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1. 发明申请

US20110143061A1 TWO-COMPONENT ADHESIVE SUITABLE FOR CONSTRUCTION PURPOSES, ITS USE AND THE CURED STRUCTURAL BONDS OBTAINED THEREBY 有权
标题翻译：适用于施工用途的两种组分粘合剂，其使用和固化的结构性骨料
公开(公告)号：US20110143061A1
公开(公告)日：2011-06-16
申请号：US12955838
申请日：2010-11-29
申请人： Frank THIEMANN , Armin Pfeil
发明人： Frank THIEMANN , Armin Pfeil
IPC分类号： B32B1/02 , C08L33/10 , C08K3/34 , C08K3/30 , C08K3/22 , C08K3/26 , B32B27/30 , B32B15/08 , B32B37/12 , B32B37/14 , B32B37/06 , B32B37/02
CPC分类号： C09J133/10 , C08F222/1006 , C08F232/08 , C08G59/66 , C08G75/04 , C08G75/045 , C08L23/20 , C09J133/08 , Y10T428/13 , Y10T428/31699 , Y10T428/31855
摘要： A two-component adhesive composition suitable for structural bonding of concrete/concrete, steel/concrete, or steel/steel, as well as for structural strengthening and reinforcing applications with fiber reinforced polymers, is disclosed. The composition includes a resin component A with a peroxide containing at least one norbornene group and at least one methacrylate containing compound and a hardener component B comprising a peroxide and at least one thiol. The resin component A and the hardener component B are spatially separated from one another to inhibit any reaction before mixing of the components.
摘要翻译：公开了一种适用于混凝土/混凝土，钢/混凝土或钢/钢的结构粘合的双组分粘合剂组合物，以及用于纤维增强聚合物的结构强化和增强应用。组合物包括具有至少一个降冰片烯基团的过氧化物和至少一种含甲基丙烯酸酯化合物的树脂组分A和包含过氧化物和至少一种硫醇的固化剂组分B. 在混合组分之前，树脂组分A和固化剂组分B在空间上彼此分离以抑制任何反应。

2. 发明授权

US08445615B2 Two-component adhesive suitable for construction purposes, its use and the cured structural bonds obtained thereby 有权
标题翻译：适用于建筑目的的双组分粘合剂，其用途和由此得到的固化结构键
公开(公告)号：US08445615B2
公开(公告)日：2013-05-21
申请号：US12955838
申请日：2010-11-29
申请人： Frank Thiemann , Armin Pfeil
发明人： Frank Thiemann , Armin Pfeil
IPC分类号： C08K5/101 , C08K5/23 , C08K5/36 , B32B27/30
CPC分类号： C09J133/10 , C08F222/1006 , C08F232/08 , C08G59/66 , C08G75/04 , C08G75/045 , C08L23/20 , C09J133/08 , Y10T428/13 , Y10T428/31699 , Y10T428/31855
摘要： A two-component adhesive composition suitable for structural bonding of concrete/concrete, steel/concrete, or steel/steel, as well as for structural strengthening and reinforcing applications with fiber reinforced polymers, is disclosed. The composition includes a resin component A with a peroxide containing at least one norbornene group and at least one methacrylate containing compound and a hardener component B comprising a peroxide and at least one thiol. The resin component A and the hardener component B are spatially separated from one another to inhibit any reaction before mixing of the components.
摘要翻译：公开了一种适用于混凝土/混凝土，钢/混凝土或钢/钢的结构粘合的双组分粘合剂组合物，以及用于纤维增强聚合物的结构强化和增强应用。组合物包括具有至少一个降冰片烯基团的过氧化物和至少一种含甲基丙烯酸酯化合物的树脂组分A和包含过氧化物和至少一种硫醇的固化剂组分B. 在混合组分之前，树脂组分A和固化剂组分B在空间上彼此分离以抑制任何反应。

