用水溶性酞菁衍生物处理底物，同时照射在红外和/或可见光范围内，描述了含有水溶性酞菁化合物的抗微生物剂以及新的酞菁化合物。

6. 发明授权

US4394125A Process for bleaching textiles and for combating micro-organisms with sulfonated phthalocyanine of aluminum or zinc and containing halogen or cyano substituents as photoactivator 失效
标题翻译：用于漂白纺织品和用铝或锌的磺化酞菁与含有卤素或氰基取代基作为光活化剂的微生物相结合的方法
公开(公告)号：US4394125A
公开(公告)日：1983-07-19
申请号：US298229
申请日：1981-08-31
申请人： Gerd Holzle , Gerhard Reinert , Rudolf Polony
发明人： Gerd Holzle , Gerhard Reinert , Rudolf Polony
IPC分类号： C02F1/30 , A01N43/90 , A01N55/02 , C07D487/22 , C09B47/04 , C11D3/00 , C11D7/54 , D06L3/00 , D06L3/04 , D06L3/12 , D06M13/02 , D06M13/244 , D06M13/248 , D06M13/262 , D06M13/322 , D06M13/342 , D06M13/345 , D06M13/35 , D06M13/352 , D06M13/50 , D06M13/503 , D06M23/00 , A01N43/00 , C02F1/50
CPC分类号： C09B47/045 , C11D3/0063 , Y02W10/37
摘要： A process is proposed for bleaching textiles or removing stains from textiles and for combating micro-organisms in or on organic or inorganic substrates, or for protecting the latter against attack by micro-organisms, by treating the textiles or the substrates to be freed of or protected from micro-organisms with a water-soluble zinc phthalocyanine or aluminium phthalocyanine, in the presence of water and under irradiation with light, in which process a sulfonated zinc phthalocyanine or aluminium phthalocyanine which is further substituted by neutral groups which do not confer solubility in water, for example by halogen atoms or pseudo-halogens, or a mixture of these phthalocyanine compounds, is used as the water-soluble zinc phthalocyanine or aluminium phthalocyanine.Bleaching, washing and soaking agents or agents having an antimicrobial action, for carrying out the process, are also proposed, which, in addition to the active ingredient, contain, if appropriate, inorganic salts, water and also, in the case of washing agents, customary washing agent constituents. Novel sulfonated zinc phthalocyanine and aluminium phthalocyanine compounds and their preparation are furthermore described.
摘要翻译：提出了一种方法，用于漂白纺织品或从织物上除去污渍并在有机或无机基材中或其上或与有机或无机基材上的微生物相抗衡，或通过处理纺织品或基材以免去或在水和光照射下用水溶性锌酞菁或铝酞菁保护免受微生物的侵害，其中进一步被中性基团取代的磺化锌酞菁或铝酞菁，其不被赋予溶解度水，例如卤素原子或假卤素，或这些酞菁化合物的混合物，被用作水溶性锌酞菁或铝酞菁。还提出了用于进行该方法的具有抗微生物作用的漂白，洗涤和浸泡剂或试剂，除了活性成分之外，还可以含有无机盐，水以及在洗涤剂的情况下，习惯洗涤剂成分。还描述了新型磺化锌酞菁和铝酞菁化合物及其制备。

7. 发明授权

US4166718A Process for bleaching textiles 失效
标题翻译：漂白纺织品的工艺
公开(公告)号：US4166718A
公开(公告)日：1979-09-04
申请号：US888593
申请日：1978-03-20
申请人： Gerhard Reinert , Gerd Holzle , Andre Pugin
发明人： Gerhard Reinert , Gerd Holzle , Andre Pugin
IPC分类号： C11D3/395 , C09B47/24 , C11D3/00 , C11D3/40 , C11D7/54 , D06L4/50 , D06L3/02
CPC分类号： C11D3/40 , C11D3/0063
摘要： A process for bleaching textiles which comprises treating stained textiles in an aqueous bath containing at least one water-soluble aluminium phthalocyanine, under irradiation with light and in the presence of oxygen, while either irradiating the bleaching bath direct or subsequently irradiating the moist textiles outside the bath, as well as water-soluble aluminium phthalocyanines containing detergent compositions are described.
摘要翻译：一种用于漂白纺织品的方法，其包括在用光照射和氧气存在下处理含有至少一种水溶性铝酞菁的水浴中的染色纺织品，同时向所述漂白浴照射所述漂白浴直接或随后照射所述湿纺织品浴，以及含有洗涤剂组合物的水溶性铝酞菁。

