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1. 发明授权

US07193093B2 Process for producing alkylene oxide 有权
标题翻译：环氧烷生产方法
公开(公告)号：US07193093B2
公开(公告)日：2007-03-20
申请号：US10872849
申请日：2004-06-21
申请人： Brendan Dermot Murray , Garo Garbis Vaporciyan
发明人： Brendan Dermot Murray , Garo Garbis Vaporciyan
IPC分类号： C07D301/19
CPC分类号： C07D301/19 , Y02P20/127
摘要： A process for preparing an alkylene oxide, which process comprises: (i) oxidizing an alkylbenzene to obtain a stream comprising alkylbenzene hydroperoxide, (ii) contacting at least part of the alkylbenzene hydroperoxide obtained in step (i) with an olefin to obtain a product stream comprising an alkylene oxide (iii) separating alkylene oxide compound from the product stream of step (ii) to obtain (a) a residual product stream comprising alkylphenyl alcohol, and (b) alkylene oxide, (iv) feeding at least a part of the residual product stream comprising alkylphenyl alcohol to a reactor having a catalytic distillation zone, and concurrently in the reactor, (a) contacting the residual product stream comprising alkylphenyl alcohol with hydrogen in the catalytic distillation zone to convert the alkylphenyl alcohol in the residual product stream to alkylbenzene and form a reaction mixture, and (b) separating alkylbenzene from the reaction mixture by fractional distillation, (v) withdrawing a stream comprising alkylbenzene and having a reduced concentration of alkylphenyl alcohol than the feed stream from the reactor at a position upper from the catalytic reaction zone; (vi) withdrawing from the reactor at a position lower than the catalytic distillation zone a bottom stream comprising dimer(s) of alkylbenzene; (vii) converting the dimer(s) of alkylbenzene in the bottom stream from (vi) to alkylbenzene; and (viii) recycle at least a part of the alkylbenzene produced from (iv)(b) and/or (vi) to step (i).
摘要翻译：一种制备环氧烷的方法，该方法包括：（ⅰ）氧化烷基苯以获得包含烷基苯氢过氧化物的物流，（ⅱ）将步骤（ⅰ）中获得的烷基苯氢过氧化物的至少一部分与烯烃接触，得到产物包含环氧烷的物流（iii）将烯化氧化合物与步骤（ii）的产物流分离，得到（a）包含烷基苯基醇的残余产物流，和（b）烯化氧，（iv）将至少一部分残余产物流包含烷基苯醇至具有催化蒸馏区的反应器，并且同时在反应器中，（a）在催化蒸馏区中使包含烷基苯基醇的残余产物流与氢接触以将残余产物流中的烷基苯醇形成反应混合物，和（b）通过分馏从反应混合物中分离出烷基苯，（v）作为包含烷基苯并且具有降低的烷基苯醇浓度比来自反应器的进料流在催化反应区上方的位置; （vi）在低于催化蒸馏区的位置从反应器中排出包含烷基苯二聚体的底部流; （vii）将底部物流中烷基苯的二聚体从（vi）转化为烷基苯; 和（viii）将从（iv）（b）和/或（vi）至（ⅰ）产生的至少一部分烷基苯再循环。

2. 发明授权

US06455712B1 Preparation of oxirane compounds 有权
标题翻译：环氧乙烷化合物的制备
公开(公告)号：US06455712B1
公开(公告)日：2002-09-24
申请号：US09736522
申请日：2000-12-13
申请人： Garo Garbis Vaporciyan , Brendan Dermot Murray
发明人： Garo Garbis Vaporciyan , Brendan Dermot Murray
IPC分类号： C07D30119
CPC分类号： C07D301/19
摘要： A process for preparing oxirane compounds, which process comprises: (i) oxidizing an alkylaryl to obtain a stream comprising alkylaryl hydroperoxide, (ii) contacting at least a part of the alkylaryl hydroperoxide obtained in step (i) with an olefin in the presence of a catalyst to obtain a product stream comprising an oxirane compound and alkylaryl hydroxyl, (iii) optionally reacting part of the alkylaryl hydroperoxide obtained in step (i) to obtain a mixture comprising (a) phenol, and (b) a ketone and/or aldehyde, and (c) optionally by-products, (iv) separating oxirane compound from the product stream of step (ii) to obtain (a) a residual product stream and (b) oxirane, and (v) contacting at least a part of the residual product stream with hydrogen to obtain alkylaryl, wherein at least a part of said alkylaryl is recycled to step (i).
摘要翻译：一种制备环氧乙烷化合物的方法，该方法包括：（i）氧化烷基芳基以获得包含烷基芳基氢过氧化物的流，（ii）使步骤（i）中获得的烷基芳基氢过氧化物的至少一部分与烯烃在获得包含环氧乙烷化合物和烷基芳基羟基的产物流的催化剂，（iii）任选地使步骤（i）中获得的烷基芳基氢过氧化物的一部分反应以获得包含（a）苯酚和（b）酮和/或醛，和（c）任选的副产物，（iv）从步骤（ii）的产物流中分离环氧乙烷化合物以获得（a）残余产物流和（b）环氧乙烷，和（v）使至少一部分的剩余产物流与氢气反应以获得烷基芳基，其中至少一部分所述烷基芳基被再循环到步骤（i）。

