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1. 发明授权

US3307544A Surgical pressure-sensitive adhesive sheet with n-tert-butylacrylamide copolymer adhesive 失效
标题翻译：具有正丁基丙烯酰胺共聚物粘合剂的手术压敏粘合片
公开(公告)号：US3307544A
公开(公告)日：1967-03-07
申请号：US30781463
申请日：1963-09-10
申请人： JOHNSON & JOHNSON , GOODRICH CO B F
发明人： GANDER ROBERT J , BROWN HAROLD P
IPC分类号： A61L15/58 , C08F20/52 , C08F20/54 , C08F220/18 , C09J7/02
CPC分类号： A61L15/58 , C08F20/52 , C08F20/54 , C08F220/18 , C09J7/22 , C09J7/38 , C09J7/385 , Y10T428/2887 , Y10T428/2891 , C08L33/26 , C08L33/06 , C08L33/02
摘要： Coating compositions comprise solutions of a copolymer of 65 to 85 parts by weight of an alkyl acrylate having an alkyl group of at least 6 carbon atoms, and 35 to 15 parts by weight of N-tertiary butylacrylamide, the copolymer having a William's plasticity of 1.3 to 3.0 mm. Specified acrylates are 2-ethylhexyl, heptyl, octyl, nonyl and decyl acrylates. In the example the copolymer is prepared by polymerizing 2-ethylhexyl acrylate and N-tert.butylacrylamide in ethyl acetate at 80 DEG C. in the presence of benzoyl peroxide.ALSO:Adhesive tapes, bandages, corn-pads and sheets comprise a flexible backing material coated with an adhesive comprising a co-polymer of 65 to 85 parts by weight of an alkyl acrylate having an alkyl group of at least 6 carbon atoms, and 35 to 15 parts by weight of N-tertiary butylacrylamide, the copolymer having a Williams plasticity of 1.3 to 3.0 mm. Specified acrylates are 2- ethylhexyl, heptyl, octyl, nonyl and decyl acrylates. The backing material may be polyethylene film or a non-woven fabric/polyethylene film laminate. The adhesive is applied in solution by doctor blade and the solvent evaporated off.ALSO:Adhesive tapes, bandages, corn-pads and sheets comprise a flexible backing material coated with an adhesive comprising a co-polymer of 65 to 85 parts by weight of an alkyl acrylate having an alkyl group of at least 6 carbon atoms, and 35 to 15 parts by weight of N-tertiary butylacrylamide, the copolymer having a Williams plasticity of 1.3 to 3.0 mm. Specified acrylates are 2-ethylhexyl, heptyl, octyl, nonyl and decyl acrylates. The backing material may be polyethylene film or a non-woven fabric/polyethylene film laminate. The adhesive is applied in solution by doctor blade and the solvent evaporated off.

2. 发明授权

US2710292A Preparation of plastic condensable synthetic rubbers and subsequent elastocondensation thereof 失效
标题翻译：塑料可冷凝合成橡胶的制备及其随后的弹性缩合
公开(公告)号：US2710292A
公开(公告)日：1955-06-07
申请号：US19352350
申请日：1950-11-01
申请人： GOODRICH CO B F
发明人： BROWN HAROLD P
IPC分类号： C08C19/34 , C08C19/36 , C08L13/00
CPC分类号： C08L13/00 , C08C19/34 , C08C19/36 , Y10S260/31

3. 发明授权

US2669550A Method of elasticizing plastic carboxyl containing synthetic polymeric rubbery materials and elastic products produced thereby 失效
标题翻译：弹性塑料含羧基的合成聚合橡胶材料和由此生产的弹性产品的方法
公开(公告)号：US2669550A
公开(公告)日：1954-02-16
申请号：US19749550
申请日：1950-11-24
申请人： GOODRICH CO B F
发明人： BROWN HAROLD P
IPC分类号： C08C19/36 , C08K5/09 , C08K5/37
CPC分类号： C08K5/09 , C08C19/36 , C08K5/37 , Y10S260/31 , C08L13/00

4. 发明授权

US2981721A Method of elasticizing plastic carboxylcontaining synthetic rubbery polymeric materials and elastic products produced thereby 失效
标题翻译：弹性塑料含羧基的合成橡胶聚合物材料和由此生产的弹性产品的方法
公开(公告)号：US2981721A
公开(公告)日：1961-04-25
申请号：US61294256
申请日：1956-10-01
申请人： GOODRICH CO B F
发明人： BROWN HAROLD P
IPC分类号： C08K5/19
CPC分类号： C08K5/19 , Y10S260/31 , C08L13/00

5. 发明授权

US2858281A Insoluble, acid and alkali-resistant carboxylic polymers 失效
标题翻译：不溶性，耐酸和耐碱的羧酸聚合物
公开(公告)号：US2858281A
公开(公告)日：1958-10-28
申请号：US40565954
申请日：1954-01-22
申请人： GOODRICH CO B F
发明人： BAUMAN RICHARD G , BROWN HAROLD P
IPC分类号： C08F22/00 , C08F36/20 , C08F279/02
CPC分类号： C08F279/02 , C08F22/00 , C08F36/20 , Y10S526/93