8. 发明授权

US4657554A Water-soluble azaphthalocyanines and their use as photoactivators in bleaching 失效
标题翻译：水溶性萘酞菁及其作为光活化剂在漂白中的应用
公开(公告)号：US4657554A
公开(公告)日：1987-04-14
申请号：US736913
申请日：1985-05-22
申请人： Gerhard Reinert , Gerd Holzle , Gregor Graf
发明人： Gerhard Reinert , Gerd Holzle , Gregor Graf
IPC分类号： A01N43/90 , A01N55/02 , A01N55/04 , A61L2/16 , C02F1/50 , C07D471/22 , C07D487/22 , C09B47/04 , C09B47/08 , C09B62/537 , C11D3/00 , C11D3/395 , C11D3/42 , D06L3/00 , D06L3/02
CPC分类号： C11D3/0063 , A01N55/02 , A01N55/04 , C07D471/22 , C07D487/22 , C09B47/045 , C09B62/537 , Y02W10/37
摘要： Novel azaphthalocyanines are described which are of the formula ##STR1## in which Me is Al(III), Zn(II), Ge(IV) or Sn(IV), E is an anionic group, Z is a cation, Y is a halogen, n is any desired number from 1 to 3 and p is any desired number from 0 to 2, the sum n+p being at most 8 and A, B, C and D independently of one another completing a benzene ring or a ring of the formula ##STR2## at least one of the rings completed by A, B, C or D being one of the said heterocyclic rings.The novel compounds can be used as photoactivators, in particular for bleaching textiles and for controlling microorganisms in or on organic or inorganic substrates.Bleaching, washing and steeping agents and antimicrobially active agents are also described which contain the novel azaphthalocyanine compounds. The azaphthalocyanine pigments which arise as intermediates and which do not carry groups EZ imparting solubility in water, their preparation and their use as photosensitizers in non-aqueous or heterogeneous systems are likewise described.
摘要翻译：描述了具有其中Me为Al（III），Zn（II），Ge（IV）或Sn（IV）的式“IMAGE”的新型氮杂酞菁，E为阴离子基团，Z为阳离子，Y为卤素，n是1至3的任何所需数，p是0至2的任何所需数，n + p最多为8，A，B，C和D彼此独立地完成苯环或环由式A，B，C或D所完成的至少一个环是所述杂环之一。新化合物可用作光活化剂，特别是用于漂白纺织品和用于控制有机或无机基材中或之上的微生物。还描述了含有新型氮杂萘菁化合物的漂白剂，洗涤剂和浸渍剂和抗微生物剂。同样描述了作为中间体产生并且不携带在水中赋予溶解性的组EZ，它们的制备及其作为光敏剂在非水或异质体系中的用途的氮杂酞菁颜料。