3. 发明授权

US07358411B2 Hydrocracking of diphenylalkanes 有权
标题翻译：二苯基烷烃加氢裂化
公开(公告)号：US07358411B2
公开(公告)日：2008-04-15
申请号：US10872703
申请日：2004-06-21
申请人： Brendan Dermot Murray , Garo Garbis Vaporciyan
发明人： Brendan Dermot Murray , Garo Garbis Vaporciyan
IPC分类号： C07C4/26
CPC分类号： C07C4/24 , C07C2521/08 , C07C2521/12 , C07C2523/40 , C07C2523/44 , C07C2523/72 , C07C2523/74 , C07C2529/064 , C07C2529/22 , Y02P20/127 , C07C15/085
摘要： The invention relates to a hydrocracking process involving the steps of reacting a diphenyl alkane having a formulation of R1R2C(Ph)-(C)n(H)m-C(Ph)R3R4 with hydrogen using a catalyst containing a metal selected from the group consisting of Group IB and Group VIII metal compounds, preferably on an acidic support, to produce alkylbenzene(s) having a structure of R1R2C(Ph)R5 and R6(Ph)CR3R4; wherein the total number of carbon atoms for R5 and R6 is equal to n; wherein R1, R2, R3, R4 each is a H or a hydrocarbon group having 1-10 carbon atoms.
摘要翻译：本发明涉及一种加氢裂化方法，其涉及使用含有选自以下的金属的催化剂使具有R1R2C（Ph） - （C）n（H）mC（Ph）R3R4的配方的二苯基烷烃与氢气反应 IB族和VIII族金属化合物，优选在酸性载体上，以产生具有R 1 R 2 C（Ph）R 5和R 6（Ph）CR 3 R 4结构的烷基苯; 其中R5和R6的碳原子总数等于n; 其中R1，R2，R3，R4各自为H或具有1-10个碳原子的烃基。

4. 发明授权

US07189886B2 Process for producing alkylbenzene 有权
标题翻译：生产烷基苯的方法
公开(公告)号：US07189886B2
公开(公告)日：2007-03-13
申请号：US10880072
申请日：2004-06-29
申请人： Brendan Dermot Murray , Garo Garbis Vaporciyan
发明人： Brendan Dermot Murray , Garo Garbis Vaporciyan
IPC分类号： C07C1/20
CPC分类号： C07C15/085 , C07C1/22 , C07C2523/40 , C07C2523/44 , C07C2523/72 , C07C2523/74 , C07C2529/22 , Y02P20/127 , Y10S203/06
摘要： A process for producing an alkylbenzene from an alkylphenyl alcohol involving the steps of: (a) feeding a feed stream containing alkylphenyl a reactor having a catalytic distillation zone; and, (b) concurrently in the reactor (i) contacting the feed stream containing alkylphenyl alcohol with hydrogen in the catalytic distillation zone to convert alkylphenyl alcohol to alkylbenzene over a catalyst containing Group VIII or a Group IB metal; and, (ii) separating alkylbenzene from the reaction mixture by fractional distillation to produce an overhead stream containing alkylbenzene having a reduced concentration of alkylphenyl alcohol than the feed stream from the distillation column reactor. Examples of the alkylphenyl alcohol include cumyl alcohol, phenyl ethyl alcohol, or di(2-hydroxyl 2-propyl)benzene, and that for the alkylbenzene include cumene and di-ethyl benzene, or di(2-hydroxyl-2-propyl)benzene.
摘要翻译：包括以下步骤生产烷基苯的方法：（a）将含有烷基苯基的进料流输送到具有催化蒸馏区的反应器; 和（b）在反应器中同时（i）在催化蒸馏区中使含有烷基苯基醇的进料流与氢气接触，以使烷基苯醇在含有VIII族或IB族金属的催化剂上转化为烷基苯; 和（ii）通过分馏从反应混合物中分离出烷基苯，以产生含有烷基苯醇浓度低于来自蒸馏塔反应器的进料流的烷基苯的塔顶液流。烷基苯醇的实例包括枯基醇，苯基乙醇或二（2-羟基-2-丙基）苯，对于烷基苯包括枯烯和二乙基苯，或二（2-羟基-2-丙基）苯。

