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    • 1. 发明授权
    • Encapsulated solar cell assemblage and method of making
    • 封装太阳能电池组合及制作方法
    • US4692557A
    • 1987-09-08
    • US919918
    • 1986-10-16
    • Gay M. SamuelsonDavid J. St. Clair
    • Gay M. SamuelsonDavid J. St. Clair
    • H01L31/048H01L25/02H01L21/56H01L31/18
    • B32B17/10761B32B17/10678B32B17/10788H01L31/048Y02E10/50Y10T156/1092
    • A solar cell assemblage and method of making, comprising:(a) a pre-treated silanized transparent substrate;(b) a layer of semiconductor material;(c) an electrical contact on the surface of said layer of semiconductor material;(d) an extruded transparent film encapsulating the assemblage which comprises 75 to 91 parts by weight of a blend of:65 to 75 parts by weight of a selectively hydrogenated two-block polymer wherein(1) each A is a polymer block of a monovinyl or alpha alkyl monovinyl arene and the A blocks are from 10 to 40% by weight of the total block copolymer, and(2) each B is a polymer block formed by polymerizing a conjugated diene, and the B blocks are 90 to 60% weight of the total block copolymer, and25 to 35 parts by weight of a selectively hydrogenated multiblock copolymer wherein:(1) each A is a polymer endblock of a monovinyl or alpha alkyl monovinyl arene and the A blocks are 10 to 40% by weight of the total block copolymer, and(2) each B is a polymer midblock is formed by polymerizing a conjugated diene and the B blocks are 90 to 10% weight of the total block copolymer,about 8.5 to about 23.5 parts by weight of an (alpha) methyl styrene polymer tackifying resin; andabout 0.5 to about 1.5 parts by weight of a mixture of a phenolic antioxidant, a UV absorber with benzotriazole functionality and a UV absorber with hindered amine functionality;(e) a carbon filled polymer frame; and(f) sealant.
    • 一种太阳能电池组件及其制造方法,包括:(a)预处理的硅烷化透明基板; (b)半导体材料层; (c)在所述半导体材料层的表面上的电接触; (d)封装组合物的挤出透明膜,其包含75至91重量份的以65至75重量份的选择性氢化的二嵌段聚合物的共混物,其中(A)每个A是单乙烯基的聚合物嵌段 或α-烷基单乙烯基芳烃,并且A嵌段占总嵌段共聚物的10〜40重量%,(2)各B是通过使共轭二烯聚合而形成的聚合物嵌段,B嵌段为90〜60重量% 的总嵌段共聚物和25至35重量份的选择性氢化的多嵌段共聚物,其中:(1)每个A是单乙烯基或α-烷基单乙烯基芳烃的聚合物端嵌段,并且A嵌段是10至40重量% 总嵌段共聚物和(2)每个B是聚合物中间嵌段通过聚合共轭二烯而形成,并且B嵌段是总嵌段共聚物的90至1​​0重量%,约8.5至约23.5重量份的(α )甲基苯乙烯聚合物增粘树脂; 和约0.5至约1.5重量份的酚类抗氧化剂,具有苯并三唑官能团的UV吸收剂和具有受阻胺官能团的UV吸收剂的混合物; (e)碳填充聚合物框架; 和(f)密封剂。
    • 2. 发明授权
    • Encapsulated assemblage and method of making
    • US4869966A
    • 1989-09-26
    • US204335
    • 1988-05-27
    • Gay M. SamuelsonDavid J. St. ClairRichard L. Danforth
    • Gay M. SamuelsonDavid J. St. ClairRichard L. Danforth
    • C03C17/32C08L53/02
    • B32B17/10761B32B17/1055B32B17/10678B32B17/10788C03C17/32C08L53/025Y10T428/31612Y10T428/31663
    • An encapsulated assemblage and a process for making an encapsulated assemblage comprising:(a) silanizing a substrate thereby forming a silanized substrate;(b) coating said silanized substrate with at least one thin extruded coherent film forming a coated substrate, said film consisting essentially of:(1) about 75 to about 90 parts by weight of a blend of:(a) about 65 to about 75 parts by weight of a selectively hydrogenated two-block polymer wherein one polymer block is designated by A and a second polmer block is designated by B such that prior to hydrogenation,(1) each A is a polymer block of a monovinyl or alpha alkyl monovinyl arene having a number average molecular weight in the range of from about 5,000 to about 75,000, said A blocks comprising from about 10 to about 40% by weight of the total block copolymer, and(2) each B is a polymer block having a number average molecular weight in the range of from about 10,000 to 150,000 and is formed by polymerizing a conjugated diene having from 4 to 10 carbon atoms per molecule, and said B blocks comprising from about 90 to about 60% weight of the total block copolymer, and(b) about 25 to about 35 parts by weight of a selectively hydrogenated multiblock copolymer which contains at least two kinds of polymer blocks wherein one polymer block is designated by A and a second polymer block is designated by B such that:(1) each A is a polymer endblock of a monovinyl or alpha alkyl monovinyl arene having a number average molecular weight in the range of from about 5,000 to about 75,000, said A blocks comprising from about 10 to about 40% by weight of the total block copolymer, and(2) each B is a polymer midblock having a number average molecular weight in the range of from about 10,000 to about 150,000 and is formed polymerizing a conjugated diene having from 4 to 10 carbon atoms per molecule, and said B blocks comprising from about 90 to about 10% weight of the total block copolymer, and(2) about 9.5 to about 23.5 parts by weight of a hydrogenated .alpha.-methyl styrene polymer resin;(3) about 0.5 to about 1.5 parts by weight of a phenolic antioxidant, a UV absorber with benzotriazole functionality, and a UV absorber with hindered amine functionality;(c) applying a vacuum to the assemblage thereby forming a pressure gradient between said substrate and said film, and thereby vacuum laminating the assemblage; and(d) heating said vacuum laminated assemblage to a temperature greater than the softening point of said film and less than the melting point of solder and thereby heat sealing said assemblage.