3. 发明授权

US07166670B2 Two-component chemical fastening systems 失效
标题翻译：双组分化学紧固系统
公开(公告)号：US07166670B2
公开(公告)日：2007-01-23
申请号：US10451103
申请日：2001-12-19
申请人： Jan H Udding , Agnes E Wolters , Heinz Wilhelm , Armin Pfeil , Thomas Bürgel , Lutz Sager
发明人： Jan H Udding , Agnes E Wolters , Heinz Wilhelm , Armin Pfeil , Thomas Bürgel , Lutz Sager
IPC分类号： C08L35/08
CPC分类号： C08G18/672 , C08F283/00 , C08F283/01 , C08F290/06 , C08G18/6715
摘要： The invention relates to two-component chemical fastening systems, the A-component containing an unsaturated polyester and a reactive diluent, and the B-component containing a peroxide and an extender, wherein the extender is either a monomeric component according to formula 1 (A—CH═CH—O)n—R (formula 1) or a resinous compound comprising, in a covalently built-in manner, a component having vinyl ether group(s), and the content of the peroxide in the B-component is from 0.5 to 99 wt. %. In the formula A, R and n are specified as hydrogen or C1-3 alkyl; C1-20 (hetero)-aliphatic with hydroxyl or amino groups, or poly(C2 or 3)glycol with 2–120 glycol units; and 1 to 4, respectively. The resinous compounds with built-in vinyl ether group(s) (0.5 to 50 wt. %, calculated as indicated) are obtained by reaction of a mixture of appropriate amounts of: a) a first compound (HVE) containing at least one hydroxyl group and at least one vinyl ether group, and b) a second compound (D/HIC), being an isocyanate; and c) a third compound (G/P/HP) from (1) C2-6 glycols, (2) C5-20 polyols having 2–5 hydroxyl groups and (3) hydroxyl terminated polyester compounds, not being alkyd resins, having 1–5 free hydroxyl groups and 2–50 monomeric units, or mixtures thereof. The invention also relates to methods for preparing (the B-component) of such two-component chemical fastening systems, as well as to use of the systems for chemical fastening.
摘要翻译：本发明涉及双组分化学紧固系统，含有不饱和聚酯和反应性稀释剂的A组分和含有过氧化物和增量剂的B组分，其中增量剂是根据式1的单体组分。（A-CH-CH-O）n（式1）<？在线公式描述=“In-line formula”end =“lead”？或者含有乙烯基醚基的成分，B成分中的过氧化物的含量以共价构成的方式构成的树脂状化合物为0.5〜99wt。％。在式A中，R和n被指定为氢或C 1-3烷基; 具有羟基或氨基的C 1-20（杂） - 脂族基或具有2-120个二醇单元的聚（C 2或3）二醇; 和1至4。通过将适当量的混合物反应获得含有内置乙烯基醚基团的树脂化合物（0.5至50重量％，如所示计算）：a）含有至少一个羟基的第一化合物（HVE）基团和至少一个乙烯基醚基团，和b）第二化合物（D / HIC），其为异氰酸酯; 和c）来自（1）C 2-6二醇的第三化合物（G / P / HP），（2）具有2-5个羟基的C 5-20-20多元醇基团和（3）羟基封端的聚酯化合物，不是醇酸树脂，具有1-5个游离羟基和2-50个单体单元，或其混合物。本发明还涉及这种双组分化学紧固系统的制备（B组分）的方法以及用于化学固定的系统。

