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1. 发明授权

US4788254A Curable polymer composition 失效
标题翻译：可固化的聚合物组成
公开(公告)号：US4788254A
公开(公告)日：1988-11-29
申请号：US75229
申请日：1987-07-13
申请人： Fumio Kawakubo , Sadao Yukimoto , Miyako Takanoo , Katsuhiko Isayama , Takahisa Iwahara
发明人： Fumio Kawakubo , Sadao Yukimoto , Miyako Takanoo , Katsuhiko Isayama , Takahisa Iwahara
IPC分类号： C08K5/54 , C08F8/00
CPC分类号： C08K5/54
摘要： A moisture curable polymer composition comprising (A) an organic polymer having at least one reactive silicone group in a molecule and (B) a compound having one silanol group in a molecule and/or a compound which reacts with water or moisture to form a compound having one silanol group in a molecule, which is cured with moisture to give an elastomeric material with improved tensile properties and surface characteristics.
摘要翻译：一种湿气固化聚合物组合物，其包含（A）在分子中具有至少一个反应性硅氧烷基团的有机聚合物和（B）在分子中具有一个硅烷醇基团的化合物和/或与水或水分反应以形成化合物的化合物在分子中具有一个硅烷醇基团，其被水分固化以得到具有改进的拉伸性能和表面特性的弹性体材料。

2. 发明授权

US4618656A Novel polymer and cured product of the same 失效
标题翻译：新型聚合物和固化产物相同
公开(公告)号：US4618656A
公开(公告)日：1986-10-21
申请号：US727295
申请日：1985-04-25
申请人： Fumio Kawakubo , Miyako Takanoo , Sadao Yukimoto , Katsuhiko Isayama
发明人： Fumio Kawakubo , Miyako Takanoo , Sadao Yukimoto , Katsuhiko Isayama
IPC分类号： C08F2/00 , C08F2/02 , C08F2/38 , C08F4/00 , C08F4/04 , C08F4/28 , C08F4/32 , C08F4/42 , C08F4/72 , C08F283/00 , C08F283/06 , C08G77/46 , C09J151/00 , C08L71/02
CPC分类号： C08F283/00 , C08F283/004
摘要： A polymer which is prepared by polymerizing at least one ethylenically unsaturated monomer in the presence of an organic polymer having at least one reactive silicone group in a molecule and a compound having at least two independent ethylenically unsaturated functional groups in a molecule by use of a radical polymerization initiator having a reactive silicone group and/or a chain transfer agent having a reactive silicone group, which is cured with moisture to give a product having improved properties such as tensile properties and weather resistance.
摘要翻译：通过在分子中具有至少一个反应性硅氧烷基团的有机聚合物和在分子中具有至少两个独立的烯属不饱和官能团的化合物的存在下使用至少一种烯属不饱和单体通过使用基团具有反应性硅氧烷基团的聚合引发剂和/或具有反应性硅氧烷基团的链转移剂，其用水分固化，得到具有改善的性能如拉伸性能和耐候性的产品。

3. 发明授权

US4687818A Polymer and pressure sensitive adhesive composition 失效
标题翻译：聚合物和压敏粘合剂组合物
公开(公告)号：US4687818A
公开(公告)日：1987-08-18
申请号：US759877
申请日：1985-07-29
申请人： Fumio Kawakubo , Miyako Takanoo , Sadao Yukimoto , Katsuhiko Isayama
发明人： Fumio Kawakubo , Miyako Takanoo , Sadao Yukimoto , Katsuhiko Isayama
IPC分类号： C08F291/00 , C08F283/06 , C08F290/06 , C08L57/00 , C08L71/02 , C08L83/12
CPC分类号： C08L57/00 , C08F290/062 , C08L71/02 , C08L83/12
摘要： A novel moisture-curable polymer useful as a pressure sensitive adhesive, a paint, a sealant, etc. obtained by polymerizing a polymerizable monomer in the presence of an organic polymer having at least one reactive silicon-containing functional group in the molecule on the average. A pressure sensitive adhesive composition having excellent adhesive property as well as excellent initial tackiness, heat resistance, workability and weather resistance comprising a polymer obtained by polymerizing a polymerizable monomer in the presence of (A) an organic polymer having at least one reactive silicon functional group in the molecule on the average and/or (B) an organic polymer having at least one olefin group in the molecule on the average. The composition is also useful as a sealant, a coating material, a packing, an electric insulation, a corrosionproof, a masking and a surface-protection.
摘要翻译：在分子中具有至少一个反应性含硅官能团的有机聚合物的存在下，通过使可聚合单体聚合而获得的用作压敏粘合剂，油漆，密封剂等的新型湿气固化性聚合物平均。一种具有优异的粘合性能以及优异的初始粘合性，耐热性，可加工性和耐候性的压敏粘合剂组合物，其包含通过在（A）具有至少一个反应性硅官能团的有机聚合物存在下使可聚合单体聚合而获得的聚合物在平均分子中和/或（B）平均分子中具有至少一个烯基的有机聚合物。该组合物还可用作密封剂，涂料，包装，电绝缘，防腐，掩蔽和表面保护。