5. 发明申请

US20110113958A1 METHOD OF MAKING A HIGH-PERFORMANCE SUPPORTED GAS SEPARATION MOLECULAR SIEVE MEMBRANE USING A SHORTENED CRYSTALLIZATION TIME 失效
标题翻译：使用短时间结晶时间制备高性能支持气体分离分子筛膜的方法
公开(公告)号：US20110113958A1
公开(公告)日：2011-05-19
申请号：US12936795
申请日：2009-05-15
申请人： Moises Abraham Carreon , Zaida Diaz , John Lucien Falconer , Hans Heinrich Funke , Shiguang Li , Brendan Dermot Murray , Richard Daniel Noble , Paul Jason Williams
发明人： Moises Abraham Carreon , Zaida Diaz , John Lucien Falconer , Hans Heinrich Funke , Shiguang Li , Brendan Dermot Murray , Richard Daniel Noble , Paul Jason Williams
IPC分类号： B01D53/22 , B05D5/00
CPC分类号： B01D71/028 , B01D53/22 , B01D53/228 , B01D63/06 , B01D67/0051 , B01D67/0083 , B01D69/105 , B01D2256/22 , B01D2256/24 , B01D2257/504 , B01D2257/7022 , B01D2323/12 , Y02C10/10
摘要： A method of making a supported gas separation molecular sieve membrane. In this method a porous support, which is preferably pretreated, is contacted with a molecular sieve synthesis mixture under hydrothermal synthesis conditions. The contacting step is conducted for a shortened crystallization time period. The resulting coated porous support is calcined to yield the supported gas separation molecular sieve membrane having particularly good gas separation characteristics.
摘要翻译：制备负载型气体分离分子筛膜的方法。在该方法中，优选预处理的多孔载体在水热合成条件下与分子筛合成混合物接触。接触步骤进行缩短的结晶时间段。将得到的涂覆的多孔载体煅烧，得到具有特别好的气体分离特性的负载气体分离分子筛膜。

6. 发明授权

US07462752B2 Process to convert linear alkanes into alpha olefins 失效
标题翻译：将线性烷烃转化为α-烯烃的方法
公开(公告)号：US07462752B2
公开(公告)日：2008-12-09
申请号：US11109551
申请日：2005-04-19
申请人： Howard Lam-Ho Fong , Lizbeth Olivia Cisneros Trevino , Brendan Dermot Murray , Manuel Luis Cano
发明人： Howard Lam-Ho Fong , Lizbeth Olivia Cisneros Trevino , Brendan Dermot Murray , Manuel Luis Cano
IPC分类号： C07C1/26
CPC分类号： C07C29/124 , C07C1/30 , C07C11/02 , C07C17/10 , C07C17/358 , C07C17/37 , C07C2521/10 , C07C2521/14 , C07C2523/14 , C07C2523/44 , C07C2523/745 , C07C2523/78 , C07C19/075 , C07C19/01 , C07C31/125
摘要： This invention provides for a process to convert branched or linear alkanes to branched or linear alpha olefins (AO) of the same carbon number. The process comprises the steps of: a) halogenating linear alkanes, branched alkanes, or a mixture of linear and branched alkane to produce a mixture containing primary mono-haloalkanes and hydrogen halide; b) separating the hydrogen halide from the mixture and optionally neutralizing it with a metal oxide to produce a partially halogenated metal oxide and/or metal halide which may be regenerated; c) separating the primary mono-haloalkanes from the mixture; d) reacting the separated primary mono-haloalkanes with a metal oxide to produce a mixture of products that contains alpha olefins, unconverted primary mono-haloalkanes, possibly other reaction products, and a partially halogenated metal oxide and/or metal halide which may be regenerated; e) regenerating the partially halogenated metal oxide and/or metal halide to halogen and/or acid and a metal oxide (such as Cl2) for recycle by reaction with air or oxygen ; and f) removing the unreacted primary mono-haloalkane from the reaction mixture and then purifying the alpha olefin.
摘要翻译：本发明提供将支链或直链烷烃转化为相同碳数的支链或直链α-烯烃（AO）的方法。该方法包括以下步骤：a）将直链烷烃，支链烷烃或直链和支链烷烃的混合物卤化以产生含有主要单卤代烷烃和卤化氢的混合物; b）从混合物中分离卤化氢并任选地用金属氧化物中和它以产生可再生的部分卤化的金属氧化物和/或金属卤化物; c）从混合物中分离初级单卤代烷烃; d）使分离的初级单卤代烷烃与金属氧化物反应以产生含有α-烯烃，未转化的初级单卤代烷烃，可能的其它反应产物和可再生的部分卤化的金属氧化物和/或金属卤化物的产物的混合物 ; e）将部分卤化的金属氧化物和/或金属卤化物再生成卤素和/或酸和金属氧化物（例如Cl 2），以通过与空气或氧气反应再循环; 和f）从反应混合物中除去未反应的主要单卤代烷烃，然后纯化α-烯烃。

