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    • 1. 发明授权
    • Method for the isomerization of allyl alcohols
    • 烯丙醇异构化方法
    • US06989468B2
    • 2006-01-24
    • US10380116
    • 2001-09-18
    • Frank HaeseKlaus Ebel
    • Frank HaeseKlaus Ebel
    • C07C29/56B01J31/02B01J31/16B01J35/02
    • B01J31/2213B01J23/30B01J31/1805B01J31/181B01J31/1815B01J31/2243B01J2231/52B01J2531/0216B01J2531/66C07C29/56C07C33/02C07C33/03
    • The present invention relates to a process for the isomerization of precursor allyl alcohols of the formula (I) to product allyl alcohols of the formula (II) where R1 to R5 are hydrogen or a mono- or polyunsaturated or saturated C1-C12-alkyl radical, which may be substituted, in both directions of the equilibrium, wherein the reaction takes place in the presence of an oxoperoxotungsten(VI) complex of the formula (III), where L1, L2 in each case independently of one another are water or a free coordination site, or are optionally a ligand chosen from the group of aminoalcohols, aminophenols, aminocarboxylic acids or mixtures thereof or mixtures of amines with alcohols, phenols or carboxylic acids, m is the number 1 or 2 n is a number from 1 to 6 p is a number from 1 to 6, where in the case of p>1 a di- or polynuclear complex is formed, and also to novel oxoperoxotungsten(VI) complexes and to the use thereof.
    • 本发明涉及将式(I)的前体烯丙醇异构化制备成式(II)的产物烯丙醇的方法,其中R 1至R 5, 是在平衡的两个方向上是氢或可以被取代的单或多不饱和或饱和的C 1 -C 12 - 烷基,其中反应发生 在式(III)的氧代过氧钨(VI)络合物的存在下,其中每种情况下,L 1,L 2彼此独立地是水或游离配位部位,或任选地是选自氨基醇,氨基苯酚, 氨基羧酸或其混合物或胺与醇,酚或羧酸的混合物,m为1或2,n为1至6的数,p为1至6的数,其中在p> 1的情况下 形成二核或多核络合物,还涉及新型氧合倍钨(VI)络合物及其用途。