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    • 9. 发明申请
    • WIDELY WAVELENGTH TUNEABLE POLYCHROME COLLOIDAL PHOTONIC CRYSTAL DEVICE
    • 宽带波长可调谐聚合胶体光电晶体装置
    • US20080224103A1
    • 2008-09-18
    • US12046313
    • 2008-03-11
    • Andre ArsenaultHernan MiguezIan MannersGeoffrey Alan Ozin
    • Andre ArsenaultHernan MiguezIan MannersGeoffrey Alan Ozin
    • H01B1/12
    • B82Y20/00C09K2019/0496G02B6/1225G02F1/01G02F1/19G02F1/21G02F2201/305G02F2201/346G02F2202/022G02F2202/32G02F2203/055Y10T428/1023
    • The present invention discloses a widely wavelength tunable polychrome colloidal photonic crystal device whose optical Bragg diffraction stop bands and higher energy bands wavelength, width and intensity can be tuned in a continuous and fine, rapid and reversible, reproducible and predictable fashion and over a broad spectral range by a controlled expansion or contraction of the colloidal photonic lattice dimension, effected by a predetermined change in the electronic configuration of the composite material. In its preferred embodiment, the material is a composite in the form of a film or a patterned film or shape of any dimension or array of shapes of any dimension comprised of an organized array of microspheres in a matrix of a cross-linked metallopolymer network with a continuously variable redox state of charge and fluid content. The chemo-mechanical and electro-mechanical optical response of the colloidal photonic crystal-metallopolymer gel is exceptionally fast and reversible, attaining its fully swollen state from the dry shrunken state and vice versa on a sub-second time-scale. These composite materials can be inverted by removal of the constituent microspheres from the aforementioned colloidal photonic crystal metallopolymer-gel network to create a macroporous metallopolymer-gel network inverse colloidal photonic crystal film or patterned film or shape of any dimension optical Bragg diffraction stop bands and higher energy bands wavelength, width and intensity can be redox tuned in a continuous and fine, rapid and reversible, reproducible and predictable fashion and over a broad spectral range by a controlled expansion or contraction of the colloidal photonic lattice dimensions.
    • 本发明公开了一种广泛波长可调谐的多色胶体光子晶体器件,其光学布拉格衍射阻挡带和更高能带的波长,宽度和强度可以以连续和精细,快速和可逆,可再现和可预测的方式调谐,并且在宽光谱 通过胶体光子晶格尺寸的受控扩展或收缩,由复合材料的电子构型的预定变化来实现。 在其优选实施方案中,该材料是膜或图案化膜的形式的复合材料或任何尺寸或任何尺寸形状阵列的形状的复合材料,其包含在交联金属聚合物网络的基质中的有组织的微球阵列, 不断变化的氧化还原电荷和流体含量。 胶体光子晶体金属聚合物凝胶的化学机械和机电光学响应特别快速和可逆,在亚秒级时间范围内从干收缩状态获得完全膨胀的状态,反之亦然。 这些复合材料可以通过从上述胶体光子晶体金属聚合物 - 凝胶网络中除去组成微球而反转,以产生大孔金属聚合物 - 凝胶网络反胶体光子晶体膜或任何尺寸的光学布拉格衍射阻带的图案化膜或更高的形状 能带的波长,宽度和强度可以通过胶体光子晶格尺寸的受控扩展或收缩,以连续和精细,快速和可逆,可再现和可预测的方式以及在宽光谱范围内进行氧化还原。