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    • 6. 发明授权
    • Process for removing isobutene from a C.sub.4 cut and producing methyl
tert-butyl ether
    • 从C4馏分除去异丁烯并生产甲基叔丁基醚的方法
    • US4324924A
    • 1982-04-13
    • US143242
    • 1980-04-24
    • Bernard TorckAlaio ConversDidier DueePaul Mikitenko
    • Bernard TorckAlaio ConversDidier DueePaul Mikitenko
    • C07C41/06C07C7/00
    • C07C41/06
    • Process for producing methyl tert-butyl ether (MTBE) by reacting methanol with the isobutene present in a C.sub.4 cut in a proportion from 10 to 60%, wherein said cut, admixed with methanol is contacted, in a first reaction zone, with an acid catalyst in the conditions of etherification of isobutene by methanol unit 93 to 98% of the isobutene has been converted, the reaction product is fractionated under at least 10 bars to a bottom fraction consisting essentially of MTBE and a top fraction which is contacted, in a second reaction zone, with an acid catalyst, under the conditions of etherification of isobutene by methanol, until at least 99% of the initial isobutene has been converted, the resulting product is washed with water and separated into a residual C.sub.4 cut which is discharged and an aqueous phase wherefrom methanol is recovered by distillation.
    • 通过使甲醇与存在于C 4馏分中的异丁烯以10至60%的比例反应生产甲基叔丁基醚(MTBE)的方法,其中所述与甲醇混合的切割在第一反应区与酸 催化剂在甲醇单元醚化异丁烯条件下已经转化为93至98%的异丁烯,将反应产物在至少10巴下分馏至基本上由MTBE组成的底部馏分和与 第二反应区用酸催化剂在异丁烯用甲醇醚化的条件下,直到初始异丁烯的至少99%已经转化,所得产物用水洗涤并分离成残留的C4馏分,其被排出, 通过蒸馏回收甲醇的水相。