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1. 发明授权

US4524114A Bifunctional air electrode 失效
标题翻译：双功能空气电极
公开(公告)号：US4524114A
公开(公告)日：1985-06-18
申请号：US510489
申请日：1983-07-05
申请人： George J. Samuels , Thomas A. Schmitkons , Terry L. Streeter , Royce W. Murray
发明人： George J. Samuels , Thomas A. Schmitkons , Terry L. Streeter , Royce W. Murray
IPC分类号： C25B11/04 , H01M4/86
CPC分类号： C25B11/04 , H01M4/8615
摘要： Novel catalytic electrode in which the oxidation catalyst is protected from unfavorable redox potentials by an insulation/rectification matrix composed of a polymeric matrix containing an insulating and rectifying effective amount of a dispersed redox conductor.
摘要翻译：通过由含有绝缘和整流有效量的分散的氧化还原导体的聚合物基体构成的绝缘/矫正基质来保护氧化催化剂免受不利的氧化还原电位的新型催化电极。

2. 发明授权

US5603820A Nitric oxide sensor 失效
标题翻译：一氧化氮传感器
公开(公告)号：US5603820A
公开(公告)日：1997-02-18
申请号：US477620
申请日：1995-06-07
申请人： Tadeusz Malinski , David A. Wink , Janet Younathan , Royce W. Murray , Melani Sullivan , Thomas J. Meyer , Danae D. Christodoulou
发明人： Tadeusz Malinski , David A. Wink , Janet Younathan , Royce W. Murray , Melani Sullivan , Thomas J. Meyer , Danae D. Christodoulou
IPC分类号： B01J31/16 , B01J31/18 , G01N27/30 , G01N27/416 , G01N33/00 , G01N27/26
CPC分类号： B01J31/1815 , B01J31/1658 , G01N27/4045 , B01J2531/025 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： An electrode sensor which may be used to specifically and quantitatively measure nitric oxide is provided, as well as a method of preparing and using such an electrode sensor to measure nitric oxide concentration in solution. A nitric oxide (NO) microsensor based on catalytic oxidation of NO comprises a thermally-sharpened carbon fiber with a tip diameter of about 0.5-0.7 .mu.m coated with several layers of p-type semiconducting polymeric porphyrin and cationic exchanger deposited thereon. The microsensor, which can be operated in either the amperometric, voltammetric or coulometric mode utilizing a two or three electrode system, is characterized by a linear response up to about 300 .mu.M, a response time better than 10 msec and a detection limit of about 10 nM. The sensor of the present invention also discriminates against nitrite, the most problematic interferant in NO measurements. The amount of NO released from a single cell can thus be selectively measured in situ by a porphyrinic microsensor of the invention. A larger scale sensor utilizing porphyrin and cationic exchanger deposited on larger fibers or wires, platinum mesh or tin indium oxide layered on glass, can also be employed when measurement of NO concentration in chemical media, tissue or cell culture is desired.
摘要翻译：提供了可用于特异性和定量测量一氧化氮的电极传感器，以及制备和使用这种电极传感器来测量溶液中的一氧化氮浓度的方法。基于NO的催化氧化的一氧化氮（NO）微量传感器包括具有约0.5-0.7μm的尖锐直径的碳纤维，其涂覆有几层p型半导体聚合物卟啉和沉积在其上的阳离子交换剂。可以使用两个或三个电极系统以电流，伏安或库仑模式操作的微传感器的特征在于线性响应高达约300μM，响应时间优于10msec，检测限为约 10nM。本发明的传感器还可以区分NO测量中最有问题的干扰物亚硝酸盐。因此，可以通过本发明的卟啉微传感器原位选择性地测量从单个电池释放的NO的量。当需要在化学介质，组织或细胞培养物中测量NO浓度时，也可以使用沉积在较大纤维或电线上的卟啉和阳离子交换剂的更大规模的传感器，铂玻璃或层状玻璃上的氧化铟锡。