4. 发明授权

US4618653A Novel polymer and cured product of the same 失效
标题翻译：新型聚合物和固化产物相同
公开(公告)号：US4618653A
公开(公告)日：1986-10-21
申请号：US727296
申请日：1985-04-25
申请人： Fumio Kawakubo , Miyako Takanoo , Sadao Yukimoto , Katsuhiko Isayama
发明人： Fumio Kawakubo , Miyako Takanoo , Sadao Yukimoto , Katsuhiko Isayama
IPC分类号： C08F2/00 , C08F2/02 , C08F2/38 , C08F4/00 , C08F4/04 , C08F4/28 , C08F4/32 , C08F4/42 , C08F4/72 , C08F283/00 , C08F283/06 , C08F283/12 , C08F290/12 , C08G77/46 , C08L71/02
CPC分类号： C08F290/12 , C08F283/004 , C08F283/124
摘要： A polymer which is prepared by polymerizing at least one polymerizable monomer in the presence of an organic polymer having a reactive silicone group and a polymerizable ethylenically unsaturated group in a molecule, the total number of the silicone group and the unsaturated group being on the average not less than 1.1 and the number of the ethylenically unsaturated group being on the average not less than 0.1 by use of a radical polymerization initiator having a reactive silicone group and/or a chain transfer agent having a reactive silicone group, which is cured with moisture to give a product having improved properties such as tensile properties and weather resistance.
摘要翻译：通过在分子中具有反应性硅氧烷基和可聚合的烯键式不饱和基团的有机聚合物的存在下使至少一种可聚合单体聚合制备的聚合物，硅氧烷基和不饱和基团的总数平均不是通过使用具有反应性硅氧烷基团的自由基聚合引发剂和/或具有反应性硅氧烷基团的链转移剂，烯键式不饱和基团的数量平均不小于0.1，其通过水分固化得到具有改善的性能如拉伸性能和耐候性的产品。

5. 发明授权

US5063270A Curable composition 失效
标题翻译：可固化组合物
公开(公告)号：US5063270A
公开(公告)日：1991-11-05
申请号：US362776
申请日：1989-06-07
申请人： Sadao Yukimoto , Toshifumi Hirose , Hiroshi Wakabayashi , Katsuhiko Isayama
发明人： Sadao Yukimoto , Toshifumi Hirose , Hiroshi Wakabayashi , Katsuhiko Isayama
IPC分类号： C08G77/46 , C08J7/04 , C08K5/00 , C08K5/01 , C08K5/54 , C08L9/00 , C08L21/00 , C08L25/06 , C08L67/00 , C08L71/00 , C08L71/02 , C08L101/00
CPC分类号： C08J7/047 , C08K5/0016 , C08K5/54 , C08L71/02 , C08J2371/02 , C08J2467/00 , Y10T428/31663
摘要： A curable composition. The composition contains(A) 100 parts of an oxyalkylene polymer having at least one silicon-containing group containing a hydroxyl group and/or hydrolyzable group bound to a silicon atom and capable of crosslinking through the formation of a siloxane bond;(B) 1 to 150 parts of a high molecular weight and/or high viscosity plasticizer; and(c) 0.1 to 20 parts of a compound having one silanol group per molecular and/or a compound capable of reacting with moisture to thereby form one silanol group per molecule. When an alkyd paint is applied onto the surface of a cured material formed from this curable composition excellent coating properties can be obtained, the other physical characteristics of the cured material being maintained.

