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    • 4. 发明授权
    • Coated composite high voltage electrical insulator
    • 涂层复合高压电绝缘子
    • US07232609B2
    • 2007-06-19
    • US11130107
    • 2005-05-17
    • Farooq AhmedFaisal HudaSeraj ul HudaJohn Barr
    • Farooq AhmedFaisal HudaSeraj ul HudaJohn Barr
    • B32B25/20
    • C08L83/04C08G77/16C08G77/20C08G77/70C08K3/22C08K9/06Y10T428/31663C08L2666/44C08L2666/54
    • A polymer base composite high voltage insulator is described having a monolithic protective coating of a one-part room temperature vulcanizable organopolysiloxane rubber composition obtained by mixing a) from about 20 to about 60 weight percent of one or more polydiorganosiloxane fluids having a viscosity of from about 10 to about 100,000 centipoise at 25° C., b) from 0 to about 40 weight percent of a cyclo-organosiloxane c) from 0 to about 40 weight percent of an inorganic extending or non-reinforcing filler d) from about 0.5 to about 15 weight percent of an amorphous SiO2 reinforcing filler having a surface area of between about 100 to 250 m2/g and a particle size range between about 0.01 and 0.03 microns; e) from about 1 to about 10 weight percent of an oximinosilane cross-linking agent f) from about 0.2 to about 3 weight percent of an adhesion promoter g) from about 0.02 to about 3 weight percent of an organotin salt as a condensation catalyst; and h) from about 20 to about 50 weight percent of alumina trihydrate, the alumina trihydrate having a median particle size of 10 μm to 3 μm, containing 65.1 percent Al2O3, 34.5 percent combined H2O, 0.3 percent Na2O, 0.02 percent CaO, 0.01 percent SiO2 and having a specific gravity of 2.42.
    • 描述了一种聚合物基复合高压绝缘体,其具有通过将a)约20至约60重量%的一种或多种聚二有机硅氧烷流体的粘度为约 在25℃下为10至约100,000厘泊,b)0至约40重量%的环有机硅氧烷c)0至约40重量%的无机延伸或非增强填料d)约0.5至约 15重量%的表面积为约100-250μm2 / g和粒度范围为约0.01至0.03微米的无定形SiO 2补强填料; e)约1至约10重量%的肟基硅烷交联剂f)约0.2至约3重量%的粘合促进剂g)约0.02至约3重量%的作为缩合催化剂的有机锡盐; 和h)约20至约50重量%的三水合氧化铝,所述三水合氧化铝的中值粒径为10〜3μm,含有65.1%的Al 2 O 3 ,34.5%的H 2 O 2,0.3%的Na 2 O,0.02%的CaO,0.01%的SiO 2,并且比重为 2.42。
    • 6. 发明申请
    • Silicone coating composition for protection from cathodic stress
    • 用于保护阴极应力的硅酮涂料组合物
    • US20070232749A1
    • 2007-10-04
    • US11375211
    • 2006-03-15
    • Farooq AhmedFaisal HudaSeraj ul HudaJohn Barr
    • Farooq AhmedFaisal HudaSeraj ul HudaJohn Barr
    • C08L83/04B05D3/00B32B27/00
    • C09D5/10C08K3/10C08K5/544C08K9/06C09D183/04
    • This invention relates to a corrosion protection silicone coating system provides for easy and convenient application by conventional methods such as dipping, brushing or spraying. The coating provides a guard against environmental effects causing cathodic stress along with high physical strength and adhesion achieved with a suitable blend of reinforcing and extending fillers. The coating is an organopolysiloxane rubber coating composition containing between about 10 and 80 weight percent of a sacrificial metal filler to provide protection against environmental effects causing cathodic stress. Preferably, the coating is a one-part room temperature vulcanizing organopolysiloxane rubber coating composition to provide protection against cathodic stress. The present invention also provides for a method of coating metal surfaces to protect the metal surface from corrosion and cathodic stress. The method comprises applying to the surface a thin layer of the above one-part organopolysiloxane rubber composition and allowing the layer of the one-part organopolysiloxane rubber composition to cure at room temperature to a silicone elastomer.