3. 发明授权

US4756807A Chemically modified electrodes for the catalytic reduction of CO.sub.2 失效
标题翻译：用于催化还原二氧化碳的化学改性电极
公开(公告)号：US4756807A
公开(公告)日：1988-07-12
申请号：US109836
申请日：1987-10-14
申请人： Thomas J. Meyer , Terrence R. O'Toole , Lawrence D. Margerum , T. David Westmoreland , William J. Vining , Royce W. Murray , B. Patrick Sullivan
发明人： Thomas J. Meyer , Terrence R. O'Toole , Lawrence D. Margerum , T. David Westmoreland , William J. Vining , Royce W. Murray , B. Patrick Sullivan
IPC分类号： C08G79/00 , C25C1/00
CPC分类号： C08G79/00
摘要： An electrode that has a film adsorbed to its surface by reductive electropolymerization of (vbpy)Re(CO).sub.3 Cl (4-vinyl-4'-methyl-2,2'-bipyridine tricarbonylchlororhenium(I)) or its acetonitrile analogue, [(vbpy)Re(CO).sub.3 (MeCN)].sup.+ (4-vinyl-4'-methyl-2,2'-bipyridine tricarbonylacetonitrile rhenium (I)). The poly(vbpy)Re(CO).sub.3 Cl or poly[(vbpy)Re(CO).sub.3 (MeCN)].sup.+ adsorbed onto the electrode, acts as a catalyst for CO.sub.2 reduction to CO. Stability and the reactivity of the polymer film may be increased by co-reductive electropolymerization of either of the aforesaid Re complexes with [(bpy).sub.2 Ru(vpy).sub.2.sup.2+ (bis(4-vinyl-pyridine)bis(2,2'-bipyridine) ruthenium (II)) (vpy is 4-vinylpyridine). A bilayer film assembly consisting of poly-[(bpy).sub.2 Ru(vpy).sub.2 ].sup.2+ as an inner film and the aforementioned copolymer of Ru/Re yields even greater reactivity to CO.sub.2.A method of forming a polymeric film on an electrode.A method of reducing CO.sub.2 to CO using an electrode having a polymeric film adsorbed to its surface.
摘要翻译：通过（vbpy）Re（CO）3Cl（4-乙烯基-4'-甲基-2,2'-联吡啶三羰基氯钌（I））或其乙腈类似物的还原电解聚合[ vbpy）Re（CO）3（MeCN）] +（4-乙烯基-4'-甲基-2,2'-联吡啶三羰基乙腈铼（I））。吸附到电极上的聚（vbpy）Re（CO）3Cl或聚[（vbpy）Re（CO）3（MeCN）] +作为CO 2还原为CO的催化剂。稳定性和聚合物膜的反应性可能通过上述Re配合物与[（bpy）2uu（vpy）22+（双（4-乙烯基 - 吡啶）双（2,2'-联吡啶）钌（II））（vpy）的共还原电聚合来增加是4-乙烯基吡啶）。由作为内膜的聚[（bpy）2u（vpy）2] 2+和上述Ru / Re共聚物组成的双层膜组合物产生与CO 2更大的反应性。在电极上形成聚合物膜的方法。使用吸附在其表面上的聚合物膜的电极将CO 2还原成CO的方法。