6. 发明授权

US5011900A Curable composition 失效
标题翻译：可固化组合物
公开(公告)号：US5011900A
公开(公告)日：1991-04-30
申请号：US362714
申请日：1989-06-07
申请人： Sadao Yukimoto , Toshifumi Hirose , Hiroshi Wakabayashi , Katsuhiko Isayama
发明人： Sadao Yukimoto , Toshifumi Hirose , Hiroshi Wakabayashi , Katsuhiko Isayama
IPC分类号： C08K5/00 , C08K5/01 , C08K5/54 , C08L33/00 , C08L33/04 , C08L47/00 , C08L63/00 , C08L63/10 , C08L67/08 , C08L71/02 , C08L83/02 , C08L83/10 , C08L91/00 , C08L101/02
CPC分类号： C08K5/54
摘要： A curable composition. The composition comprises (A) 100 parts by weight of an oxyalkylene polymer having at least one silicon-containing group in which a hydroxy group and/or hydrolyzable group is or are bonded to the silicon atom, said polymer being crosslinkable by formation of a siloxane bond, (B) from 0.1 to 20 parts by weight of a compound having one silanol group per molecule and/or a compound capable of forming a compound having one silanol group per molecule on reacting with moisture, and (C) from 0.1 to 20 parts by weight of a compound having an air oxidative curing unsaturated group. The composition provides a cured product which has low modulus and resistance to dust adhesion and on which an alkyd coating shows excellent coating properties.

7. 发明授权

US4902575A Method of applying alkyd paints to oxyalkylene polymers having a reactive silicon group 失效
标题翻译：将醇酸漆施用于具有反应性硅基团的氧化烯聚合物的方法
公开(公告)号：US4902575A
公开(公告)日：1990-02-20
申请号：US288177
申请日：1988-12-22
申请人： Sadao Yukimoto , Toshifumi Hirose , Katsuhiko Isayama
发明人： Sadao Yukimoto , Toshifumi Hirose , Katsuhiko Isayama
IPC分类号： B05D7/24 , C08G65/336 , C08J7/04 , C08L71/02
CPC分类号： C08J7/047 , C08G65/336 , C08L71/02 , C08J2371/02 , C08J2467/00 , Y10T428/31663 , Y10T428/31786
摘要： A method of coating the cured product of an oxyalkylene polymer having reactive silicon groups with an alkyd paint. The oxyalkylene polymer is combined with a high-molecular weight plasticizer and the composition is cured and the cured product coated with an alkyd paint.

8. 发明授权

US5051463A Curable polymer composition 失效
公开(公告)号：US5051463A
公开(公告)日：1991-09-24
申请号：US417133
申请日：1989-10-04
申请人： Sadao Yukimoto , Hiroshi Wakabayashi , Katsuhiko Isayama
发明人： Sadao Yukimoto , Hiroshi Wakabayashi , Katsuhiko Isayama
IPC分类号： C08L15/00 , C08L7/00 , C08L21/00 , C08L27/06 , C08L33/00 , C08L33/04 , C08L71/02 , C08L101/00 , C08L101/10
CPC分类号： C08L27/06 , C08L101/10 , C08L71/02
摘要： A curable resin composition comprising:(A) 100 parts by weight of a rubbery organic polymer having at least one silicon-containing group to the silicon atom of which a hydrolyzable group is bonded and which is cross linkable through formation of a siloxane bond in a molecule.(B) 10 to 500 parts by weight of a vinyl chloride base resin, and(C) 1 to 150 parts by weight of a polymeric plasticizer, which has improved storage stability and is easily cured in the presence of water.