    • 本发明涉及防腐硅氧烷涂层系统,其通过常规方法如浸渍,刷涂或喷涂方便地应用。 涂层提供防止产生阴极应力的环境影响的保护,同时具有通过增强和延伸填料的合适混合物实现的高物理强度和粘合力。 该涂层是含有约10至80重量%的牺牲金属填料的有机聚硅氧烷橡胶涂料组合物,以提供防止引起阴极应力的环境影响的保护。 优选地,涂层是一部分室温硫化有机聚硅氧烷橡胶涂料组合物,以提供防止阴极应力的保护。 本发明还提供一种涂覆金属表面以保护金属表面免受腐蚀和阴极应力的方法。 该方法包括将上述一部分有机基聚硅氧烷橡胶组合物的薄层施加到表面上,并允许一部分有机聚硅氧烷橡胶组合物的层在室温下固化成硅氧烷弹性体。
    • 7. 发明申请
    • Method for protecting pipelines against corrosion
    • 保护管道免受腐蚀的方法
    • US20070218211A1
    • 2007-09-20
    • US11375397
    • 2006-03-15
    • Farooq AhmedFaisal HudaSeraj ul HudaJohn Barr
    • Farooq AhmedFaisal HudaSeraj ul HudaJohn Barr
    • B05D3/00C08L83/04B32B27/00
    • C09D183/04C09D5/08
    • The invention provides for the protection of pipelines and other metal surfaces from corrosion. The metal surface is coated with a vulcanizable elastomeric polyorganosiloxane coating re-inforced with geo-tech fabric or any other similar nature fabric or sheeting materials. In a preferred embodiment the geo-tech re-inforced silicone provides both cathodic and corrosion protection in submersible underground and overground pipelines. The present invention also provides for a method of protecting exposed surfaces particularly metal surfaces more particularly, metal pipelines from the effects of a corrosive environment. The method comprises applying to the surface a thin layer of a vulcanizable elastomeric polyorganosiloxane rubber composition, applying geo-tech or similar fabric onto the wet surface; optionally applying a second application of the same or different vulcanizable elastomeric polyorganosiloxane rubber composition and allowing the composition to cure to a silicone elastomer.
    • 本发明提供了管道和其他金属表面防腐蚀的保护。 金属表面涂覆有可再生土工织物或任何其他类似性质织物或片材材料的可硫化弹性体聚有机硅氧烷涂层。 在优选的实施方案中,地质技术重新引入的硅氧烷在潜水地下和地上管道中提供阴极和腐蚀保护。 本发明还提供了一种保护暴露表面的方法,特别是金属表面更具体地,金属管道不受腐蚀环境的影响。 该方法包括向该表面施加薄层的可硫化弹性体聚有机硅氧烷橡胶组合物,将地质技术或类似织物施加到湿表面上; 任选地施加相同或不同的可硫化的弹性体聚有机硅氧烷橡胶组合物的第二次施用,并使组合物固化成硅氧烷弹性体。
    • 8. 发明申请
    • Coated composite high voltage electrical insulator
    • US20050209384A1
    • 2005-09-22
    • US11130107
    • 2005-05-17
    • Farooq AhmedFaisal HudaSeraj ul HudaJohn Barr
    • Farooq AhmedFaisal HudaSeraj ul HudaJohn Barr
    • C08K3/10C08K3/22C08K3/34C08K9/06C08L83/04
    • C08L83/04C08G77/16C08G77/20C08G77/70C08K3/22C08K9/06Y10T428/31663C08L2666/44C08L2666/54
    • The present invention relates to a one-part room temperature vulcanizable organopolysiloxane rubber composition which crosslinks in the presence of moisture to form a coating for the high voltage insulators including composite insulators. The one-part organopolysiloxane rubber composition comprises the product which is obtained by mixing the following: a) from about 20 to about 60 weight percent of one or more polydiorganosiloxane fluids of the formula R″[(R)2SiO]n(R)2SiR′ in which R is a monovalent alkyl or alkenyl radical having 1 to 8 carbon atoms or a phenyl radical, R′ and R″ which may be the same or different are OH or a monovalent alkyl or alkylene radical having 1 to 8 carbon atoms or a phenyl radical and n has an average value such that the viscosity is from about 10 to about 100,000 centipoise at 25° C., wherein at least one of the polyorganosiloxane fluid has at least one of R′ and R″ equal to OH and n has an average value such that the viscosity is in the range from 100 to 100,000 centipoise at 25° C., preferably from 1,000 to 40,000 centipoise at 25° C.; b) from 0 to about 40 weight percent of a cycloorganosiloxane of the formula [(R)2SiO]n in which R is a monovalent alkyl or alkenyl radical having 1 to 8 carbon atoms or a phenyl radical which may optionally be substituted with an alkyl radical having 1 to 8 carbon atoms and n has an average value of 3 to 10 c) from 0 to about 40 weight percent of an inorganic extending or non-reinforcing filler b) from about 0.5 to about 15 weight percent of an amorphous SiO2 reinforcing filler having a surface area of between about 100 to 250 m2/g and a particle size range between about 0.01 and 0.03 microns; e) from about 1 to about 10 weight percent of an oximinosilane cross-linking agent of