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1. 发明授权

US06235960B1 Process for improving the pour point, and a catalyst based on at least one MTT, Ton or Fer zeolite 有权
标题翻译：改善倾点的方法，以及基于至少一种MTT，Ton或Fer沸石的催化剂
公开(公告)号：US06235960B1
公开(公告)日：2001-05-22
申请号：US09310181
申请日：1999-05-12
申请人： Eric Benazzi , Slavik Kasztelan , Nathalie George-Marchal
发明人： Eric Benazzi , Slavik Kasztelan , Nathalie George-Marchal
IPC分类号： C07C513
CPC分类号： C10G45/64 , B01J29/67 , B01J29/7284 , B01J29/7292 , B01J29/7484 , B01J29/7492 , B01J29/7884 , B01J29/7892 , B01J35/1061 , B01J35/1085 , B01J2229/26 , B01J2229/42
摘要： A process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which the feed to be treated is brought into contact with a catalyst comprising at least one zeolite with structure type MTT, TON or FER or any possible combination of these three, at least one hydro-dehydrogenating element selected from elements from group VIB and group VIII of the periodic table, at least one deposited promoter element (boron, silicon, phosphorous), optionally at least one group VIIA element, optionally at least one group VIIB element, at a temperature in the range 170° C. to 500° C., a pressure in the range 1 to 250 bars and at an hourly space velocity in the range 0.05 to 100 h−1, in the presence of hydrogen in an amount of 50 to 2000 l/l of feed. The oils obtained have good pour points and high viscosity indices (VI). The process is also applicable to gas oils, and other feeds requiring a reduction in pour point. The invention also relates to a catalyst containing silicon and to its use for converting hydrocarbon-containing feeds.
摘要翻译：一种用于改进含有多于10个碳原子的链烷烃的进料的倾点的方法，其中待处理的进料与包含至少一种结构类型为MTT，TON或FER的沸石或任何可能的组合的催化剂接触这些三种中的至少一种选自元素周期表第VIB族和第VIII族元素的至少一种加氢脱氢元素，至少一种沉积的促进元素（硼，硅，磷），任选至少一种VIIA族元素，任选至少一组VIIB元素，在170℃至500℃的温度范围内，压力范围为1至250巴，时间空间速度为0.05至100小时-1，在存在量为50至2000升/升的进料的氢。所得油具有良好的倾点和高粘度指数（VI）。该方法也适用于需要降低倾点的瓦斯油和其它进料。本发明还涉及含硅的催化剂及其用于转化含烃物料的用途。

2. 发明授权

US6106698A Catalyst comprising a zeolite selected from the group formed by NU-85, NU-86 and NU-87 zeolites and its use for hydroconverting hydrocarbon-containing petroleum feeds 失效
标题翻译：包含选自由NU-85，NU-86和NU-87沸石形成的基团的沸石及其用于加氢转化含烃石油原料的催化剂
公开(公告)号：US6106698A
公开(公告)日：2000-08-22
申请号：US257932
申请日：1999-02-26
申请人： Eric Benazzi , Nathalie George-Marchal , Slavik Kasztelan
发明人： Eric Benazzi , Nathalie George-Marchal , Slavik Kasztelan
IPC分类号： B01J29/72 , B01J29/06 , B01J29/78 , C10G45/12 , C10G47/00 , C10G47/16 , C10G47/20
CPC分类号： C10G47/20 , B01J29/78 , B01J2229/26 , B01J2229/42
摘要： The invention provides a hydrocracking catalyst comprising at least one matrix, a zeolite selected from the group formed by NU-85, NU-86 and NU-87 zeolites, at least one metal selected from the group formed by metals from group VIB and VIII of the periodic table, at least one element selected from the group formed by boron and silicon, optionally phosphorous, optionally at least one group VIIA element, and optionally at least one group VIIB element. The invention also relates to the use of the catalyst for hydrocracking hydrocarbon feeds.
摘要翻译：本发明提供一种加氢裂化催化剂，其包括至少一种基质，选自由NU-85，NU-86和NU-87沸石形成的基团的沸石，至少一种选自由VIB和VIII族的金属形成的金属周期表，选自由硼和硅形成的组中的至少一种元素，任选的磷，任选的至少一种VIIA族元素和任选的至少一种VIIB族元素。本发明还涉及催化剂用于加氢裂化烃进料的用途。

