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    • 9. 发明授权
    • Macromolecular complexes of amidocarbonylic water-soluble polymers and
square planar platinous and equivalent organometallics
    • 氨基羰基水溶性聚合物和正方形平面铂和等效有机金属的大分子络合物
    • US4405757A
    • 1983-09-20
    • US75722
    • 1979-09-14
    • Bobby A. HowellErik W. Walles
    • Bobby A. HowellErik W. Walles
    • C08F8/42
    • C08F8/42
    • Unique, valuable and multifariously utile macromolecular complexes are comprised of: (i) non-ionic, amidocarbonylic, water-soluble polymers (and, for some embodimental purposes, the monomeric precursor(s) thereof), including such known materials as (poly)N-vinylpyrrolidone (i.e., "PVP") and/or (poly)N-vinyl-5-methyl-2-oxazolidinone (i.e., "PVO-M") and the hereinafter disclosed like(s) and/or equivalent(s) thereof which, for convenience, may be herein generically identified as "WSP"; and (ii) square planar configured platinous and, for instant applicancy, equivalently metalled organometallic compounds characterized in containing in ligandal inclusion an aromatic moiety from which depends and to which is connected at least a single distinctly polar substituent group (or "handle", as it were), such as an hydroxide (i.e., "--OH"), carboxylic acid (i.e., "--COOH") or sulfonic acid - (i.e., "--SO.sub.3 H") unit and/or equivalents thereof as herein disclosed which, for convenience, may for generic identification be herein called an "SPOM". The WSP:SPOM complex(es) are associated by non-ionic or other bonding attachment in the nature of hydrogen bonding and/or closely related electrostatic interaction between or through and to the polar substituent in the SPOM and the amidocarbonylic unit in the WSP.
    • 独特的,有价值的和多种多样的大分子复合物包括:(i)非离子型,酰氨基羰基,水溶性聚合物(以及在某些实施方案中,其单体前体),包括诸如(聚) N-乙烯基吡咯烷酮(即“PVP”)和/或(聚)N-乙烯基-5-甲基-2-恶唑烷酮(即“PVO-M”)和下文所公开的类似物和/或等同物 ),为了方便起见,本文中可以将其一般性地标识为“WSP”; 并且(ii)正方形平面配置的铂,并且为了即时应用,等效金属化的有机金属化合物,其特征在于含有配体包合物,芳族部分从其中依赖并连接至少一个明显极性的取代基(或“处理”,如 它是)如本文所公开的,例如氢氧化物(即,“-OH”),羧酸(即“-COOH”)或磺酸 - (即“-SO 3 H”)单元和/ 为了方便起见,通用标识在本文中称为“SPOM”。 WSP:SPOM复合物通过非离子或其他键合附着在氢键的性质和/或与SPOM中的极性取代基和WSP中的酰胺基羰基单元之间或之间的紧密相关的静电相互作用相关联。