the formula; RSi(ON═CR′2)3 in which R and R′ are independently selected from monovalent alkyl or alkenyl radicals having 1 to 8 carbon atoms or a phenyl radical which may optionally be substituted with an alkyl radical having 1 to 8 carbon atoms; f) from about 0.2 to about 3 weight percent of an adhesion promoter of the formula R3b (R2O)3-bSiR1  in which R2 and R3 are independently selected from monovalent alkyl or alkenyl radicals having 1 to 8 carbon atoms or a phenyl radical which may optionally be substituted with an alkyl radical having 1 to 8 carbon atoms, b is an integer between 0 and 3, and R1 is a saturated, unsaturated or aromatic hydrocarbon radical having 1 to 10 carbon atoms which may optionally contain a functional group; g) from about 0.02 to about 3 weight percent of an organotin salt as a condensation catalyst; and h) from about 20 to about 50 weight percent of alumina trihydrate, the alumina trihydrate having a median particle size of 10 μm to 30 μm, containing 65.1 percent Al2O3, 34.5 percent combined H2O, 0.3 percent Na2O, 0.02 percent CaO, 0.01 percent SiO2 and having a specific gravity of 2.42.
    • 10. 发明授权
    • One-part organopolysiloxane rubber composition for use as a protection coating
    • US06437039B1
    • 2002-08-20
    • US09537664
    • 2000-03-29
    • Farooq AhmedFaisal HudaSeraj ul HudaJohn Barr
    • Farooq AhmedFaisal HudaSeraj ul HudaJohn Barr
    • C08K334
    • C09D183/04C08L2666/44C08L2666/54
    • The present invention relates to a one-part room temperature vulcanizable organopolysiloxane rubber composition which crosslinks in the presence of moisture to form a coating for the corrosion protection of metals. The one-part organopolysiloxane rubber composition comprises the product which is obtained by mixing the following: a) from about 20 to about 98 weight percent of one or more polydiorganosiloxane fluids of the formula R″[(R)2SiO]nR′ in which R is a monovalent alkyl or alkylene radical having 1 to 8 carbon atoms or a phenyl radical, R′ is a monovalent alkyl or alkylene radical having 1 to 8 carbon atoms or a phenyl radical, R″ is OH or a monovalent alkyl or alkylene radical having 1 to 8 carbon atoms or a phenyl radical and n has an average value such that the viscosity is from about 1 to about 100,000 centipoise at 25° C., wherein at least one of the polyorganosiloxane fluid has R″ equal to OH and n has an average value such that the viscosity is in the range from 1,000 to 100,000 centipoise at 25° C., preferably from 3,000 to 40,000 centipoise at 25° C.; b) from 0 to about 40 weight percent of a cyclo-organosiloxane of the formula [(R)2SiO]n in which R is a monovalent alkyl or alkylene radical having 1 to 8 carbon atoms or a phenyl radical which may optionally be substituted with an alkyl radical having 1 to 8 carbon atoms and n has an average value of 3 to 10 c) from 0 to about 40 weight percent of an inorganic extending or non-reinforcing filler d) from about 0.5 to about 10 weight percent of an amorphous SiO2 reinforcing filler having a surface area of between about 100 to 250 m2/g and a particle size range between about 0.01 and 0.03 microns; e) from about 1 to about 7 weight percent of an oximinosilane cross-linking agent of the formula; RSi (ONR′2) in which R and R′ are independently selected from monovalent alkyl or alkylene radicals having 1 to 8 carbon atoms or a phenyl radical which may optionally be substituted with an alkyl radical having 1 to 8 carbon atoms; f) from about 0.2 to about 3 weight percent of an adhesion promoter of the formula in which R2 and R3 are independently selected from monovalent alkyl or alkylene radicals having 1 to 8 carbon atoms or a phenyl radical which may optionally be substituted with an alkyl radical having 1 to 8 carbon atoms, b is an integer between 0 and 3, and R1 is a saturated, unsaturated or aromatic hydrocarbon radical having 1 to 10 carbon atoms which may optionally contain a functional group; and g) from about 0.02 to about 3 weight percent of an organotin salt as a condensation catalyst.