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1. 发明授权

US5068213A Components and catalysts for the polymerization of olefins 失效
公开(公告)号：US5068213A
公开(公告)日：1991-11-26
申请号：US675234
申请日：1991-03-26
申请人： Enrico Albizzati , Giampiero Morini , Umberto Giannini , Luisa Barino , Raimondo Scordamaglia , BarbePier C. , Luciano Noristi
发明人： Enrico Albizzati , Giampiero Morini , Umberto Giannini , Luisa Barino , Raimondo Scordamaglia , BarbePier C. , Luciano Noristi
IPC分类号： C08F4/658 , C08F4/60 , C08F4/646 , C08F4/649 , C08F4/652 , C08F4/654 , C08F10/00 , C08F110/06
CPC分类号： C08F10/00
摘要： Catalyst components for the polymerization of olefins comprising a titanium halide or alkoxyhalide and an electron-donor compound selected from ethers having two or more ether groups and containing at least one heteroatom selected from the group consisting of N, S, P, Si, non-ether O and halogen atoms or at least one double bond, or both at least one heteroatom and at least one double bond, supported on a magnesium halide in active form.Catalysts obtained from said catalyst components and an Al-alkyl compound, as well as catalysts obtained by the reaction of an Al-alkyl compound and an ether having the above defined characteristics with a solid catalyst component comprising a titanium halide or alkoxyhalide and an electron-donor compound having particular characteristics of extractability with Al-triethyl, supported on activated magnesium halide.

2. 发明授权

US4978648A Catalysts for the polymerization of olefins 失效
公开(公告)号：US4978648A
公开(公告)日：1990-12-18
申请号：US413430
申请日：1989-09-27
申请人： Pier C. Barbe , Luciano Noristi , Raimondo Scordamaglia , Luisa Barino , Enrico Albizzati , Umberto Giannini , Giampiero Morini
发明人： Pier C. Barbe , Luciano Noristi , Raimondo Scordamaglia , Luisa Barino , Enrico Albizzati , Umberto Giannini , Giampiero Morini
IPC分类号： C08F4/658 , C08F4/10 , C08F4/52 , C08F4/60 , C08F4/646 , C08F4/652 , C08F10/00 , C08F10/10 , C08F110/06
CPC分类号： C08F10/00
摘要： Catalysts for the polymerization of olefins, particularly alpha-olefin of the formula CH.sub.2 .dbd.CHR in which R is an alkyl radical with 1-6 carbon atoms or an aryl radical, obtained by the reaction of:(a) an Al-alkyl compound;(b) an ether containing at least two ether groups which can form complexes with anhydrous magnesium dichloride, under standard conditions of reaction, in an amount less than 60 mmol per 100 g Mg dichloride; and(c) a solid catalyst component comprising an anhydrous magnesium dihalide in active form and having supported thereon a titanium compound containing at least a Ti-halogen bond and an electron-donor compound which is at least 70 mole % extractable with Al-triethyl, under standard conditions of extraction, component wherein the solid, after extraction, has a surface area of more than 20 m.sup.2 g.

3. 发明授权

US4971937A Components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US4971937A
公开(公告)日：1990-11-20
申请号：US413410
申请日：1989-09-27
申请人： Enrico Albizzati , Pier C. Barbe , Luciano Noristi , Raimondo Scordamaglia , Luisa Barino , Umberto Giannini , Giampiero Morini
发明人： Enrico Albizzati , Pier C. Barbe , Luciano Noristi , Raimondo Scordamaglia , Luisa Barino , Umberto Giannini , Giampiero Morini
IPC分类号： C08F4/658 , C08F4/60 , C08F4/646 , C08F4/654 , C08F4/659 , C08F10/00 , C08F10/06 , C08F110/06
CPC分类号： C08F10/00 , C08F110/06
摘要： Solid catalyst components for the polymerization of olefins and modified with electron-donor compounds, comprising a titanium halide supported on a magnesium dihalide in active form and containing as an electron-donor compound a di- or other polyether having specific reactivity characteristics towards MgCl.sub.2 and TiCl.sub.4.

