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    • 5. 发明授权
    • Ni-based alloy product and producing method thereof
    • 镍基合金产品及其制备方法
    • US08801876B2
    • 2014-08-12
    • US13420918
    • 2012-03-15
    • Atsuro IsedaHiroyuki HirataHirokazu OkadaHiroyuki Semba
    • Atsuro IsedaHiroyuki HirataHirokazu OkadaHiroyuki Semba
    • C21D11/00C22C19/05C22C30/00
    • C22F1/10C22C19/05C22F1/00
    • [Problem to be Solved]A Ni-based alloy product consisting of, by mass percent, C: 0.03 to 0.10%, Si: 0.05 to 1.0%, Mn: 0.1 to 1.5%, Sol.Al: 0.0005 to 0.04%, Fe: 20 to 30%, Cr: not less than 21.0% and less than 25.0%, W: exceeding 6.0% and not more than 9.0%, Ti: 0.05 to 0.2%, Nb: 0.05 to 0.35%, and B: 0.0005 to 0.006%, the balance being Ni and impurities, the impurities being P: 0.03% or less, S: 0.01% or less, N: less than 0.010%, Mo: less than 0.5%, and Co: 0.8% or less, wherein a value of effective B (Beff) defined by the formula, Beff (%)=B−(11/14)×N+(11/48)×Ti, is 0.0050 to 0.0300%, and the rupture elongation in a tensile test at 700° C. and at a strain rate of 10−6/sec is 20% or more. This alloy may contain one or more kinds of Cu, Ta, Zr, Mg, Ca, REM, and Pd.
    • [待解决的问题]以质量%计,C:0.03〜0.10%,Si:0.05〜1.0%,Mn:0.1〜1.5%,Sol.Al:0.0005〜0.04%,Fe :20〜30%,Cr:21.0%以上25.0%以下,W:6.0以上9.0%以下,Ti:0.05〜0.2%,Nb:0.05〜0.35%,B:0.0005〜 0.006%,余量为Ni和杂质,杂质为P:0.03%以下,S:0.01%以下,N:小于0.010%,Mo:小于0.5%,Co:0.8%以下,其中, 由公式Beff(%)= B-(11/14)×N +(11/48)×Ti定义的有效B(Beff)的值为0.0050〜0.0300%,拉伸试验中的断裂伸长率为 700℃,应变速率为10-6 /秒为20%以上。 该合金可以含有Cu,Ta,Zr,Mg,Ca,REM和Pd中的一种或多种。
    • 8. 发明授权
    • Ni-based heat resistant alloy
    • 镍基耐热合金
    • US09328403B2
    • 2016-05-03
    • US14237586
    • 2012-07-31
    • Hiroyuki SembaHirokazu OkadaHiroyuki HirataMitsuru YoshizawaAtsuro Iseda
    • Hiroyuki SembaHirokazu OkadaHiroyuki HirataMitsuru YoshizawaAtsuro Iseda
    • C22C19/05C22F1/10
    • C22C19/056C22C19/05C22C19/051C22C19/055C22F1/10
    • A Ni-based heat resistant alloy as pipe, plate, rod, forgings and the like consists of C≦0.15%, Si≦2%, Mn≦3%, P≦0.03%, S≦0.01%, Cr: 15% or more and less than 28%, Mo: 3 to 15%, Co: more than 5% and not more than 25%, Al: 0.2 to 2%, Ti: 0.2% to 3%, Nd: fn to 0.08%, and O≦0.4Nd, further containing, as necessary, at least one kind of Nb, W, B, Zr, Hf, Mg, Ca, Y, La, Ce, Ta, Re and Fe of specific amounts, the balance being Ni and impurities, wherein, fn=1.7×10−5d+0.05{(Al/26.98)+(Ti/47.88)+(Nb/92.91)}. In the formula, d denotes an average grain size (μm), and each element symbol denotes the content (mass %) of that element. If the alloy contains W, Mo+(W/2)≦15% holds. The alloy has improved ductility after long-term use at high temperatures, and cracking due to welding can be avoided.
    • 作为管,板,棒,锻件等的Ni基耐热合金由C< Ll; 0.15%,Si&NlE; 2%,Mn&NlE; 3%,P&NlE; 0.03%,S< 0.01%,Cr:15% 多于28%,Mo:3〜15%,Co:5%以上25%以下,Al:0.2〜2%,Ti:0.2%〜3%,Nd:fn〜0.08% O,nNE,0.4Nd,根据需要还含有特定量的Nb,W,B,Zr,Hf,Mg,Ca,Y,La,Ce,Ta,Re和Fe中的至少一种,其余为Ni和 杂质,其中,fn = 1.7×10-5d + 0.05 {(Al / 26.98)+(Ti / 47.88)+(Nb / 92.91)}。 式中,d表示平均粒径(μm),各元素符号表示该元素的含量(质量%)。 如果合金含有W,则Mo +(W / 2)≦̸ 15%成立。 该合金在长期使用高温下具有改善的延展性,并且可以避免由于焊接引起的开裂。
    • 9. 发明授权
    • Austenitic stainless steel tube excellent in steam oxidation resistance and a manufacturing method thereof
    • 耐蒸汽抗氧化性优异的奥氏体不锈钢管及其制造方法
    • US07014720B2
    • 2006-03-21
    • US10378905
    • 2003-03-05
    • Atsuro Iseda
    • Atsuro Iseda
    • C22C38/48C22C38/50
    • C22C38/50C21D8/105C22C38/001C22C38/002C22C38/02C22C38/48C22C38/58
    • The present invention provides an austenitic stainless steel tube with a uniform fine grained structure of regular grains, which is not changed to a coarse structure and the steam oxidation resistance is maintained even if the tube is subjected to a high temperature reheating during welding and high temperature bending working. The austenitic stainless steel tube consists of, by mass %, C: 0.03–0.12%, Si: 0.1–0.9%, Mn: 0.1–2%, Cr: 15–22%, Ni: 8–15%, Ti: 0.002–0.05%, Nb: 0.3–1.5%, sol. Al: 0.0005–0.03%, N: 0.005–0.2% and O (oxygen): 0.001–0.008%, and the balance Fe and impurities, the austenitic stainless steel tube having austenitic grain size number of 7 or more and a mixed grain ratio of preferably 10% or less.
    • 本发明提供一种具有规则晶粒均匀细粒度结构的奥氏体不锈钢管,其不会变成粗糙结构,并且即使管在焊接和高温下经受高温再加热也保持了蒸汽抗氧化性 弯曲工作。 奥氏体不锈钢管以质量%计含有C:0.03〜0.12%,Si:0.1-0.9%,Mn:0.1〜2%,Cr:15〜22%,Ni:8〜15%,Ti:0.002 -0.05%,Nb:0.3-1.5%,溶胶。 Al:0.0005-0.03%,N:0.005-0.2%,O(氧):0.001-0.008%,余量为Fe和杂质,奥氏体晶粒数为7以上的奥氏体不锈钢管和混合晶粒比 优选为10%以下。