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    • 2. 发明授权
    • Propylene copolymers containing styrene units
    • 含苯乙烯单元的丙烯共聚物
    • US06617410B2
    • 2003-09-09
    • US10068361
    • 2002-02-06
    • Leone OlivaGaetano GuerraLucia CaporasoLorella IzzoLuigi Resconi
    • Leone OlivaGaetano GuerraLucia CaporasoLorella IzzoLuigi Resconi
    • C08F21006
    • C08F210/06C08F210/16C08F212/08C08F2500/15C08F2500/20
    • Isotactic-polypropylene-based copolymers having a homogenous distribution of recurring units of formula (1): where R is a hydrogen, halide radical or a hydrocarbyl radical optionally containing an atom selected from oxygen, nitrogen, sulphur, phosphorus and silicon, and n is an integer ranging from 1 to 3; said copolymer having a 13C-NMR spectrum wherein the resonance signals attributed to the links between different monomeric units fall around 30, 34, 35, 45 and 47 ppm and present intensities at least two times higher than the resonance signals attributed to styrene—styrene sequences around 41 ppm and 44-46 ppm; a process for preparing said copolymers carried out in the presence of homogeneous catalytic systems comprising a metallocene compound and a cocatalyst; functionalized copolymers obtained from said isotactic-polypropylene-based copolymers; and graft copolymers comprising said isotactic-polypropylene-based copolymers as backbones.
    • 具有式(1)的重复单元的均匀分布的全同立构聚丙烯基共聚物:其中R是氢,卤化物基团或任选地含有选自氧,氮,硫,磷和硅的原子的烃基,n是 整数范围从1到3; 所述共聚物具有13 C-NMR光谱,其中归因于不同单体单元之间的连接的共振信号落在30,34,35,45和47ppm附近,并且呈现比归因于苯乙烯 - 苯乙烯序列的共振信号高至少两倍的强度 约41ppm和44-46ppm; 在包含金属茂化合物和助催化剂的均相催化体系存在下进行所述共聚物的方法; 由所述全同立构聚丙烯基共聚物获得的官能化共聚物; 和包含所述全同立构聚丙烯基共聚物作为骨架的接枝共聚物。