4. 发明授权

US5468704A Components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US5468704A
公开(公告)日：1995-11-21
申请号：US315747
申请日：1994-09-30
申请人： Giampiero Morini , Enrico Albizzati , Umberto Giannini , Raimondo Scordamaglia , Luisa Barino
发明人： Giampiero Morini , Enrico Albizzati , Umberto Giannini , Raimondo Scordamaglia , Luisa Barino
IPC分类号： B01J27/138 , B01J31/02 , B01J31/26 , B01J31/38 , C07C45/45 , C07C45/68 , C07C49/12 , C07C49/784 , C08F4/60 , C08F4/64 , C08F4/649 , C08F4/654 , C08F10/00
CPC分类号： B01J31/0204 , B01J27/138 , B01J31/0208 , B01J31/0237 , B01J31/0274 , B01J31/26 , B01J31/38 , C07C45/455 , C07C45/68 , C07C49/12 , C07C49/784 , C08F10/00
摘要： Disclosed is a catalyst for the polymerization of olefins, which includes the product of the reaction between an Al-alkyl compound and a solid catalyst component containing a magnesium halide in active form, a titanium compound and an electron-donor selected from the 1,3-diketones of formula: ##STR1## wherein the radicals R are the same or different, the radicals R.sup.I are the same or different, and R and R.sup.I are C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.20 cycloalkyl, C.sub.6 -C.sub.12 aryl, C.sub.7 -C.sub.20 arylalkyl or alkylaryl radicals or hydrogen, with the proviso that at least one of the R radicals is not hydrogen and can be bonded with the other R radical to form a cyclic structure, and at least one of the R.sup.I radicals, which are not bonded to one another to form a cyclic structure, is a branched alkyl, cycloalkyl or aryl radical, or is bonded to one or both R radicals to form a cyclic structure.
摘要翻译：公开了一种用于烯烃聚合的催化剂，其包括含有活性形式的卤化镁的Al-烷基化合物和固体催化剂组分之间的反应的产物，钛化合物和选自1,3 式：其中基团R相同或不同，基团R 1相同或不同，并且R和R 1是C 1 -C 20烷基，C 3 -C 20环烷基，C 6 -C 12芳基，C 7 -C 20 芳基烷基或烷基芳基或氢，条件是R基团中的至少一个不是氢并且可以与其它R基团键合以形成环状结构，并且至少一个RI基团不与彼此形成环状结构，是支链烷基，环烷基或芳基，或者与一个或两个R基团结合形成环状结构。

5. 发明授权

US5106807A Components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US5106807A
公开(公告)日：1992-04-21
申请号：US638289
申请日：1991-01-04
申请人： Giampiero Morini , Enrico Albizzati , Umberto Giannini , Luisa Barino , Raimondo Scordamaglia , Elisabetta Barbassa
发明人： Giampiero Morini , Enrico Albizzati , Umberto Giannini , Luisa Barino , Raimondo Scordamaglia , Elisabetta Barbassa
IPC分类号： C08F4/658 , C08F4/60 , C08F4/649 , C08F10/00
CPC分类号： C08F10/00
摘要： Disclosed are solid catalyst components for the polymerization of olefins comprising a titanium halide or titanium alkoxy halide, and an electron-donor compound selected from silicon compounds of the formula ##STR1## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrocarbyl radicals, supported on a magnesium halide in active form.Also disclosed are catalysts obtained from said catalyst components and from an Al-alkyl compound, as well as catalysts obtained by the reaction of an Al-alkyl compound and a silicon compound of the formula above with a solid catalyst component comprising a titanium halide or halogen alcoholate and an electron-donor compound having specific characteristics of extractability with Al-triethyl, supported on an active magnesium halide.

6. 发明授权

US4980329A Catalyst component and catalyst for the polymerization of alpha-olefins to stereoregular polymers having narrow molecular weight distribution 失效
标题翻译：用于将α-烯烃聚合成具有窄分子量分布的立体规则聚合物的催化剂组分和催化剂
公开(公告)号：US4980329A
公开(公告)日：1990-12-25
申请号：US353223
申请日：1989-05-15
申请人： Pier C. Barbe , Enrico Albizzati , Umberto Giannini , Giovanni Baruzzi , Luciano Noristi
发明人： Pier C. Barbe , Enrico Albizzati , Umberto Giannini , Giovanni Baruzzi , Luciano Noristi
IPC分类号： B01J37/00 , B01J31/38 , C08F4/60 , C08F4/64 , C08F4/643 , C08F4/654 , C08F10/00
CPC分类号： C08F10/00
摘要： Disclosed is a component for a catalyst for the polymerization of alpha-olefins to stereoregular polymers having narrow molecular weight distribution. The product is formed by the reaction of a solid catalyst-forming component comprising (1) a Ti compound having at least one Ti-halogen bond and (2) optionally, an electron-donor compound, supported on an anhydrous Mg dihalide in active form, with certain amounts of an organic compound (AH) containing at least one active hydrogen atom, in the presence of a liquid medium which is inert with respect to the Ti compound and the other components of the catalyst component, and which has a dielectric constant greater than 2 at 20.degree. C.Catalysts comprising the reaction product of the solid catalyst component prepared as above described, with an Al-alkyl compound and an electron-donor compound are also disclosed.
摘要翻译：公开了用于将α-烯烃聚合成具有窄分子量分布的立体规则聚合物的催化剂的组分。该产物是由固体催化剂形成组分反应形成的，该组分包含（1）具有至少一个Ti-卤素键的Ti化合物和（2）任选的电子给体化合物，负载在活性形式的无水Mg二卤化物上在一定量的含有至少一个活性氢原子的有机化合物（AH）的存在下，相对于Ti化合物和催化剂组分的其它组分是惰性的，并且具有介电常数在20℃下大于2的催化剂也包括如上所述制备的固体催化剂组分与烷基铝化合物和电子给体化合物的反应产物。

