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1. 发明授权

US08269037B2 Absorption medium for removing acid gases which comprises amino acid and acid promoter 有权
标题翻译：用于除去含有氨基酸和酸促进剂的酸性气体的吸收介质
公开(公告)号：US08269037B2
公开(公告)日：2012-09-18
申请号：US12695601
申请日：2010-01-28
申请人： Gerald Vorberg , Torsten Katz , Georg Sieder , Christian Riemann , Rupert Wagner , Ute Lichtfers , Erika Dengler
发明人： Gerald Vorberg , Torsten Katz , Georg Sieder , Christian Riemann , Rupert Wagner , Ute Lichtfers , Erika Dengler
IPC分类号： C07F9/38 , C07C229/04 , B01D53/40
CPC分类号： B01D53/1493 , B01D53/52 , B01D53/62 , B01D2252/20494 , B01D2252/205 , B01D2256/24 , B01D2257/302 , B01D2257/306 , B01D2257/308 , B01D2257/408 , B01D2257/504 , B01D2258/06 , C10L3/10 , C10L3/102 , Y02C10/04
摘要： An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution of a) of at least one metal salt of an aminocarboxylic acid, and b) of at least one acid promoter, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The acid promoter is selected from mineral acids, carboxylic acids, sulfonic acids, organic phosphonic acids and partial esters thereof. The absorption medium, compared with absorption media based on amino acid salts, has a reduced regeneration energy requirement without significantly reducing the absorption capacity of the solution for acid gases. In a process for removing acid gases from the fluid stream, the fluid stream is brought into contact with the absorption medium.
摘要翻译：用于从流体流中除去酸性气体的吸收介质包含a）至少一种氨基羧酸金属盐的水溶液，和b）至少一种酸促进剂，其中b）与a）的摩尔比为在0.0005至1.0的范围内。酸促进剂选自无机酸，羧酸，磺酸，有机膦酸及其偏酯。与基于氨基酸盐的吸收介质相比，吸收介质具有降低的再生能量需求，而不显着降低酸性气体溶液的吸收能力。在从流体流中除去酸性气体的过程中，流体物流与吸收介质接触。

2. 发明授权

US08221712B2 Absorption medium for the selective removal of hydrogen sulfide from fluid streams 有权
标题翻译：用于从流体流中选择性除去硫化氢的吸收介质
公开(公告)号：US08221712B2
公开(公告)日：2012-07-17
申请号：US12576277
申请日：2009-10-09
申请人： Gerald Vorberg , Torsten Katz , Georg Sieder , Christian Riemann , Erika Dengler
发明人： Gerald Vorberg , Torsten Katz , Georg Sieder , Christian Riemann , Erika Dengler
IPC分类号： C07F9/38 , B01D53/14 , B01D53/46 , B01D53/48 , B01D53/54 , B01D53/62 , B01D53/68
CPC分类号： B01D53/1462 , B01D53/1493 , B01D2251/70 , B01D2257/304 , B01D2258/06 , Y02E50/346
摘要： An absorption medium for the removal of acid gases from a fluid stream comprises an aqueous solution a) of at least one amine and b) at least one phosphonic acid, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The phosphonic acid is, e.g., 1-hydroxyethane-1,1-diphosphonic acid. The absorption medium exhibits a reduced regeneration energy requirement compared with absorption media based on amines or amine/promoter combinations, without significantly decreasing the absorption capacity of the solution for acid gases.
摘要翻译：用于从流体流中除去酸性气体的吸收介质包含至少一种胺的水溶液a）和b）至少一种膦酸，其中b）与a）的摩尔比在0.0005至 1.0。膦酸是例如1-羟基乙烷-1,1-二膦酸。与基于胺或胺/促进剂组合的吸收介质相比，吸收介质显示出降低的再生能量需求，而不显着降低酸性气体溶液的吸收能力。

