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    • 3. 发明授权
    • HDP-CVD deposition of low dielectric constant amorphous carbon film
    • 低介电常数无定形碳膜的HDP-CVD沉积
    • US06423384B1
    • 2002-07-23
    • US09339888
    • 1999-06-25
    • Kasra KhazeniEugene TzouZhengquan Tan
    • Kasra KhazeniEugene TzouZhengquan Tan
    • H05H124
    • H01L21/3146C23C16/26H01L21/0276H01L21/0332
    • The present invention generally provides a method for depositing a low dielectric constant amorphous carbon film on a substrate or other workpiece using high density plasma chemical vapor deposition (HDP-CVD) techniques. Specifically, the present invention provides a method for forming an amorphous carbon film having a low dielectric constant of less than about 3.0 and a high thermal stability at a temperature of at least about 400° C. In a preferred embodiment, the film is deposited using methane (CH4) and argon in a HDP-CVD reactor. The amorphous carbon film formed according to the invention is useful for many applications in ultra large scale integration (ULSI) structures and devices, such as for example, an inter-metal dielectric material and an anti-reflective coating useful for patterning sub-micron interconnect features.
    • 本发明通常提供了使用高密度等离子体化学气相沉积(HDP-CVD)技术在衬底或其它工件上沉积低介电常数非晶碳膜的方法。 具体地说,本发明提供一种形成低介电常数小于约3.0的非晶碳膜和在至少约400℃的温度下的高热稳定性的方法。在优选实施例中,使用 甲烷(CH4)和氩气。 根据本发明形成的无定形碳膜可用于超大规模集成(ULSI)结构和器件中的许多应用,例如金属间电介质材料和用于构图亚微米互连的抗反射涂层 特征。
    • 4. 发明授权
    • Method of depositing and amorphous fluorocarbon film using HDP-CVD
    • 使用HDP-CVD沉积非晶碳氟膜的方法
    • US06211065B1
    • 2001-04-03
    • US08948799
    • 1997-10-10
    • Ming XiEugene TzouLie-Yea ChengTurgut SahinYaxin Wang
    • Ming XiEugene TzouLie-Yea ChengTurgut SahinYaxin Wang
    • C23C1622
    • B05D1/62C23C16/0272C23C16/0281C23C16/26
    • The present invention provides a method of depositing an amorphous fluorocarbon film using a high bias power applied to the substrate on which the material is deposited. The invention contemplates flowing a carbon precursor at rate and at a power level so that equal same molar ratios of a carbon source is available to bind the fragmented fluorine in the film thereby improving film quality while also enabling improved gap fill performance. The invention further provides for improved adhesion of the amorphous fluorocarbon film to metal surfaces by first depositing a metal or TiN adhesion layer on the metal surfaces and then stuffing the surface of the deposited adhesion layer with nitrogen. Adhesion is further improved by coating the chamber walls with silicon nitride or silicon oxynitride.
    • 本发明提供了一种使用施加到其上沉积材料的衬底的高偏置功率沉积非晶碳氟化合物膜的方法。 本发明考虑了以速率和功率水平流动碳前体,使得碳源的相等摩尔比可用于结合薄膜中的碎裂氟,从而提高膜质量,同时还实现改进的间隙填充性能。 本发明进一步提供了通过首先在金属表面上沉积金属或TiN粘附层,然后用氮气填充沉积的粘合层的表面来改善非晶碳氟化合物膜对金属表面的粘合性。 通过用氮化硅或氮氧化硅涂覆室壁来进一步改善粘合性。