6. 发明授权

US2698318A Rubbery interpolymers of butadiene-1, 3 hydrocarbons with polyunsaturated carboxylic acids 失效
标题翻译：丁二烯-1,3烃与多不饱和羧酸的橡胶互聚物
公开(公告)号：US2698318A
公开(公告)日：1954-12-28
申请号：US18865150
申请日：1950-10-05
申请人： GOODRICH CO B F
发明人： BROWN HAROLD P
IPC分类号： C08F236/04
CPC分类号： C08F236/04 , Y10S260/31 , Y10S526/911 , Y10S526/915 , Y10S526/938

7. 发明授权

US2937164A Composition consisting of the reaction product of a linear synthetic polymer and a monocarbodiimide and process for crosslinking 失效
标题翻译：由线性合成聚合物和单碳二亚胺的反应产物组成的组合物和交联方法
公开(公告)号：US2937164A
公开(公告)日：1960-05-17
申请号：US69836457
申请日：1957-11-25
申请人： GOODRICH CO B F
发明人： BROWN HAROLD P , JANSEN JACOB E , SCHOLLENBERGER CHARLES S
IPC分类号： C08C19/22 , C08F236/04
CPC分类号： C08C19/22 , C08F236/04 , Y10S260/31

8. 发明授权

US2566821A Polymerization of butadiene-1,3 hydrocarbons in aqueous emulsion in the presence of a ferricyanide, a diazomercapto compound, and an alcohol 失效
标题翻译：在铁氰化物，重氮化合物巯基化合物和醇的存在下，水性乳液中丁二烯-1,3-烃的聚合
公开(公告)号：US2566821A
公开(公告)日：1951-09-04
申请号：US78956047
申请日：1947-12-03
申请人： GOODRICH CO B F
发明人： BROWN HAROLD P , HOUSTON ROBERT J
IPC分类号： C08F36/04
CPC分类号： C08F36/04 , C08F4/04

9. 发明授权

US3100760A Polymeric adhesives and method of preparation 失效
标题翻译：聚合物粘合剂及其制备方法
公开(公告)号：US3100760A
公开(公告)日：1963-08-13
申请号：US6139360
申请日：1960-10-10
申请人： GOODRICH CO B F
发明人： BROWN HAROLD P , WALTERS MAXIE R , ANDERSON JOHN F
IPC分类号： C08F220/18 , C09J133/08
CPC分类号： C09J133/08 , C08F220/18 , C08L2666/28 , Y10T428/264 , Y10T428/265 , Y10T428/266 , Y10T428/269 , Y10T428/31544 , Y10T428/31649 , Y10T428/31699 , Y10T428/31797 , Y10T428/31833 , Y10T428/31906 , Y10T428/31928 , Y10T428/31935
摘要： A copolymer of at least one ester of a primary monohydric alcohol and acrylic acid and at least one ester of acrylic acid and a monohydroxy compound having the OH groups on a C atom which is free of H. The copolymer may contain 20-80% of at least one monomer, CH2=CHCOOCH2R, where R is an alkyl group having from 3-9 C atoms, e.g. n- or isobutyl, n- or iso-amyl acrylates or the acrylate esters of the monohyric primary hexyl, heptyl,octyl, nonyl or decyl alcohols; and 80-20% of at least one monomer, CH2=CHCOOR1, where R1 is an aromatic hydrocarbon group having 6-10 C atoms, e.g. phenyl, o-, m- or pcresyl or a - or b -naphthyl acrylates; or monomer, where R2, R3 and R4 are aliphatic hydrocarbon groups having from 1-7 C atoms and whose total C atoms is not more than 10, e.g. t-butyl or t-amyl acrylate or the acrylate esters of the monohydric t-hexyl, t-heptyl, t-nonyl or t-decyl alcohols. The copolymers may be 40-55% n-butyl and 45-60% t-butyl acrylates; 50-70% 2-ethylhexyl and 30-50% t-butyl acrylates; 50-80% n-butyl and 20-50% t-amyl acrylates; 20-30% a - or b -naphthyl and 70-80% n-butyl acrylates; and 40-50% phenyl and 50-60% n-butyl acrylates. The copolymers may be produced by copolymerizing the acrylate esters in a solvent with free radical initiator at 0 DEG -100 DEG C., or by using mass or emulsion polymerization. The solvent may be toluene, xylene, mesitylene, benzene, bromo-trichloromethane, CHCl3, methyl ethyl ketone, methyl isobutyl ketone, butane, pentane, hexane, heptane, ethyl or propyl acetate, ethyl propionate or mixtures thereof. The radical initiator, e.g. 0,1-5 parts, may be peroxides, e.g. benzoyl hydroperoxides, acyl peroxides, azo compounds and redox initiators, or the free radicals may be generated by radiant energy, e.g. U.V. light, g - or X-rays. The copolymers have molecular weights corresponding to dilute solution viscosities of 0,25-1,75. In an example n-butyl/t-butyl acrylate copolymer was prepared at 50 DEG C. in O2-free N2 using methyl ethyl ketone and azobisisobutyronitrile. Specification 779,687 is referred to.

10. 发明授权

US2994632A Laminated compositions and method for their preparation 失效
标题翻译：复合组合物及其制备方法
公开(公告)号：US2994632A
公开(公告)日：1961-08-01
申请号：US71019058
申请日：1958-01-21
申请人： GOODRICH CO B F
发明人： BROWN HAROLD P , ANDERSON JOHN F
IPC分类号： B32B27/00
CPC分类号： B32B27/00 , Y10T428/266 , Y10T428/31544 , Y10T428/31699 , Y10T428/31797 , Y10T428/31833 , Y10T428/31906 , Y10T428/3192 , Y10T428/31928

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