4. 发明授权

US07160951B2 Peroxide compositions with reactive diluents 失效
标题翻译：具有活性稀释剂的过氧化物组合物
公开(公告)号：US07160951B2
公开(公告)日：2007-01-09
申请号：US10451049
申请日：2001-12-19
申请人： Jan H Udding , Agnes E Wolters , Heinz Wilhelm , Armin Pfeil , Thomas Bürgel , Lutz Sager
发明人： Jan H Udding , Agnes E Wolters , Heinz Wilhelm , Armin Pfeil , Thomas Bürgel , Lutz Sager
IPC分类号： C08F261/06
CPC分类号： C07C407/006 , C07C407/00 , C08F4/32 , C07C409/22 , C07C409/38 , C07C409/34 , C07C409/10
摘要： The invention relates to peroxide compositions comprising a reactive diluent for the peroxide, wherein the diluent is either a component containing one or more vinyl ether group(s) and having a monomeric structure according to formula 1, (A—CH═CH—O)n—R, or is a suitable resinous compound comprising, in a covalently built-in manner, a component containing one or more vinyl ether group(s). In the formula A represents hydrogen or an alkyl group with 1–3 C atoms, and individual A groups may be different R either represents an aliphatic group, optionally branched, with 1–20 C atoms, etc. or represents a polyethylene or polypropylene glycol with 2 to 120 glycol units, etc. and n is 1, 2, 3 or 4. The resinous compounds comprising, in a covalently built-in manner, a component containing one or more vinyl ether group(s)are obtained by reaction of: a) a first compound (the HVE-compound) containing at least one hydroxyl group and at least one vinyl ether group, and b) a second compound (the D/HIC-compound), being an isocyanate, reacting with formation of one or more urethane group(s), and c) a third compound (the G/P/HP-compound) chosen from the groups of (1) C2-6 glycols, (2) C5-20 polyols having 2–5 hydroxyl groups and (3) hydroxyl terminated polyester compounds, not being alkyd resins, having 1–5 free hydroxyl groups and from 2–50 monomeric ester units (the G/P/HP-compound), or mixtures thereof. The invention also relates to the preparation of such compositions and to the use of such reactive diluents for peroxides in radically curing of unsaturated polyester resins for structural applications.
摘要翻译：本发明涉及包含用于过氧化物的反应性稀释剂的过氧化物组合物，其中稀释剂是含有一个或多个乙烯基醚基团并且具有根据式1的单体结构的组分（A-CH-CH-O）或者是合适的树脂化合物，其以共价内置的方式包含含有一个或多个乙烯基醚基团的组分。式A表示氢或具有1-3个C原子的烷基，各个A基团可以不同，R表示任选支链的1-20个C原子的脂族基团等，或代表聚乙烯或聚丙二醇 2〜120个二醇单元等，n为1,2,3或4.含有一个或多个乙烯基醚基的成分以共价内置的方式包含的树脂化合物是通过：a）含有至少一个羟基和至少一个乙烯基醚基团的第一化合物（HVE-化合物），和b）作为异氰酸酯的第二化合物（D / HIC-化合物）与形成一个或更多个氨基甲酸酯基团，和c）选自（1）C 2-6 - 二醇的第三化合物（G / P / HP-化合物），（2）C < 具有2-5个羟基的（3）羟基封端的聚酯化合物，不具有1-5个游离羟基的醇酸树脂和2-50个单体酯单元（t 他G / P / HP-化合物）或其混合物。本发明还涉及这种组合物的制备以及这种反应性稀释剂在不饱和聚酯树脂的自由基固化中用于结构应用的过氧化物的用途。

5. 发明授权

US5935710A Liquid two-component coating compositions 失效
公开(公告)号：US5935710A
公开(公告)日：1999-08-10
申请号：US972038
申请日：1997-11-17
申请人： Michael Hoenel , Armin Pfeil , Thomas Budnick , Heiner Schwan
发明人： Michael Hoenel , Armin Pfeil , Thomas Budnick , Heiner Schwan
IPC分类号： B05D7/24 , B05C9/06 , B05D7/14 , C08G59/50 , C08G71/00 , C08G71/04 , C09D163/00 , C09D175/04 , C08F283/02 , C08L63/00
CPC分类号： C09D163/00 , C08G59/50 , C08G71/00 , C08G71/04 , C09D175/04 , Y10S525/934 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , Y10T428/31551
摘要： This invention relates to coating compositions including one or more resins having amino-reactive groups; one or more polyamine curing agents; and one or more aminourethanes. The aminourethanes can be reaction products of (i) oligomeric or polymeric compounds which contain at least one, preferably two or more terminal 2-oxo-1,3-dioxolane groups (cyclic carbonate groups), and (ii) amines containing at least one primary, preferably two or more primary and, if desired, also secondary and tertiary amino groups. The ratios of equivalents of C1):C2) typically is from 1:1 to 1:10, preferably from 1:1.05 to 1:5 and particularly preferably from 1:1.1 to 1:2, and the end product preferably contains one or more free primary amino groups. The composition further may contain, if desired, pigments, fillers, one or more organic solvents, water and conventional additives.

