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    • 3. 发明授权
    • Laundry compositions comprising alkoxylated polyalkyleneimine dispersants
    • 包含烷氧基化聚亚烷基亚胺分散剂的洗衣组合物
    • US6127331A
    • 2000-10-03
    • US103240
    • 1998-06-23
    • James Albert ClearyShulin ZhangEugene Paul Gosselink
    • James Albert ClearyShulin ZhangEugene Paul Gosselink
    • C11D3/37C11D3/39C11D3/30C11D3/386C11D3/395
    • C11D3/3723C11D3/3907C11D3/3915C11D3/3917C11D3/392
    • The present invention relates to laundry detergent compositions which comprise an alkoxylated polyalkyleneimine soil dispersant having the formula: ##STR1## wherein R is C.sub.2 -C.sub.6 linear alkylene, C.sub.3 -C.sub.6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula:--(R.sup.1 O).sub.m (R.sup.2 O).sub.n R.sup.3wherein R.sup.1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R.sup.2 is ethylene; R.sup.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x, and y are each independently from about 4 to about 200; provided at least one --(R.sup.1 O) unit is attached to the backbone prior to attachment of an --(R.sup.2 O) unit and further provided m+n is at least 12, said dispersants are compatible with bleach. The disclosed alkoxylated polyalkyleneimines are also suitable for use as soil dispersant in bleach-containing laundry pre-soaks and bleaching agents.
    • 本发明涉及衣物洗涤剂组合物,其包含具有下式的烷氧基化聚亚烷基亚胺土壤分散剂:其中R是C 2 -C 6直链亚烷基,C 3 -C 6支链亚烷基及其混合物; B是分支的延续; E是具有下式的亚烷氧基单元: - (R 1 O)m(R 20)n R 3,其中R 1是1,2-亚丙基,1,2-亚丁基及其混合物; R2是乙烯; R3是氢,C1-C4烷基及其混合物; m为约1至约10; n为约10至约40; w,x和y各自独立地为约4至约200; 提供至少一个 - (R 1 O)单元在连接 - (R 2 O)单元之前连接到骨架上,并进一步提供m + n至少为12,所述分散剂与漂白剂相容。 所公开的烷氧基化聚亚烷基亚胺也适用于含漂白剂的洗衣前预浸和漂白剂中的土壤分散剂。
    • 8. 发明授权
    • Laundry detergent compositions comprising hydrophobically modified polyamines
    • 包含疏水改性多胺的洗衣洗涤剂组合物
    • US06812198B2
    • 2004-11-02
    • US10233196
    • 2002-08-30
    • Jeffrey Scott DupontEugene Paul GosselinkKenneth Nathan PriceRobert Henry Rohrbaugh
    • Jeffrey Scott DupontEugene Paul GosselinkKenneth Nathan PriceRobert Henry Rohrbaugh
    • C11D183
    • C07C217/50C08G65/2621C11D1/62C11D3/3723
    • The present invention relates to hydrophobically modified polyamines and laundry detergent compositions which comprise said polyamines, said compositions comprising: A) from about 0.01%, preferably from about 0.1%, more preferably from about 1%, most preferably from about 3% to about 50%, preferably to about 20%, more preferably to about 10%, most preferably to about 7% by weight, of a hydrophobically modified polyamine having the formula: wherein R is C6-C20 linear or branched alkylene, and mixtures thereof; R1 is an alkyleneoxy unit having the formula: —(R2O)x—R3 wherein R2 is C2-C4 linear or branched alkylene, and mixtures thereof; R3 is hydrogen, C1-C22 alkyl, C7-C22 alkylenearyl, and mixtures thereof; x is from about 15 to about 30; at least one Q moiety is a hydrophobic quaternizing unit selected from the group consisting of C8-C30 substituted or unsubstituted linear or branched alkyl, C6-C30 substituted or unsubstituted cycloalkyl, C7-C30 substituted or unsubstituted alkylenearyl, and mixtures thereof, and the remaining Q moieties are selected from the group consisting of lone pairs of electrons on the unreacted nitrogens, hydrogen, C1-C30 substituted or unsubstituted linear or branched alkyl, C3-C30 substituted or unsubstituted cycloalkyl, C7-C30 substituted or unsubstituted alkylenearyl, and mixtures thereof; X is an anion present in sufficient amount to provide electronic neutrality; n is from 0 to 3; B) from about 0.01% by weight, of a surfactant system comprising one or more surfactants selected from: i) from 0% to 100% by weight, of one or more anionic surfactants; ii) from 0% to 100% by weight, of one or more nonionic surfactants; iii) optionally from 0.1% to about 80% by weight, of one or more cationic surfactants; iv) optionally from 0.1% to about 80% by weight, of one or more zwitterionic surfactants; v) optionally from 0.1% to about 80% by weight, of one or more ampholytic surfactants; or vi) mixtures thereof; C) the balance carriers and adjunct ingredients.