3. 发明授权

US08501035B2 Absorption medium for removing acid gases from a fluid stream 有权
标题翻译：用于从流体流中除去酸性气体的吸收介质
公开(公告)号：US08501035B2
公开(公告)日：2013-08-06
申请号：US12850041
申请日：2010-08-04
申请人： Christian Riemann , Torsten Katz , Georg Sieder , Gerald Vorberg , Erika Dengler
发明人： Christian Riemann , Torsten Katz , Georg Sieder , Gerald Vorberg , Erika Dengler
IPC分类号： C07C229/12 , C07D241/04 , B01D53/40
CPC分类号： B01D53/1456 , B01D53/1487 , B01D53/1493 , B01D2257/302 , B01D2257/304 , B01D2257/306 , B01D2257/308 , B01D2257/504 , B01D2258/05 , B01D2258/06 , C12M47/18 , Y02E50/346 , Y02P20/59
摘要： An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution (A) of an alkali metal salt of an N,N-di-C1-C4-alkylaminocarboxylic acid and (B) N-hydroxyethylpiperazine. The absorption medium has a low vapor pressure and an increased resistance to oxygen. Preferred fluid streams are combustion exhaust gases or biogas.
摘要翻译：用于从流体流中除去酸性气体的吸收介质包含N，N-二-C1- C4烷基氨基羧酸和（B）N-羟乙基哌嗪的碱金属盐的水溶液（A）。吸收介质具有低蒸气压和增加的耐氧性。优选的流体流是燃烧废气或沼气。

4. 发明申请

US20100288125A1 ABSORPTION MEDIUM FOR THE SELECTIVE REMOVAL OF HYDROGEN SULFIDE FROM FLUID STREAMS 有权
标题翻译：从流体流中选择性去除氢硫化物的吸收介质
公开(公告)号：US20100288125A1
公开(公告)日：2010-11-18
申请号：US12576277
申请日：2009-10-09
申请人： Gerald Vorberg , Torsten Katz , Georg Sieder , Christian Riemann , Erika Dengler
发明人： Gerald Vorberg , Torsten Katz , Georg Sieder , Christian Riemann , Erika Dengler
IPC分类号： B01D53/14 , C09K3/00
CPC分类号： B01D53/1462 , B01D53/1493 , B01D2251/70 , B01D2257/304 , B01D2258/06 , Y02E50/346
摘要： An absorption medium for the removal of acid gases from a fluid stream comprises an aqueous solution a) of at least one amine and b) at least one phosphonic acid, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The phosphonic acid is, e.g., 1-hydroxyethane-1,1-diphosphonic acid. The absorption medium exhibits a reduced regeneration energy requirement compared with absorption media based on amines or amine/promoter combinations, without significantly decreasing the absorption capacity of the solution for acid gases.
摘要翻译：用于从流体流中除去酸性气体的吸收介质包含至少一种胺的水溶液a）和b）至少一种膦酸，其中b）与a）的摩尔比在0.0005至 1.0。膦酸是例如1-羟基乙烷-1,1-二膦酸。与基于胺或胺/促进剂组合的吸收介质相比，吸收介质显示出降低的再生能量需求，而不显着降低酸性气体溶液的吸收能力。

5. 发明申请

US20110033354A1 ABSORPTION MEDIUM FOR REMOVING ACID GASES FROM A FLUID STREAM 有权
标题翻译：用于从流体流中去除酸性气体的吸收介质
公开(公告)号：US20110033354A1
公开(公告)日：2011-02-10
申请号：US12850041
申请日：2010-08-04
申请人： Christian Riemann , Torsten Katz , Georg Sieder , Gerald Vorberg , Erika Dengler
发明人： Christian Riemann , Torsten Katz , Georg Sieder , Gerald Vorberg , Erika Dengler
IPC分类号： B01D53/40 , C09K3/00 , B01D53/14
CPC分类号： B01D53/1456 , B01D53/1487 , B01D53/1493 , B01D2257/302 , B01D2257/304 , B01D2257/306 , B01D2257/308 , B01D2257/504 , B01D2258/05 , B01D2258/06 , C12M47/18 , Y02E50/346 , Y02P20/59
摘要： An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution (A) of an alkali metal salt of an N,N-di-C1-C4-alkylaminocarboxylic acid and (B) N-hydroxyethylpiperazine. The absorption medium has a low vapor pressure and an increased resistance to oxygen. Preferred fluid streams are combustion exhaust gases or biogas.
摘要翻译：用于从流体流中除去酸性气体的吸收介质包含N，N-二-C1- C4烷基氨基羧酸和（B）N-羟乙基哌嗪的碱金属盐的水溶液（A）。吸收介质具有低蒸气压和增加的耐氧性。优选的流体流是燃烧废气或沼气。

