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    • 3. 发明授权
    • Hop extracts and method of preparation
    • Hop提取物及其制备方法
    • US4324810A
    • 1982-04-13
    • US154577
    • 1980-05-29
    • Henry GoldsteinWalter FlyPatrick TingEtzer Chicoye
    • Henry GoldsteinWalter FlyPatrick TingEtzer Chicoye
    • C12C3/00C12C3/08C12C3/12C12C9/02
    • C12C3/12C12C3/00C12C3/08
    • Hop extracts useful in the preparation of anactinic or light stable malt beverages are obtained by a method which does not use organic solvents. The extracts are obtained by first treating a crude hop extract containing humulone with an aqueous reducing solution, heating the resulting mixture to form reduced isohumulone, acidifying the reaction mixture to form an aqueous phase and an organic phase, and then adjusting the temperature to facilitate the separation of the two phases. The organic phase which is obtained contains the desired isomerized and reduced humulone and it can be used per se as an anactinic brew kettle flavoring additive for beer or ale. In a preferred embodiment, the organic phase is further treated with an amount of an aqueous KOH solution sufficient to neutralize the reduced isohumulone and to form both an aqueous phase and a solid phase. The aqueous phase which contains reduced isohumulone of about 90+% purity can be used as an anactinic post-kettle additive and the solid phase which contains the remainder of the reduced isohumulone and other hop constituents can be used as an anactinic brew kettle additive.
    • 通过不使用有机溶剂的方法获得用于制备不稳定或不稳定的麦芽饮料的Hop提取物。 通过首先用还原水溶液处理含有葎草酮的粗啤酒花提取物,加热所得混合物以形成还原异葎草酮,酸化反应混合物以形成水相和有机相,然后调节温度以促进 分离两相。 获得的有机相包含所需的异构化和还原的葎草酮,并且其本身可以用作啤酒或啤酒的不确定性酿造壶调味添加剂。 在优选的实施方案中,有机相进一步用一定量的KOH水溶液进行处理,该溶液足以中和还原异葎草酮并形成水相和固相。 含有约90 +%纯度的还原异葎草酮的水相可以用作不活泼的后釜添加剂,并且含有剩余的还原异葎草酮和其它啤酒花组分的固相可以用作非活性酿造壶添加剂。
    • 4. 发明授权
    • Anactinic hopping materials and method of preparation
    • 催眠材料及其制备方法
    • US4759941A
    • 1988-07-26
    • US728831
    • 1985-04-30
    • Etzer ChicoyeWalter H. FlyHenry Goldstein
    • Etzer ChicoyeWalter H. FlyHenry Goldstein
    • C12C3/00C12C3/12A23L1/221
    • C12C3/00C12C3/12
    • A hopping material useful as a kettle additive in preparing anactinic malt beverages is prepared by a method which includes first forming an aqueous suspension of crude hops, containing alpha acids and cellulosic material and alkali hydroxide and an alkali borohydride. The suspension, which has a pH above about 10.5, is heated to isomerize and reduce the alpha acids initially present in the hops. The pH is lowered to about 2 to convert the reduced iso-alpha acids to their free acid forms so that they are adsorbed on cellulosic hop material in the reaction mixture. The cellulosic material which now contains the free isomerized and reduced alpha acids is isolated and is useful as an anactinic kettle additive which can be stored for prolonged periods with no decomposition. If desired, the cellulosic material thus obtained can be further treated by adjusting the pH with an alkaline solution to obtain an aqueous solution containing only reduced iso-alpha acids, which is useful as an anactinic post-kettle additive, and a cellulosic material, which is useful as an anactinic kettle additive.
    • 通过包括首先形成含有α-酸和纤维素材料的粗啤酒花的水性悬浮液和碱金属氢氧化物和碱金属硼氢化物的方法,制备用作制备不育麦芽饮料中的水壶添加剂的跳跃材料。 将pH高于约10.5的悬浮液加热至异构化并降低啤酒花中最初存在的α酸。 将pH降低至约2以将还原的异α酸转化为游离酸形式,使得它们被吸附在反应混合物中的纤维素啤酒花材料上。 现在含有游离异构化和还原的α-酸的纤维素材料被分离,并且可用作不加分解的长时间储存​​的催乳剂添加剂。 如果需要,由此获得的纤维素材料可以通过用碱性溶液调节pH进一步处理,以获得仅含有还原的异α酸的水溶液,其可用作不活泼的后锅添加剂和纤维素材料,其中 作为一种非活性水壶添加剂是有用的。