3. 发明授权

US5762902A Catalyst comprising a faujasite type zeolite and a ton type zeolite and a process for the hydroconversion of hydrocarbon petroleum feeds 失效
标题翻译：包含八面沸石型沸石和吨型沸石的催化剂以及烃石油原料的加氢转化方法
公开(公告)号：US5762902A
公开(公告)日：1998-06-09
申请号：US786646
申请日：1997-01-21
申请人： Eric Benazzi , Samuel Mignard , Nathalie George-Marchal , Slavik Kasztelan
发明人： Eric Benazzi , Samuel Mignard , Nathalie George-Marchal , Slavik Kasztelan
IPC分类号： B01J29/08 , B01J29/70 , B01J29/80 , C01B39/20 , C10G47/20 , C10G49/16 , C01B33/36 , B01J29/06
CPC分类号： C10G49/16 , B01J29/80 , B01J29/084 , B01J29/70 , Y10S423/21 , Y10S423/35
摘要： The invention concerns a composition comprising at least one matrix, at least one faujasite type zeolite and at least one TON type zeolite. The TON type zeolite can be Nu-10, THETA-1, KZ-2, or ISI-1. The catalyst also contains at least one hydrogenating element from groups VIII and VI. The catalyst is particularly for use for hydrocracking to maximize the yield of middle distillates (kerosine and gas oil).
摘要翻译：本发明涉及包含至少一种基质，至少一种八面沸石型沸石和至少一种TON型沸石的组合物。 TON型沸石可以是Nu-10，THETA-1，KZ-2或ISI-1。催化剂还含有至少一个来自VIII和VI族的氢化元素。催化剂特别用于加氢裂化以使中间馏分（煤油和瓦斯油）的产率最大化。

4. 发明授权

US06524470B1 Catalyst comprising beta zeolite and promoter element for hydrocracking 失效
标题翻译：包含β沸石和加氢裂化促进剂元素的催化剂
公开(公告)号：US06524470B1
公开(公告)日：2003-02-25
申请号：US09305290
申请日：1999-05-05
申请人： Slavik Kasztelan , Nathalie George-Marchal , Eric Benazzi
发明人： Slavik Kasztelan , Nathalie George-Marchal , Eric Benazzi
IPC分类号： B01J2976
CPC分类号： C10G47/20 , B01J29/7615 , B01J29/7815 , B01J2229/16 , B01J2229/26 , B01J2229/42 , C10G47/16
摘要： A catalyst comprising, in weight % with respect to the total catalyst weight 0.1% to 60% (expressed as the % by weight of oxide) of at least one hydro-dehydrogenating metal selected from the group formed by group VIB and VIII metals; 0.1% to 99% of at least one amorphous or low crystallinity porous matrix; 0.1% to 99.7% of beta zeolite; 0.1% to 20% (expressed as the % by weight of oxide) of at least one promoter element selected from the group formed by boron, silicon and phosphorous; 0 to 20% of at least one halogen; 0 to 20% (expressed as the % by weight of oxide) of at least one group VIIB element, the catalyst being especially useful for cracking hydrocarbon feeds.
摘要翻译：一种催化剂，其以相对于总催化剂重量％计含有选自由VIB族和VIII族金属形成的基团的至少一种加氢脱氢金属的0.1％至60％（以氧化物重量计） 0.1％至99％的至少一种无定形或低结晶度多孔基体; 0.1％至99.7％的β沸石; 至少一种选自硼，硅和磷形成的助催化剂元素的0.1％至20％（表示为氧化物的重量％）; 0至20％的至少一种卤素; 0至20％（表示为氧化物的重量％）的至少一种VIIB族元素，该催化剂特别适用于裂化烃进料。