6. 发明申请

US20100186590A1 ABSORPTION MEDIUM FOR REMOVING ACID GASES WHICH COMPRISES AMINO ACID AND ACID PROMOTER 有权
标题翻译：用于去除含有氨基酸和酸性促进剂的酸性气体的吸收介质
公开(公告)号：US20100186590A1
公开(公告)日：2010-07-29
申请号：US12695601
申请日：2010-01-28
申请人： Gerald Vorberg , Torsten Katz , Georg Sieder , Christian Riemann , Rupert Wagner , Ute Lichtfers , Erika Dengler
发明人： Gerald Vorberg , Torsten Katz , Georg Sieder , Christian Riemann , Rupert Wagner , Ute Lichtfers , Erika Dengler
IPC分类号： B01D53/14 , C09K3/00
CPC分类号： B01D53/1493 , B01D53/52 , B01D53/62 , B01D2252/20494 , B01D2252/205 , B01D2256/24 , B01D2257/302 , B01D2257/306 , B01D2257/308 , B01D2257/408 , B01D2257/504 , B01D2258/06 , C10L3/10 , C10L3/102 , Y02C10/04
摘要： An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution of a) of at least one metal salt of an aminocarboxylic acid, and b) of at least one acid promoter, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The acid promoter is selected from mineral acids, carboxylic acids, sulfonic acids, organic phosphonic acids and partial esters thereof. The absorption medium, compared with absorption media based on amino acid salts, has a reduced regeneration energy requirement without significantly reducing the absorption capacity of the solution for acid gases. In a process for removing acid gases from the fluid stream, the fluid stream is brought into contact with the absorption medium.
摘要翻译：用于从流体流中除去酸性气体的吸收介质包含a）至少一种氨基羧酸金属盐的水溶液，和b）至少一种酸促进剂，其中b）与a）的摩尔比为在0.0005至1.0的范围内。酸促进剂选自无机酸，羧酸，磺酸，有机膦酸及其偏酯。与基于氨基酸盐的吸收介质相比，吸收介质具有降低的再生能量需求，而不显着降低酸性气体溶液的吸收能力。在从流体流中除去酸性气体的过程中，流体物流与吸收介质接触。

7. 发明授权

US08758483B2 Process for recovery of carbon dioxide from a fluid stream, in particular from syngas 有权
公开(公告)号：US08758483B2
公开(公告)日：2014-06-24
申请号：US13322125
申请日：2010-05-25
申请人： Torsten Katz , Georg Sieder , Koji Tanaka
发明人： Torsten Katz , Georg Sieder , Koji Tanaka
IPC分类号： B01D53/14
摘要： A process for removing carbon dioxide from a fluid comprises the steps of: (a) treating the fluid by bringing it into countercurrent contact with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone to absorb at least part of the carbon dioxide contained in the fluid into the absorbent; (b) depressurizing the loaded absorbent to release a first stream of carbon dioxide and yield a partially regenerated absorbent; (c) recycling a first stream of the partially regenerated absorbent into the first absorption zone; (d) heating a second stream of the partially regenerated absorbent to release a second stream of carbon dioxide and yield a regenerated absorbent; (e) recycling the regenerated absorbent into the second absorption zone; (f) condensing water vapor entrained in the second stream of carbon dioxide by cooling the second stream of carbon dioxide and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange. The invention provides a two-stage carbon dioxide recovery process wherein the overall energy required for carbon dioxide recovery is reduced and/or wherein at least part of the carbon dioxide is recovered at a pressure higher than atmospheric pressure so as to reduce the energy required for compression of the carbon dioxide, e.g., for sequestration. Also disclosed is a plant for removing carbon dioxide from a fluid.