    • 3. 发明授权
    • Method of making an encapsulated assemblage
    • 制作封装组合的方法
    • US4749430A
    • 1988-06-07
    • US919919
    • 1986-10-16
    • Gay M. SamuelsonDavid J. St. ClairRichard L. Danforth
    • Gay M. SamuelsonDavid J. St. ClairRichard L. Danforth
    • C03C17/32C08L53/02B29C47/04
    • B32B17/1055B32B17/10678B32B17/10761B32B17/10788C03C17/32C08L53/025Y10T428/2995Y10T428/2998Y10T428/31612
    • An encapsulated assemblage and a process for making comprising:(a) silanizing a substrate;(b) coating the silanized substrate with at least one thin extruded coherent film consisting essentially of:(1) about 75-90 parts by weight of:(a) about 65 to about 75 parts of a selectively hydrogenated two-block polymer (A-B) such that prior to hydrogenation,(1) each A is a polymer block of a monovinyl or alpha alkyl monovinyl arene having a number average molecular weight of 5000 to 75,000 and comprising from about 10 to about 40% by weight of the total block copolymer, and(2) each B is a polymer block having a number average molecular weight of 10,000 to 150,000 and comprising from about 90 to about 60% weight of the total block copolymer, and(b) about 25 to about 35 parts by weight of a selectively hydrogenated multiblock copolymer (A-B) such that:(1) each A is a polymer endblock of a monovinyl or alpha alkyl monovinyl arene having a number average molecular weight of 5,000 to 75,000, said A blocks comprising from about 10 to about 40% by weight of the total block copolymer, and(2) each B is a polymer midblock having a number average molecular weight of 10,000 to 150,000 and is formed by polymerizing a conjugated diene having from 4 to 10 carbon atoms per molecule, and said B blocks comprising from about 90 to about 10% weight of the total block copolymer and(2) about 9.5 to about 23.5 parts by weight of a hydrogenated .alpha.-methyl styrene polymer resin;(3) about 0.5 to about 1.5 parts by weight of a phenolic antioxidant, a UV absorber with benzotriazole functionality, and a UV absorber with hindered amine functionality;(c) vacuum laminating the assemblage; and(d) heat sealing said assemblage.
    • 封装的组合物和制备方法包括:(a)使基底硅烷化; (b)用至少一种薄的挤出相干膜涂覆硅烷化基材,该薄膜基本上由以下组成:(1)约75-90重量份:(a)约65至约75份选择性氢化的二嵌段聚合物 ),使得在氢化之前,(1)每个A是数均分子量为5000至75,000并且包含总嵌段共聚物的约10至约40重量%的单乙烯基或α烷基单乙烯基芳烃的聚合物嵌段 ,和(2)每个B是数均分子量为10,000至150,000且包含总嵌段共聚物的约90至约60重量%的聚合物嵌段,和(b)约25至约35重量份的 选择性氢化多嵌段共聚物(AB),使得:(1)每个A是数均分子量为5,000至75,000的单乙烯基或α-烷基单乙烯基芳烃的聚合物端嵌段,所述A嵌段包含约10至约40% 的总嵌段共聚物, 和(2)每个B是数均分子量为10,000至150,000的聚合物中间嵌段,并且通过每分子聚合具有4至10个碳原子的共轭二烯而形成,并且所述B嵌段包含约90至约10重量% 总嵌段共聚物的重量和(2)约9.5至约23.5重量份的氢化α-甲基苯乙烯聚合物树脂; (3)约0.5至约1.5重量份的酚类抗氧化剂,具有苯并三唑官能团的UV吸收剂和具有受阻胺官能团的UV吸收剂; (c)真空层压组合件; 和(d)热封所述组合件。