6. 发明授权

US5612394A Aqueous, modified epoxy resin dispersions 失效
标题翻译：水性改性环氧树脂分散体
公开(公告)号：US5612394A
公开(公告)日：1997-03-18
申请号：US253077
申请日：1994-06-02
申请人： Armin Pfeil , Michael Hoenel , Paul Oberressl , Dieter Dreischhoff , Stefan Petri
发明人： Armin Pfeil , Michael Hoenel , Paul Oberressl , Dieter Dreischhoff , Stefan Petri
IPC分类号： C08L51/08 , C08F2/44 , C08F283/00 , C08F283/10 , C08G59/06 , C08L71/02 , C08K3/20 , C08L63/00
CPC分类号： C08G59/066 , C08F283/10 , C08L71/02
摘要： Aqueous epoxy resin dispersion comprising (A) an epoxy resin which is a condensation product of (A-1) from 50 to 95% by weight, preferably from 55 to 85% by weight, of one or more epoxide compounds having at least two epoxide groups per molecule and an epoxide equivalent mass of from 100 to 2000 g/mol, (A-2) from 5 to 50% by weight, preferably from 15 to 45% by weight, of an aromatic polyol; and (A-3) from 0 to 25% by weight, preferably from 0 to 10% by weight, of modifying compounds containing at least two epoxide-reactive groups; (B) a dispersant comprising (B-1) a condensation product of a polyol having a weight-average molecular mass (M.sub.w) of from 200 to 20,000 g/mol and an epoxide compound having on average at least two epoxide groups per molecule and an epoxide equivalent mass of from 100 to 10,000 g/mol, and (B-2) if desired other surfactants, preferably nonionic surfactants; (C) a polymer, prepared in this dispersion, of ethylenically unsaturated monomers which are capable of free-radical polymerization or copolymerization; (D) a curing agent for the epoxy resin (A); and (E) if desired, conventional additives and catalysts. These aqueous epoxy resin dispersions are suitable for the production of coatings, in particular for interior coatings of cans for beverages and preserves.
摘要翻译：一种水性环氧树脂分散体，其包含（A）环氧树脂，其为（A-1）50至95重量％，优选55至85重量％的一种或多种具有至少两个环氧化物的环氧化合物的缩合产物（A-2）为5〜50重量％，优选为15〜45重量％的芳香族多元醇的环氧当量为100〜2000克/摩尔，和（A-3）0至25重量％，优选0至10重量％的包含至少两个环氧化物反应性基团的化合物; （B）分散剂，其包含（B-1）重均分子量（Mw）为200〜20,000g / mol的多元醇与每分子平均具有至少两个环氧基的环氧化合物的缩合物，和环氧当量为100至10,000g / mol，和（B-2）如果需要其他表面活性剂，优选非离子表面活性剂; （C）在该分散体中制备的能够进行自由基聚合或共聚的烯属不饱和单体的聚合物; （D）环氧树脂（A）的固化剂; 和（E）如果需要，常规添加剂和催化剂。这些水性环氧树脂分散体适用于制备涂料，特别是用于饮料和保鲜罐的罐的内部涂料。

