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    • 8. 发明申请
    • TERNARY THERMOELECTRIC MATERIALS AND METHODS OF FABRICATION
    • 三元热电材料和制造方法
    • US20090235969A1
    • 2009-09-24
    • US12359052
    • 2009-01-23
    • Joseph P. HeremansVladimir JovovicDonald T. Morelli
    • Joseph P. HeremansVladimir JovovicDonald T. Morelli
    • H01L35/12C22C5/06C22C12/00C22C28/00
    • C01B19/007C01B19/002C01P2006/40H01L35/16H01L35/34Y02P20/129
    • A thermoelectric material and a method of fabricating a thermoelectric material are provided. The thermoelectric material includes a compound having an elemental formula of A1−xB1+yC2+z and having a coefficient of thermal expansion greater than 20 parts-per-million per degree Celsius in at least one direction at one or more operating temperatures. The A component of the compound includes at least one element selected from the group consisting of: at least one Group Ia element and at least one Group Ib element, the B component of the compound includes at least one element selected from the group consisting of: at least one Group V element and at least one Group VIII element, and the C component of the compound includes at least one Group VI element. In addition, x is between −0.2 and 0.3, y is between −0.2 and 0.4, and z is between −0.2 and 0.8. Furthermore, the A component includes no more than 95 atomic % silver when the B component includes antimony and the C component includes tellurium, the B component includes no more than 95 atomic % antimony when the A component includes silver and the C component includes tellurium, and the C component includes no more than 95 atomic % tellurium when the A component includes silver and the B component includes antimony.
    • 提供热电材料和制造热电材料的方法。 热电材料包括具有A1-xB1 + yC2 + z的元素式的化合物,并且在一个或多个工作温度下,在至少一个方向上的热膨胀系数大于每百万摄氏度20百万分之一。 化合物的A组分包括至少一种选自以下的元素:至少一种Ia族元素和至少一种Ib族元素,该化合物的B成分包括至少一种选自以下的元素: 至少一个V族元素和至少一个VIII族元素,并且该化合物的C成分包括至少一个VI族元素。 此外,x在-0.2和0.3之间,y在-0.2和0.4之间,z在-0.2和0.8之间。 此外,当B成分含有锑,C成分含有碲时,A成分含有不超过95原子%的银,当A成分含有银时,B成分含有不超过95原子%的锑,C成分含有碲, 当A成分含有银,B成分含有锑时,C成分含有不超过95原子%的碲。