8. 发明授权

US08795415B2 Process for recovery of carbon dioxide from a fluid stream, in particular from syngas 有权
标题翻译：从流体流，特别是合成气回收二氧化碳的方法
公开(公告)号：US08795415B2
公开(公告)日：2014-08-05
申请号：US13322125
申请日：2010-05-25
申请人： Torsten Katz , Georg Sieder , Koji Tanaka
发明人： Torsten Katz , Georg Sieder , Koji Tanaka
IPC分类号： B01D53/14
CPC分类号： C10K1/08 , Y02C10/06 , Y02E20/16 , Y02E20/18 , Y02E20/185
摘要： A process for removing carbon dioxide from a fluid comprises the steps of: (a) treating the fluid by bringing it into countercurrent contact with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone to absorb at least part of the carbon dioxide contained in the fluid into the absorbent; (b) depressurizing the loaded absorbent to release a first stream of carbon dioxide and yield a partially regenerated absorbent; (c) recycling a first stream of the partially regenerated absorbent into the first absorption zone; (d) heating a second stream of the partially regenerated absorbent to release a second stream of carbon dioxide and yield a regenerated absorbent; (e) recycling the regenerated absorbent into the second absorption zone; (f) condensing water vapor entrained in the second stream of carbon dioxide by cooling the second stream of carbon dioxide and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange. The invention provides a two-stage carbon dioxide recovery process wherein the overall energy required for carbon dioxide recovery is reduced and/or wherein at least part of the carbon dioxide is recovered at a pressure higher than atmospheric pressure so as to reduce the energy required for compression of the carbon dioxide, e.g., for sequestration. Also disclosed is a plant for removing carbon dioxide from a fluid.
摘要翻译：从流体中除去二氧化碳的方法包括以下步骤：（a）通过使流体与第一吸收区中的液体吸收剂逆流接触，然后在第二吸收区中以吸收至少部分碳包含在流体中的二氧化碳变成吸收剂; （b）减压负载的吸收剂以释放第一流二氧化碳并产生部分再生的吸收剂; （c）将部分再生的吸收剂的第一流再循环到第一吸收区中; （d）加热部分再生的吸收剂的第二料流以释放第二二氧化碳流并产生再生的吸收剂; （e）将再生的吸收剂再循环到第二吸收区; （f）通过冷却第二二氧化碳流将夹带在第二二氧化碳流中的水蒸汽冷凝，并通过间接热交换将至少部分回收的热量转移到部分再生的吸收剂中。本发明提供二阶段二氧化碳回收方法，其中减少二氧化碳回收所需的总能量和/或其中至少部分二氧化碳在高于大气压的压力下回收，以便减少二氧化碳回收所需的能量压缩二氧化碳，例如用于封存。还公开了一种用于从流体中除去二氧化碳的设备。