7. 发明授权

US5424340A Aqueous epoxy resin dispersions 失效
标题翻译：水性环氧树脂分散体
公开(公告)号：US5424340A
公开(公告)日：1995-06-13
申请号：US216664
申请日：1994-03-23
申请人： Armin Pfeil , Joerg-Peter Geisler , Paul Oberressl , Dieter Dreischhoff
发明人： Armin Pfeil , Joerg-Peter Geisler , Paul Oberressl , Dieter Dreischhoff
IPC分类号： C08G59/20 , C08G59/04 , C08G59/42 , C08L63/00 , C09D5/00 , C09D5/02 , C09D163/00 , C08K3/20 , C08L63/02
CPC分类号： C08G59/04 , C08L63/00 , Y10T428/31511
摘要： Aqueous epoxy resin dispersions containing(A) an epoxy resin which is a condensation product of one or more epoxy compound(s), of an aromatic polyol and, if used, of a modifying compound having at least two groups which are reactive with epoxides,(B) a dispersing agent in the form of a condensation product of an aliphatic polyol and an epoxy compound, the equivalent ratio of the OH groups to the epoxy groups being 1:0.8 to 1:3.5,(C) a carboxyl-containing or -releasing curing agent for the epoxy resin comprising one or more carboxyl-containing compound(s), at least one of these compounds having a functionality of at least three carboxyl groups per molecule, and(D) if desired customary additives, components (A), (B) and (C) being used in such amounts by weight that the equivalent ratio of the epoxy groups of component (A) capable of reacting to the carboxyl groups of component (B) is at least 1:0.5.
摘要翻译：含有（A）环氧树脂的水性环氧树脂分散体，其是一种或多种环氧化合物与芳族多元醇的缩合产物，如果使用的话，具有至少两个与环氧化物反应的基团的改性化合物，（B）脂族多元醇与环氧化合物缩合产物形式的分散剂，OH基与环氧基的当量比为1:0.8至1:3.5，（C）含羧基或对于包含一种或多种含羧基化合物的环氧树脂的可释放固化剂，每分子具有至少三个羧基官能度的这些化合物中的至少一种，和（D）如果需要，常规添加剂，组分（A ），（B）和（C）以按组分（B）能够与羧基反应的组分（A）的环氧基的当量比至少为1:0.5的重量使用。

8. 发明授权

US5855961A Liquid two-component coating compositions 失效
标题翻译：液体双组分涂料组合物
公开(公告)号：US5855961A
公开(公告)日：1999-01-05
申请号：US854677
申请日：1997-05-12
申请人： Michael Hoenel , Armin Pfeil , Thomas Budnick , Heiner Schwan
发明人： Michael Hoenel , Armin Pfeil , Thomas Budnick , Heiner Schwan
IPC分类号： B05D7/24 , B05C9/06 , B05D7/14 , C08G59/50 , C08G71/00 , C08G71/04 , C09D163/00 , C09D175/04 , D02G3/00
CPC分类号： C09D163/00 , C08G59/50 , C08G71/00 , C08G71/04 , C09D175/04 , Y10S525/934 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , Y10T428/31551
摘要： This invention relates to coating compositions including one or more resins having amino-reactive groups; one or more polyamine curing agents; and one or more aminourethanes. The aminourethanes can be reaction products of (i) oligomeric or polymeric compounds which contain at least one, preferably two or more terminal 2-oxo-1,3-dioxolane groups (cyclic carbonate groups), and (ii) amines containing at least one primary, preferably two or more primary and, if desired, also secondary and tertiary amino groups. The ratios of equivalents of C1):C2) typically is from 1:1 to 1:10, preferably from 1:1.05 to 1:5 and particularly preferably from 1:1.1 to 1:2, and the end product preferably contains one or more free primary amino groups. The composition further may contain, if desired, pigments, fillers, one or more organic solvents, water and conventional additives.
摘要翻译：本发明涉及包含一种或多种具有氨基反应性基团的树脂的涂料组合物; 一种或多种多胺固化剂; 和一种或多种氨基甲酸酯。氨基氨基甲酸酯可以是（i）含有至少一个，优选两个或多个末端2-氧代-1,3-二氧戊环（环状碳酸酯基）的低聚或聚合化合物的反应产物，和（ii）含有至少一个初级，优选两个或更多个伯，如果需要，也是仲氨基和叔氨基。 C1）：C2）的当量比通常为1:1至1:10，优选1：1.05至1：5，特别优选1：1.1至1：2，最终产物优选含有一个或多个更多游离的伯氨基。如果需要，组合物还可以含有颜料，填料，一种或多种有机溶剂，水和常规添加剂。

