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    • 6. 发明授权
    • Non-aqueous electrolyte secondary cell
    • 非水电解质二次电池
    • US5601950A
    • 1997-02-11
    • US493464
    • 1995-06-22
    • Takayuki YamahiraYoshiaki Takeuchi
    • Takayuki YamahiraYoshiaki Takeuchi
    • H01M4/58H01M4/66H01M4/36H01M4/62
    • H01M4/587H01M4/661H01M4/663
    • A non-aqueous electrolyte secondary cell having a negative electrode, a positive electrode and a non-aqueous electrolytic solution, in which a carbonaceous material is used as an active negative-electrode material, is disclosed. The negative electrode is constituted by a carbon sintered mass obtained on sintering the carbonaceous material or a carbon sintered mass-current collector composite material. The secondary cell is improved in the amount of the active material packed in the negative electrode, energy density and in the charging/discharging efficiency. If the carbon sintered mass-current collector composite material is employed for the negative electrode, further improvement in the electrical conductivity and charging/discharging efficiency in the negative electrode is achieved.
    • 公开了一种具有负极,正极和非水电解液的非水电解质二次电池,其中使用碳质材料作为活性负极材料。 负极由烧结碳质材料得到的碳烧结体或碳烧结体集电体复合材料构成。 二次电池在负极中填充的活性材料的量,能量密度和充电/放电效率都得到改善。 如果将碳烧结质量集电体复合材料用于负极,则可以进一步提高负极中的导电性和充放电效率。
    • 9. 发明授权
    • Non-aqueous electrolyte secondary cell
    • 非水电解质二次电池
    • US06355372B2
    • 2002-03-12
    • US09196319
    • 1998-11-20
    • Takayuki YamahiraAyaki WatanabeToshizou KameishiKoji Kihara
    • Takayuki YamahiraAyaki WatanabeToshizou KameishiKoji Kihara
    • H01M212
    • H01M10/0525H01M2/1241H01M2/26H01M6/10H01M10/052
    • An extremely safe non-aqueous electrolyte secondary cell free of explosions and which can promptly release the internal pressure in case of rise in the internal pressure. The non-aqueous electrolyte secondary cell has in its opening a cleavage valve obtained on bonding a metal foil to the opening. In case of rise in the internal pressure, the cleavage valve is cleft to release the pressure. In this cell, a value K corresponding to the internal volume in the cell in cm3 divided by the area of the opening in cm2 is set so that 40≦K≦350. By selecting the value K to a suitable value, the cleavage valve is in operation when the internal pressure reaches a predetermined value to release the pressure. The metal foil is produced by, for example, a electro-forming method or a cladding method. Preferably, a fluorine-based water-proofing agent is coated on the foil surface.
    • 非常安全的非水电解质二次电池没有爆炸,并且可以在内部压力升高的情况下迅速释放内部压力。 非水电解质二次电池在其开口处具有将金属箔接合到开口而获得的裂开阀。 在内部压力升高的情况下,裂解阀会裂开以释放压力。 在该单元中,将以cm为单位的电池内部体积相当于开口面积的单位为cm 2的值K设定为40≤K≤350。 通过将值K选择为合适的值,当内部压力达到预定值以释放压力时,裂解阀正在运行。 金属箔通过例如电铸法或包层法制造。 优选地,氟化防水剂涂覆在箔表面上。