7. 发明授权

US07348462B2 Process for preparing branched olefins from a paraffinic wax 有权
标题翻译：从链烷烃蜡制备支链烯烃的方法
公开(公告)号：US07348462B2
公开(公告)日：2008-03-25
申请号：US10789115
申请日：2004-02-27
申请人： Laurent Alain Michel Fenouil , Brendan Dermot Murray , Paul Marie Ayoub
发明人： Laurent Alain Michel Fenouil , Brendan Dermot Murray , Paul Marie Ayoub
IPC分类号： C10L5/00 , C10L1/16 , C10M101/02 , C10M107/00 , C10M143/00 , C10M165/00 , C10M167/00 , C10M169/00 , C10M171/00
CPC分类号： C10G45/00 , C10G65/043 , C10G69/123 , C10G2300/1085 , C10G2300/1096 , C10G2400/22 , C10G2400/30
摘要： A process for preparing branched alkyl aromatic hydrocarbons, which process comprises contacting branched olefins with an aromatic hydrocarbon under alkylating conditions, which branched olefins have been obtained by a process which comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition has been obtained by hydrocracking and hydroisomerization of a paraffinic wax and which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.5 and the branching comprising methyl and optionally ethyl branches; a process for preparing (branched-alkyl)arylsulfonates, comprising sulfonating branched alkyl aromatic hydrocarbons which branched alkyl aromatic hydrocarbons have been prepared by the said process for preparing branched alkyl aromatic hydrocarbons; and branched alkyl aromatic hydrocarbon compositions and (branched-alkyl)arylsulfonate compositions which are obtainable by the processes so defined.
摘要翻译：一种制备支链烷基芳烃的方法，该方法包括在烷基化条件下使支链烯烃与芳族烃接触，该支链烯烃已经通过包括使异链烷烃组合物在合适的催化剂上脱氢的方法获得，该催化剂已经通过加氢裂化获得了异链烷烃组合物和链烷烃蜡的加氢异构化，并且所述异链烷烃组合物包含碳数为7至35的链烷烃，其中至少部分分子的链烷烃是支链的，每个链烷烃分子的平均支链数为至少0.5 并且支链包含甲基和任选的乙基支链; 一种制备（支链 - 烷基）芳基磺酸盐的方法，包括磺化支化烷基芳烃，其中支链烷基芳烃是通过所述制备支链烷基芳烃的方法制备的; 和支链烷基芳烃组合物和（支链 - 烷基）芳基磺酸盐组合物，其可通过如此定义的方法获得。

8. 发明授权

US06747165B2 Process for preparing (branched-alkyl) arylsulfonates and a (branched-alkyl) arylsulfonate composition 失效
公开(公告)号：US06747165B2
公开(公告)日：2004-06-08
申请号：US10075318
申请日：2002-02-14
申请人： Laurent Alain Michel Fenouil , Brendan Dermot Murray , Paul Marie Ayoub
发明人： Laurent Alain Michel Fenouil , Brendan Dermot Murray , Paul Marie Ayoub
IPC分类号： C07C30300
CPC分类号： C10G45/00 , C10G65/043 , C10G69/123 , C10G2300/1085 , C10G2300/1096 , C10G2400/22 , C10G2400/30
摘要： A process for preparing branched alkyl aromatic hydrocarbons, which process comprises contacting branched olefins with an aromatic hydrocarbon under alkylating conditions, which branched olefins have been obtained by a process which comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition has been obtained by hydrocracking and hydroisomerization of a paraffinic wax and which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.5 and the branching comprising methyl and optionally ethyl branches; a process for preparing (branched-alkyl)arylsulfonates, comprising sulfonating branched alkyl aromatic hydrocarbons which branched alkyl aromatic hydrocarbons have been prepared by the said process for preparing branched alkyl aromatic hydrocarbons; and branched alkyl aromatic hydrocarbon compositions and (branched-alkyl)arylsulfonate compositions which are obtainable by the processes so defined.