9. 发明授权

US5708059A Stable, aqueous epoxy resin dispersions, processes for their preparation, and their use 失效
标题翻译：稳定的水性环氧树脂分散体，其制备方法及其用途
公开(公告)号：US5708059A
公开(公告)日：1998-01-13
申请号：US798759
申请日：1997-02-11
申请人： Armin Pfeil , Michael Hoenel , Uwe Neumann
发明人： Armin Pfeil , Michael Hoenel , Uwe Neumann
IPC分类号： C08F283/10 , C08F290/06 , C08F290/14 , C08G18/08 , C08G18/58 , C08G18/80 , C08G59/06 , C08G59/14 , C08G59/18 , C08G59/40 , C08G59/50 , C08G59/56 , C08L51/08 , C08L63/00 , C09D11/10 , C09D163/00 , C09J163/00 , C08K3/20
CPC分类号： C09D11/10 , C08F283/10 , C08F290/064 , C08F290/144 , C08G18/0814 , C08G18/581 , C08G18/8029 , C08G59/066 , C08G59/50 , C08G59/56 , C08L51/08 , C08L63/00
摘要： A stable, aqueous epoxy resin dispersion including: (A) an epoxy resin prepared by condensation of at least one epoxide compound having on average at least two epoxide groups per molecule, with an aralkylated polyhydroxy aromatic compound obtained by reaction of a polyhydroxy aromatic compound with an aromatic compound which carries an alkenyl group; (B) a dispersant; and water, is useful, for example, in a coating or adhesive.
摘要翻译：一种稳定的水性环氧树脂分散体，包括：（A）通过使至少一种每分子平均具有至少两个环氧基团的环氧化合物与通过多羟基芳族化合物与多羟基芳族化合物反应获得的芳烷基化多羟基芳族化合物缩合制备的环氧树脂携带烯基的芳族化合物; （B）分散剂; 和水，例如在涂层或粘合剂中是有用的。

10. 发明授权

US5707741A Liquid two-component coating compositions 失效
公开(公告)号：US5707741A
公开(公告)日：1998-01-13
申请号：US638312
申请日：1996-04-26
申请人： Michael Hoenel , Armin Pfeil , Thomas Budnick , Heiner Schwan
发明人： Michael Hoenel , Armin Pfeil , Thomas Budnick , Heiner Schwan
IPC分类号： B05D7/24 , B05C9/06 , B05D7/14 , C08G59/50 , C08G71/00 , C08G71/04 , C09D163/00 , C09D175/04 , B32B27/38 , C08F283/02 , C08L63/00
CPC分类号： C09D163/00 , C08G59/50 , C08G71/00 , C08G71/04 , C09D175/04 , Y10S525/934 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , Y10T428/31551
摘要： This invention relates to coating compositions including one or more resins having amino-reactive groups; one or more polyamine curing agents; and one or more aminourethanes. The aminourethanes can be reaction products of (i) oligomeric or polymeric compounds which contain at least one, preferably two or more terminal 2-oxo-1,3-dioxolane groups (cyclic carbonate groups), and (ii) amines containing at least one primary, preferably two or more primary and, if desired, also secondary and tertiary amino groups. The ratios of equivalents of C1):C2) typically is from 1:1 to 1:10, preferably from 1:1.05 to 1:5 and particularly preferably from 1:1.1 to 1:2, and the end product preferably contains one or more free primary amino groups. The composition further may contain, if desired, pigments, fillers, one or more organic solvents, water and conventional additives.

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