9. 发明授权

US4648992A Water-soluble phthalocyanine compounds 失效
标题翻译：水溶性酞菁化合物
公开(公告)号：US4648992A
公开(公告)日：1987-03-10
申请号：US700203
申请日：1985-02-11
申请人： Gregor Graf , Gerd Holzle , Gerhard Reinert
发明人： Gregor Graf , Gerd Holzle , Gerhard Reinert
IPC分类号： C11D7/54 , A01N43/90 , A01N55/02 , C07D487/22 , C07F5/00 , C07F7/00 , C07F9/02 , C07F11/00 , C09B47/04 , C09B47/24 , C11D3/00 , C11D3/48 , D06L3/00 , D06M16/00
CPC分类号： C07D487/22 , A01N43/90 , C09B47/045 , C09B47/24 , C11D3/0063 , C11D3/48 , D06M16/00
摘要： Novel phthalocyanine compounds are described, which have the formula ##STR1## in which MePc is the Si(IV)-, P(V)-, Ti(IV)-, Ge(IV)-, Cr(IV)-, Ga(III)-, Zr(IV)-, In(III)-, Sn(IV)- or Hf(IV)- phthalocyanine or -naphthalocyanine ring system, A is an anionic, nonionic or cationic group which imparts solubility in water, Z is the counter-ion to A, if the latter is an ionic group, and is 0 if A is a nonionic group, n is any desired number from 1 to 8, Y is a neutral substituent which does not impart solubility in water and p is any desired number from 0 to 6, it being possible for the groups AZ and Y present in the molecule to be identical or different in either case, and the sum of n+p being not more than 8 and MePc not being the Sn(IV)-phthalocyanine or Sn(IV)-naphthalocyanine ring system if p is 0 and if the only groups imparting water-solubility in the molecule are sulfo groups. The novel compounds can be used as photoactivators, particularly for bleaching textiles and for controlling microorganisms in or on organic or inorganic substrates. Bleaching, washing and steeping agents and agents having antimicrobial activity, which contain the novel phthalocyanine compounds, are also described.
摘要翻译：描述了新的酞菁化合物，其具有其中MePc是Si（IV） - ，P（V） - ，Ti（IV） - ，Ge（IV） - ，Cr（IV） - ，Ga III） - ，Zr（IV） - ，In（III） - ，Sn（IV） - 或Hf（IV） - 酞菁或 - 萘酞菁系统，A是赋予水溶性的阴离子，非离子或阳离子基团是与A的反离子，如果后者是离子基团，并且如果A是非离子基团，则为0，n是1至8的任何所需数量，Y是不赋予水溶解度的中性取代基，p 是从0到6的任何所需数目，存在于分子中的基团AZ和Y可以在任一情况下相同或不同，并且n + p的总和不大于8，MePc不是Sn（ IV） - 酞菁或Sn（IV） - 萘酞菁环体系，如果p为0，且分子中仅赋予水溶性的基团为磺基。新化合物可用作光活化剂，特别是用于漂白纺织品和用于控制有机或无机基材中或其上的微生物。还描述了漂白，洗涤和浸渍剂和具有抗微生物活性的试剂，其含有新的酞菁化合物。

10. 发明授权

US5914444A Process for increasing the sun protection factor of cellulosic fiber materials 失效
标题翻译：提高纤维素纤维材料防晒系数的方法
公开(公告)号：US5914444A
公开(公告)日：1999-06-22
申请号：US913438
申请日：1997-09-15
申请人： Gerhard Reinert , Francesco Fuso , Rolf Hilfiker
发明人： Gerhard Reinert , Francesco Fuso , Rolf Hilfiker
IPC分类号： D06P1/62 , D06P1/642 , D06P1/649 , D06P1/651 , D06P1/653 , D06P3/62
CPC分类号： D06P1/6536 , D06P1/628 , D06P1/6426 , D06P1/6495 , D06P1/65112 , D06P1/65118 , D06P1/65125 , D06P3/62
摘要： Process for increasing the sun protection factor of cellulosic fibre materials by treating the cellulosic fibre materials with at least one direct dye and at least one UV absorber.
摘要翻译： PCT No.PCT / EP96 / 00896 371日期：1997年9月15日 102（e）1997年9月15日PCT PCT 1996年3月4日PCT公布。 WO96 / 29461 PCT出版物日期1996年9月26日通过用至少一种直接染料和至少一种UV吸收剂处理纤维素纤维材料来增加纤维素纤维材料的防晒系数的方法。

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