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    • 7. 发明授权
    • Process for preparing novel high solids non-aqueous polymer compositions
    • 制备新型高固体非水性聚合物组合物的方法
    • US6110995A
    • 2000-08-29
    • US273688
    • 1994-07-12
    • Wood E. HunterKevin W. FrederickRandy J. Loeffler
    • Wood E. HunterKevin W. FrederickRandy J. Loeffler
    • C08J3/00C08F6/20C08J3/09C08J3/11
    • C08J3/09C08F6/20C08J2300/14
    • The use of falling-film evaporation and a concentration means such as centrifugal separation to dehydrate and concentrate a water-in-oil polymer emulsion or suspension is disclosed. In a preferred embodiment, a water-in-oil polymer composition containing less than about 25% active polymer solids is dehydrated in falling-film evaporator to produce an evaporator concentrate containing less than about 5.0% water. The evaporator concentrate then flows to a separation device such as a centrifuge, wherein oil is removed to produce a composition that is substantially a polymer and emulsifying surfactant-in-oil composition containing in excess of about 60 weight % polymer solids. The centrifuge raffinate may optionally be treated in a second separation means to capture additional polymer solids, with optional recycle of the oil-rich raffinate. The concentrated polymer composition is preferably stabilized with a steric stabilizer to produce a free flowing liquid product.
    • 公开了使用降膜蒸发和诸如离心分离的浓缩装置来使油包水聚合物乳液或悬浮液脱水并浓缩。 在优选的实施方案中,包含少于约25%活性聚合物固体的油包水聚合物组合物在降膜蒸发器中脱水以产生含有少于约5.0%水的蒸发浓缩物。 蒸发器浓缩物然后流到分离装置,例如离心机,其中除去油,以产生基本上是含有超过约60重量%聚合物固体的聚合物和乳化表面活性剂 - 油组合物的组合物。 离心萃余液可以任选地在第二分离装置中处理以捕获另外的聚合物固体,并且富油萃取液的任选循环。 浓缩的聚合物组合物优选用空间稳定剂稳定以产生自由流动的液体产物。