9. 发明授权

US4837401A Curable polymer composition comprising organic polymer having silicon-contaiing reactive group 失效
标题翻译：包含具有含硅反应性基团的有机聚合物的可固化聚合物组合物
公开(公告)号：US4837401A
公开(公告)日：1989-06-06
申请号：US807842
申请日：1985-12-11
申请人： Toshifumi Hirose , Sadao Yukimoto , Katsuhiko Isayama
发明人： Toshifumi Hirose , Sadao Yukimoto , Katsuhiko Isayama
IPC分类号： C08L71/00 , C08F283/06 , C08G65/336 , C08K5/57 , C08L33/00 , C08L33/02 , C08L71/02 , C08L101/00 , C08L101/10
CPC分类号： C08F283/06 , C08G65/336 , C08K5/57
摘要： A curable polymer composition comprising(A) 100 parts by weight of an organic polymer having at least one silicon-containing reactive group of the formula: ##STR1## wherein R.sup.1 is, the same or different, a C.sub.1 -C.sub.20 monovalent hydrocarbon group or a triorganosiloxy group of the formula:(R').sub.3 SiO-- (II)in which R' is, the same or different, a C.sub.1 -C.sub.20 monovalent hydrocarbon group; X is a hydroxyl group or a hydrolyzable group provided that when the number of Xs in the group (I) is at least 2, Xs are the same or different; a is 0, 1, 2 or 3; b is 0, 1 or 2; and m is an integer of 1 to 18, and(B) 0.01 to 10 parts by weight of a curing catalyst selected from the compounds of the formulas: ##STR2## wherein Q is a C.sub.1 -C.sub.20 monovalent hydrocarbon group; and Z is, the same or different, a C.sub.1 -C.sub.20 monovalent hydrocarbon group or an organic group having a functional residue which can form a coordinate bond with Sn atom, which can be quickly cured and particularly useful as a pressure sensitive adhesive and a sealing material.
摘要翻译：一种可固化聚合物组合物，其包含（A）100重量份的具有至少一个下式的含硅反应性基团的有机聚合物：其中R1是相同或不同的C1-C20单价烃基团或下式的三有机甲硅烷氧基：（R'）3SiO-（II）其中R'相同或不同，为C1-C20单价烃基; X是羟基或可水解基团，条件是当组（I）中的X的数目至少为2时，Xs相同或不同; a是0,1,2或3; b为0,1或2; m为1〜18的整数，（B）0.01〜10重量份选自下式的化合物的固化催化剂：其中Q为C1（C1a）（IIIa） -C 20单价烃基; Z是相同或不同的具有可与Sn原子形成配位键的官能残基的C1-C20单价烃基或有机基团，其能够快速固化，并且特别可用作压敏粘合剂和密封材料。

10. 发明授权

US4983700A Curable polymer composition 失效
公开(公告)号：US4983700A
公开(公告)日：1991-01-08
申请号：US363855
申请日：1989-06-09
申请人： Sadao Yukimoto , Toshifumi Hirose , Hiroshi Wakabayashi , Katsuhiko Isayama
发明人： Sadao Yukimoto , Toshifumi Hirose , Hiroshi Wakabayashi , Katsuhiko Isayama
IPC分类号： C08K5/54 , C08G65/336 , C08L71/02
CPC分类号： C08G65/336 , C08L71/02 , Y10S528/901
摘要： A curable polymer composition comprising:(A) 100 parts by weight of an oxyalkylene base polymer having at least one silicon-containing group to the silicon atom of which a hydroxy group and/or a hydrolyzable group is bonded and which is cross linkable through formation of a siloxane bond,(B) 0.1 to 20 parts by weight of at least one compound selected from the group consisting of a compound having one silanol group in the molecule and a compound which, when reacted with moisture, generates a compound having one silanol group in the molecule,(C) 0.1 to 20 parts by weight of a compound having a silicon-containing group to the silicon atom of which two hydrolyzable groups are bonded and an amino group, and(D) 0.01 to 5 parts by weight of a compound having a silicon-containing group to the silicon atom of which three hydrolyzable groups are bonded and an amino group, which composition provides a cured material having low modulus, group bond strength and improved weather resistance of bond strength.

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