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    • 7. 发明授权
    • Compositions curable by in situ generation of cations
    • 通过原位生成阳离子可固化的组合物
    • US4717440A
    • 1988-01-05
    • US821570
    • 1986-01-22
    • Kieran F. DrainDavid J. Dunn
    • Kieran F. DrainDavid J. Dunn
    • C08F4/06C08G59/68C08G85/00C08J3/24C09J5/04
    • C08G59/68C08G85/00C08J3/241C09J5/04
    • A two-part composition curable by contact of respective parts with one another, comprising: a first part comprising a cationically polymerizable material and a first latent curing component; and a second part comprising a cationically polymerizable material and a second latent curing component which is reactive with the first component to form cations which are curingly effective for the resin. A preferred class of cation species comprises carbenium ions derived from reaction of organic halide compounds, as the first component, with silver salts of non-nucleophilic anions, e.g., SbCl.sub.6.sup.-, SbCl.sub.3.sup.-, SbF.sub.6.sup.-, AsF.sub.6.sup.-, SnCl.sub.5.sup.-, PF.sub.6.sup.-, BF.sub.4.sup.-, CF.sub.3 SO.sub.3.sup.- and ClO.sub.4.sup.-, as the second component, The respective parts of the two-part composition may be applied to matable surfaces which then are contacted to effect rapid bonding cure of the composition.
    • 包括:第一部分,其包含阳离子可聚合材料和第一潜在固化组分,所述两部分组合物可通过相应部分彼此接触而固化; 以及第二部分,其包含阳离子可聚合材料和第二潜在固化组分,其与第一组分反应以形成对树脂具有固化效果的阳离子。 优选的一类阳离子种类包括衍生自作为第一组分的有机卤化物与非亲核阴离子的银盐的反应的碳鎓离子,例如SbCl 6 - ,SbCl 3 - ,SbF 6 - ,AsF 6 - ,SnCl 5 - ,PF 6 - ,BF4-,CF3SO3-和ClO4-作为第二组分。两部分组合物的相应部分可以施加到可接合的表面上,然后与其接触以实现组合物的快速粘合固化。