4. 发明授权

US4711708A Chemically modified electrodes for the catalytic reduction of CO.sub.2 失效
标题翻译：用于催化还原二氧化碳的化学改性电极
公开(公告)号：US4711708A
公开(公告)日：1987-12-08
申请号：US917383
申请日：1986-10-09
申请人： Thomas J. Meyer , Terrence R. O'Toole , Lawrence D. Margerum , T. David Westmoreland , William J. Vining , Royce W. Murray , B. Patrick Sullivan
发明人： Thomas J. Meyer , Terrence R. O'Toole , Lawrence D. Margerum , T. David Westmoreland , William J. Vining , Royce W. Murray , B. Patrick Sullivan
IPC分类号： C08G79/00 , B01D57/02 , C25B7/00
CPC分类号： C08G79/00
摘要： An electrode that has a film adsorbed to its surface by reductive electropolymerization of (vbpy)Re(CO).sub.3 Cl (4-vinyl-4'-methyl-2,2'-bipyridine tricarbonylchlororhenium(I)) or its acetonitrile analogue, [(vbpy)Re(CO).sub.3 (MeCN)].sup.+ (4-vinyl-4'-methyl-2,2'-bipyridine tricarbonylacetonitrile rhenium (I)). The poly (vbpy)Re(CO).sub.3 Cl or poly-[(vbpy)Re(CO).sub.3 (MeCN)].sup.+ adsorbed onto the electrode, acts as a catalyst for CO.sub.2 reduction to CO. Stability and the reactivity of the polymer film may be increased by co-reductive electropolymeriaztion of either of the aforesaid Re complexes with [(bpy).sub.2 Ru(vpy).sub.2.sup.2+ ](bis(4-vinyl-pyridine)bis(2,2'-bipyridine) ruthenium (II)) (vpy is 4-vinylpyridine). A bilayer film assembly consisting of poly-[(bpy).sub.2 Ru(vpy).sub.2 ].sup.2+ as an inner film and the aforementioned copolymer of Ru/Re yields even greater reactivity to CO.sub.2.A method of forming a polymeric film on an electrode.A method of reducing CO.sub.2 to CO using an electrode having a polymeric film adsorbed to its surface.
摘要翻译：通过（vbpy）Re（CO）3Cl（4-乙烯基-4'-甲基-2,2'-联吡啶三羰基氯钌（I））或其乙腈类似物的还原电解聚合[ vbpy）Re（CO）3（MeCN）] +（4-乙烯基-4'-甲基-2,2'-联吡啶三羰基乙腈铼（I））。吸附到电极上的聚（vbpy）Re（CO）3Cl或聚 - [（vbpy）Re（CO）3（MeCN）] +作为CO 2还原为CO的催化剂。稳定性和聚合物膜的反应性可以通过上述Re配合物与[（bpy）2uu（vpy）22 +]（双（4-乙烯基 - 吡啶）双（2,2'-联吡啶）钌（II））的共还原电聚合来增加。（vpy是4-乙烯基吡啶）。由作为内膜的聚[（bpy）2u（vpy）2] 2 +和Ru / Re的上述共聚物组成的双层膜组合物对CO 2产生更大的反应性。在电极上形成聚合物膜的方法。使用吸附在其表面上的聚合物膜的电极将CO 2还原成CO的方法。

5. 发明授权

US07033674B2 Electrical devices employing molten compositions of biomolecules 失效
公开(公告)号：US07033674B2
公开(公告)日：2006-04-25
申请号：US09932196
申请日：2001-08-17
申请人： H. Holden Thorp , Royce W. Murray , Anthony M. Leone , Mary Elizabeth Williams
发明人： H. Holden Thorp , Royce W. Murray , Anthony M. Leone , Mary Elizabeth Williams
IPC分类号： B32B15/04 , H01M6/00
CPC分类号： G11C13/0019 , B82Y10/00 , C08G65/329 , C08G65/333 , C08G81/00 , C08L101/02 , C09D201/02 , G11C13/0014 , Y10T428/31504 , Y10T428/31663 , Y10T428/31678 , Y10T428/31692 , Y10T428/31855 , Y10T428/31971
摘要： Compositions of biomolecules such as nucleic acids that form molten salts are provided. These compositions molten compositions that have useful electrical properties. Such compositions include a salt of (i) an organic polymer ion such as a polynucleic acid anion, and (ii) a polyether or polysiloxane couterion. Methods of making and using such compositions, along with electrical devices such as memory devices, are also provided.

6. 发明授权

US4223049A Superficially mixed metal oxide electrodes 失效
标题翻译：表面混合金属氧化物电极
公开(公告)号：US4223049A
公开(公告)日：1980-09-16
申请号：US908624
申请日：1978-05-23
申请人： Royce W. Murray , P. R. Moses , Larry Wier
发明人： Royce W. Murray , P. R. Moses , Larry Wier
IPC分类号： C25B11/04 , B05D5/12 , C25B11/00 , C25C7/02
CPC分类号： C25B11/0484
摘要： A superficially mixed metal oxide electrode and a method of preparing same. The electrode is useful in anodic electrochemical reactions. There is no distinct outer layer of either noble metal or noble metal oxide. Instead, the noble metal or noble metal oxide is superficially mixed in with a layer of an oxide of a film-forming metal which has been deposited over a conductive base metal.
摘要翻译：表面复合金属氧化物电极及其制备方法。电极可用于阳极电化学反应。贵金属或贵金属氧化物没有明显的外层。相反，贵金属或贵金属氧化物与已经沉积在导电母材上的成膜金属的氧化物层表面混合。

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