5. 发明授权

US06171474B2 Zeolite Y catalyst containing silicon useful for hydrocracking 有权
标题翻译：含有可用于加氢裂化的硅的沸石Y催化剂
公开(公告)号：US06171474B2
公开(公告)日：2001-01-09
申请号：US09305288
申请日：1999-05-05
申请人： Slavik Kasztelan , Nathalie George-Marchal , Eric Benazzi
发明人： Slavik Kasztelan , Nathalie George-Marchal , Eric Benazzi
IPC分类号： C01G4700
CPC分类号： B01J29/08 , B01J2229/16 , B01J2229/22 , C10G47/20
摘要： Useful for example, for the hydrocracking of hydrocarbons is a catalyst comprising a matrix, at least one Y zeolite which is dealuminated and has a lattice parameter in the range 2.424 nm to 2.455 nm, a global SiO2/Al2O3 mole ratio is more than 8, the quantity of alkaline-earth metal cations or alkali metal cations and/or rare earth metal cations is such that the atomic ratio (n×Mn+)/Al is less than 0.8, the specific surface area, determined using the BET method, is more than 400 m2/g, and the water adsorption capacity is more than 6% by weight for P/P0 =0.2 at 25° C., said catalyst also comprising silicon deposited on the catalyst.
摘要翻译：对于例如烃的加氢裂解是有用的催化剂，它是一种催化剂，它包括一个基体，至少一个Y脱铝的Y沸石，其晶格参数在2.424 nm到2.455 nm之间，全球的SiO2 / Al2O3摩尔比大于8，碱土金属阳离子或碱金属阳离子和/或稀土金属阳离子的数量使得原子比（nxMn +）/ Al小于0.8，使用BET法测定的比表面积大于400 m2 / g，在25℃时P / P0 = 0.2，水吸附量大于6重量％，所述催化剂还含有沉积在催化剂上的硅。

6. 发明授权

US6045687A Catalyst containing at least two dealuminated Y zeolites and a conventional hydroconversion process for petroleum cuts using this catalyst 失效
标题翻译：含有至少两种脱铝Y沸石的催化剂和使用该催化剂的石油馏分的常规加氢转化方法
公开(公告)号：US6045687A
公开(公告)日：2000-04-04
申请号：US955626
申请日：1997-10-22
申请人： Samuel Mignard , Nathalie George-Marchal , Eric Benazzi , Slavik Kasztelan
发明人： Samuel Mignard , Nathalie George-Marchal , Eric Benazzi , Slavik Kasztelan
IPC分类号： B01J29/08 , B01J29/16 , B01J35/10 , C10G47/16 , C10G47/18 , C10G47/20
CPC分类号： C10G47/20 , B01J29/084 , C10G47/16 , B01J2229/26 , B01J2229/42
摘要： A catalyst support comprising at least one matrix, at least one Y zeolite with a lattice parameter which is in the range 24.15 .ANG. to 24.38 .ANG. (1 nm=10 .ANG.) and at least one Y zeolite with a lattice parameter of more than 24.38 .ANG. and less than or equal to 24.51 .ANG.. The invention also concerns a catalyst comprising said support and at least one hydro-dehydrogenating element, and a conventional hydroconversion process for petroleum cuts using said catalyst.
摘要翻译：一种催化剂载体，其包含至少一种基质，至少一种具有晶格参数的Y沸石，所述Y沸石的范围为24.15ng至24.38（1nm =10），和至少一个晶格参数大于24.38的Y沸石小于等于24.51安。本发明还涉及包含所述载体和至少一种氢脱氢元件的催化剂，以及使用所述催化剂进行石油切割的常规加氢转化方法。

7. 发明授权

US5954947A Process for mild hydrocracking of petroleum cuts using a catalyst containing at least two dealuminated Y zeolites 失效
标题翻译：使用含有至少两种脱铝Y沸石的催化剂轻度加氢裂化石油馏分的方法
公开(公告)号：US5954947A
公开(公告)日：1999-09-21
申请号：US955623
申请日：1997-10-22
申请人： Samuel Mignard , Nathalie George-Marchal , Eric Benazzi , Slavik Kasztelan
发明人： Samuel Mignard , Nathalie George-Marchal , Eric Benazzi , Slavik Kasztelan
IPC分类号： B01J29/16 , B01J29/08 , B01J29/40 , B01J29/80 , B01J37/20 , C10G47/16 , C10G47/18 , C10G47/20
CPC分类号： B01J29/80 , C10G47/16 , C10G47/20 , B01J2229/16 , B01J2229/26 , B01J2229/42 , B01J29/084 , B01J29/40
摘要： A mild hydroconversion process for petroleum cuts using a catalyst comprising at least one matrix, at least one Y zeolite with a lattice parameter which is in the range 24.15 .ANG. to 24.38 .ANG. (1 nm--10 .ANG.), at least one Y zeolite with a lattice parameter of more than 24.38 .ANG. and less than or equal to 24.51 .ANG., and at least one hydro-dehydrogenating element.
摘要翻译：用于使用包含至少一种基质，至少一种晶格参数的Y沸石的催化剂进行石油切割的温和加氢转化方法，所述Y沸石的范围为24.15至24.38（1nm-10），至少一个具有晶格参数大于24.38安培，小于或等于24.51安培，以及至少一个氢脱氢元件。