9. 发明授权

US06492568B1 Removal of phosphorus-containing compounds from an olefin feedstock 失效
标题翻译：从烯烃原料中除去含磷化合物
公开(公告)号：US06492568B1
公开(公告)日：2002-12-10
申请号：US09566463
申请日：2000-05-08
申请人： Brendan Dermot Murray , Zaida Diaz , Glenn Charles Komplin
发明人： Brendan Dermot Murray , Zaida Diaz , Glenn Charles Komplin
IPC分类号： C07C2720
CPC分类号： C07C7/14841 , C07C29/16 , C07C11/02 , C07C31/125
摘要： The invention pertains to a process of removing phosphorus-containing impurities from an olefin stream using a sorbent comprising a metal. The olefin stream preferably comprises primarily olefins having at least 6 carbon atoms.
摘要翻译：本发明涉及使用包含金属的吸附剂从烯烃流中除去含磷杂质的方法。烯烃流优选主要包含具有至少6个碳原子的烯烃。

10. 发明授权

US5648585A Process for isomerizing linear olefins to isoolefins 失效
标题翻译：将线性烯烃异构化成异烯烃的方法
公开(公告)号：US5648585A
公开(公告)日：1997-07-15
申请号：US175010
申请日：1993-12-29
申请人： Brendan Dermot Murray , Bruce Herman Charles Winquist , Donald Henry Powers , Jon Barin Wise , Richard Brian Halsey
发明人： Brendan Dermot Murray , Bruce Herman Charles Winquist , Donald Henry Powers , Jon Barin Wise , Richard Brian Halsey
IPC分类号： B01J29/67 , A61K8/02 , A61K8/19 , A61K8/23 , A61K8/30 , A61K8/365 , A61K8/41 , A61K8/42 , A61K8/55 , A61K8/60 , A61K8/64 , A61K8/72 , A61K8/73 , A61K8/88 , A61K8/89 , A61K8/92 , A61K8/97 , A61K8/98 , A61K31/715 , A61P17/02 , A61Q5/02 , A61Q5/12 , A61Q19/00 , A61Q19/08 , A61Q19/10 , B01J29/66 , B01J29/90 , C07C5/27 , C07C11/02 , C07C11/08 , C08B37/08 , C07C5/22
CPC分类号： A61K8/736 , A61Q19/00 , B01J29/90 , C07C5/2775 , C08B37/003 , A61K2800/5426 , A61Q19/08 , Y02P20/584
摘要： This invention relates to a process in which a linear olefin is converted under isomerizing conditions to its corresponding methyl branched isoolefin by contact at a temperature of from 200.degree. C. to 650.degree. C. with an isomerizing catalyst comprising (i) at least one zeolite having only in one dimension a pore structure having a pore size small enough to retard by-product dimerization and coke formation and large enough to permit entry of the linear olefin and allow formation of the methyl branched isoolefin, (ii) an alumina binder and (iii) up to about 15% by weight of coke oxidation-promoting metal. After a period of operation, when sufficient coke has deposited on the catalyst in an amount to significantly reduce the activity of the catalyst, the catalyst is stripped of hydrocarbon and then contacted at elevated temperature with an oxygen-containing gas for a sufficient time to burn off the coke, i.e., to regenerate the catalyst at a temperature of less than about 565.degree. C. After regeneration, the isomerization process is continued. The use of palladium and/or platinum as the coke oxidation-promoting metal is particularly desirable.
摘要翻译：本发明涉及一种方法，其中线性烯烃在异构化条件下通过在200℃至650℃的温度下与异构化催化剂接触而转化成相应的甲基支链异烯烃，所述异构化催化剂包含（i）至少一种沸石仅在一个维度上具有孔径足够小以阻止副产物二聚和焦炭形成并且足够大以允许线性烯烃进入并允许形成甲基支链异烯烃的孔结构，（ii）氧化铝粘合剂和（ iii）高达约15重量％的焦炭氧化促进金属。经过一段时间的操作后，当催化剂上沉积足够的焦炭以显着降低催化剂活性的量时，将催化剂汽提出烃，然后在高温下与含氧气体接触足够的时间燃烧即，在低于约565℃的温度下再生催化剂。再生后，继续进行异构化处理。使用钯和/或铂作为焦炭氧化促进金属是特别理想的。

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