9. 发明申请

US20120067059A1 PROCESS FOR RECOVERY OF CARBON DIOXIDE FROM A FLUID STREAM, IN PARTICULAR FROM SYNGAS 有权
标题翻译：从流体流中回收二氧化碳的方法，特别是从SYNGAS
公开(公告)号：US20120067059A1
公开(公告)日：2012-03-22
申请号：US13322125
申请日：2010-05-25
申请人： Torsten Katz , Georg Sieder , Koji Tanaka
发明人： Torsten Katz , Georg Sieder , Koji Tanaka
IPC分类号： F02C6/18 , C01B3/22 , C01C1/04 , B01D53/14
CPC分类号： C10K1/08 , Y02C10/06 , Y02E20/16 , Y02E20/18 , Y02E20/185
摘要： A process for removing carbon dioxide from a fluid comprises the steps of: (a) treating the fluid by bringing it into countercurrent contact with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone to absorb at least part of the carbon dioxide contained in the fluid into the absorbent; (b) depressurizing the loaded absorbent to release a first stream of carbon dioxide and yield a partially regenerated absorbent; (c) recycling a first stream of the partially regenerated absorbent into the first absorption zone; (d) heating a second stream of the partially regenerated absorbent to release a second stream of carbon dioxide and yield a regenerated absorbent; (e) recycling the regenerated absorbent into the second absorption zone; (f) condensing water vapour entrained in the second stream of carbon dioxide by cooling the second stream of carbon dioxide and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange. The invention provides a two-stage carbon dioxide recovery process wherein the overall energy required for carbon dioxide recovery is reduced and/or wherein at least part of the carbon dioxide is recovered at a pressure higher than atmospheric pressure so as to reduce the energy required for compression of the carbon dioxide, e.g., for sequestration. Also disclosed is a plant for removing carbon dioxide from a fluid.
摘要翻译：从流体中除去二氧化碳的方法包括以下步骤：（a）通过使流体与第一吸收区中的液体吸收剂逆流接触，然后在第二吸收区中以吸收至少部分碳包含在流体中的二氧化碳变成吸收剂; （b）减压负载的吸收剂以释放第一流二氧化碳并产生部分再生的吸收剂; （c）将部分再生的吸收剂的第一流再循环到第一吸收区中; （d）加热部分再生的吸收剂的第二料流以释放第二二氧化碳流并产生再生的吸收剂; （e）将再生的吸收剂再循环到第二吸收区; （f）通过冷却第二二氧化碳流将夹带在第二二氧化碳流中的水蒸汽冷凝，并通过间接热交换将至少部分回收的热量转移到部分再生的吸收剂中。本发明提供二阶段二氧化碳回收方法，其中减少二氧化碳回收所需的总能量和/或其中至少部分二氧化碳在高于大气压的压力下回收，以便减少二氧化碳回收所需的能量压缩二氧化碳，例如用于封存。还公开了一种用于从流体中除去二氧化碳的设备。

10. 发明授权

US08030485B2 Process for the preparation of pulverulent alkoxycarbonylaminotriazine 有权
标题翻译：制备粉状烷氧基羰基氨基三嗪的方法
公开(公告)号：US08030485B2
公开(公告)日：2011-10-04
申请号：US11916747
申请日：2006-05-31
申请人： Joerg Schneider , Guenter Scherr , Rainer Erhardt , Andreas Eichfelder , Martin Reif , Stefan Hirsch , Georg Sieder , Thomas Holtmann , Juergen Ciprian , Hermann Ascherl
发明人： Joerg Schneider , Guenter Scherr , Rainer Erhardt , Andreas Eichfelder , Martin Reif , Stefan Hirsch , Georg Sieder , Thomas Holtmann , Juergen Ciprian , Hermann Ascherl
IPC分类号： C07D251/70 , C07D251/50 , C07D251/48 , C07D251/18
CPC分类号： C07D251/70
摘要： The invention relates to a process for preparing free-flowing, pulverulent alkoxycarbonylaminotriazine from an alkanolic reaction mixture which is obtained in the preparation of alkoxycarbonylaminotriazines and comprises at least one alkoxycarbonylaminotriazine, at least one cyclic and/or acyclic carbonic ester, at least one C1-C13-alkanol which optionally comprises one or two oxygen atoms in the form of ether bonds and is optionally substituted by C1-C4-alkyl and/or hydroxyl, and also at least one alkali metal or alkaline earth metal alkoxide, with or without melamine and with or without catalyst, by atomizing and drying the reaction mixture in a spray drier.
摘要翻译：本发明涉及一种从烷醇反应混合物中制备自由流动的粉末状烷氧基羰基氨基三嗪的方法，其在制备烷氧基羰基氨基三嗪时得到，并且包含至少一种烷氧基羰基氨基三嗪，至少一种环状和/或无环碳酸酯，至少一个C1- 任选地包含一个或两个醚键形式的氧原子并且任选被C 1 -C 4 - 烷基和/或羟基取代的C 13 - 链烷醇，以及至少一种具有或不具有三聚氰胺的碱金属或碱土金属醇盐，以及具有或不具有催化剂，通过在喷雾干燥器中雾化和干燥反应混合物。

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