8. 发明授权

US06527945B2 Catalyst comprising a phyllosilicate containing boron and/or silicon, and a hydrocracking process 失效
公开(公告)号：US06527945B2
公开(公告)日：2003-03-04
申请号：US09850078
申请日：2001-05-08
申请人： Eric Benazzi , Slavik Kasztelan , Nathalie George-Marchal
发明人： Eric Benazzi , Slavik Kasztelan , Nathalie George-Marchal
IPC分类号： C10G4702
CPC分类号： B01J21/16 , B01J23/85 , C10G47/20
摘要： The invention concerns a catalyst comprising at least one matrix, at least one dioctahedral 2:1 phyllosilicate which is optionally synthesised in a fluorine-containing medium and optionally bridged, at least one metal selected from elements from group VIB and/or group VIII of the periodic table, boron and/or silicon, optionally phosphorous, optionally at least one group VIIA element, and optionally at least one group VIIB element. The invention also concerns the use of the catalyst for hydrocracking hydrocarbon-containing feeds.

9. 发明授权

US06235670B1 Catalyst comprising a phyllosilicate containing boron and/or silicon, and a hydrocracking process 失效
标题翻译：包含含有硼和/或硅的页硅酸盐以及加氢裂化方法的催化剂
公开(公告)号：US06235670B1
公开(公告)日：2001-05-22
申请号：US09310182
申请日：1999-05-12
申请人： Eric Benazzi , Slavik Kasztelan , Nathalie George-Marchal
发明人： Eric Benazzi , Slavik Kasztelan , Nathalie George-Marchal
IPC分类号： B01J2116
CPC分类号： B01J21/16 , B01J23/85 , C10G47/20
摘要： The invention concerns a catalyst comprising at least one matrix, at least one dioctahedral 2:1 phyllosilicate which is optionally synthesized in a fluorine-containing medium and optionally bridged, at least one metal selected from elements from group VIB and/or group VIII of the periodic table, boron and/or silicon, optionally phosphorous, optionally at least one group VIIA element, and optionally at least one group VIIB element. The invention also concerns the use of the catalyst for hydrocracking hydrocarbon-containing feeds.
摘要翻译：本发明涉及一种催化剂，其包含至少一种基质，至少一种二（双八面体）2：1页硅酸盐，其任选地在含氟介质中合成，并任选地桥接至少一种选自VIB族和/或第VIII族元素的金属周期表，硼和/或硅，任选的磷，任选的至少一个VIIA族元素和任选的至少一个VIIB族元素。本发明还涉及催化剂用于加氢裂化含烃原料的用途。

10. 发明授权

US06117307A Catalyst comprising a NU-88 zeolite and its use for hydroconverting hydrocarbon-containing petroleum feeds 失效
标题翻译：包含NU-88沸石的催化剂及其用于加氢转化含烃石油原料的用途
公开(公告)号：US06117307A
公开(公告)日：2000-09-12
申请号：US253012
申请日：1999-02-19
申请人： Eric Benazzi , Nathalie George-Marchal , Slavik Kasztelan
发明人： Eric Benazzi , Nathalie George-Marchal , Slavik Kasztelan
IPC分类号： B01J29/04 , B01J29/06 , B01J29/72 , B01J29/76 , B01J29/78 , C01B39/48 , C10G47/16
CPC分类号： C10G47/16 , B01J29/04 , B01J29/76 , C01B39/48
摘要： An NU-88 zeolite and a hydrocracking catalyst comprising at least one matrix, a NU-88 zeolite, at least one group VIB or VII metal, a phosphorous, boron or silicon promoter, optionally at least one group VIIA element, and optionally at least one group VIIB element, and also the use of the catalyst for hydrocracking hydrocarbon feeds.
摘要翻译： NU-88沸石和加氢裂化催化剂，其包含至少一种基体，NU-88沸石，至少一种VIB或VII族金属，磷，硼或硅促进剂，任选至少一种VIIA族元素，以及任选地至少一组VIIB元素，以及催化剂用于加氢裂化烃进料的用途。

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