7. 发明授权

US5508245A Spherical components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的球形组分和催化剂
公开(公告)号：US5508245A
公开(公告)日：1996-04-16
申请号：US979243
申请日：1992-11-20
申请人： Giampiero Morini , Enrico Albizzati , Umberto Giannini , Matteo Nicolini
发明人： Giampiero Morini , Enrico Albizzati , Umberto Giannini , Matteo Nicolini
IPC分类号： C08F4/60 , C08F4/68 , C08F10/00 , B01D31/00 , C08F4/02
CPC分类号： C08F10/00
摘要： Spherical components of catalysts for the polymerization of olefins comprising:(a) a vanadium compound selected from the compounds of formula VOX.sub.2 Y or VX.sub.n Y.sub.n-4n, where X is Cl or Br and Y is Cl, Br OR or NR.sup.I.sub.2(b) MgCl.sub.2 in spherical form.Said components have an average diameter greater than 1 .mu.m, a surface area of at least 10 m.sup.2 /g, a porosity of at least 0.1 g/cm.sup.3 and an X-ray spectrum having particular characteristics.
摘要翻译：用于烯烃聚合的催化剂的球形组分包括：（a）选自式VOX2Y或VXnYn-4n的化合物的钒化合物，其中X是Cl或Br，Y是Cl，Br OR或NRI2（b）球形中的MgCl 2 形成。所述组分具有大于1μm的平均直径，至少10m 2 / g的表面积，至少0.1g / cm 3的孔隙率和具有特定特征的X射线谱。

8. 发明授权

US5122492A Components and catalysts for the polymerization of olefins 失效
公开(公告)号：US5122492A
公开(公告)日：1992-06-16
申请号：US628526
申请日：1990-12-14
申请人： Enrico Albizzati , Giampiero Morini , Umberto Giannini
发明人： Enrico Albizzati , Giampiero Morini , Umberto Giannini
IPC分类号： C08F4/658 , C07F7/28 , C08F4/60 , C08F4/646 , C08F4/654 , C08F10/00
CPC分类号： C08F10/00
摘要： Catalyst components for the polymerization of olefins and catalysts obtained therefrom, said components comprising a porous metal oxide on which a magnesium dihalide, and a titanium halide or titanium halogen alcoholate and a compound containing two or more ether groups having specific reactivity properties towards MgCl.sub.2 and TiCl.sub.4 are supported.

9. 发明授权

US5049535A Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US5049535A
公开(公告)日：1991-09-17
申请号：US471901
申请日：1990-01-30
申请人： Luigi Resconi , Umberto Giannini , Enrico Albizzati
发明人： Luigi Resconi , Umberto Giannini , Enrico Albizzati
IPC分类号： C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65922 , Y10S526/943
摘要： Catalysts for the polymerization of olefins, obtained from special zirconocenic compounds and from alkyl-Al compounds.

10. 发明授权

US4277589A Components of catalysts useful for the polymerization of alpha-olefins, and catalysts prepared therefrom 失效
标题翻译：可用于α-烯烃聚合的催化剂组分和由其制备的催化剂
公开(公告)号：US4277589A
公开(公告)日：1981-07-07
申请号：US105912
申请日：1979-12-21
申请人： Umberto Giannini , Enrico Albizzati , Sandro Parodi
发明人： Umberto Giannini , Enrico Albizzati , Sandro Parodi
IPC分类号： C08F4/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/654 , C08F10/00 , C08F10/06
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/901 , Y10S526/902 , Y10S526/906
摘要： There are disclosed new solid catalyst-forming components for use in preparing catalysts for the stereoregular polymerization of alpha-olefins containing at least 3 carbon atoms, mixtures of alpha-olefins with one another and/or with ethylene, said components being obtained by reacting(a) at least one hydrocarbon-soluble halogenated Ti compound;(b) a product comprising a Mg dihalide obtained by decomposition of an adduct of at least a Mg dihalide and an electron-donor compound present in the adduct in an amount of at least 0.5 mole per mole of Mg dihalide, the decomposition product being characterized in that, in its X-rays powder spectrum, instead of the diffraction line of maximum intensity which appears in the X-rays powder spectrum of the normal Mg dihalide, a halo appears whose intensity maximum is shifted with respect to said line, and(c) an electron-donor compound which does not contain active hydrogen atoms.The electron-donor compound (c) can be reacted with (a) or combined with (b) before the reaction of (a) and (b).Methods for preparing the new catalyst-forming components, catalysts obtained therefrom, and use of the catalysts for the production of crystalline homo- and co-polymers of the alpha-olefins are also disclosed.
摘要翻译：公开了用于制备含有至少3个碳原子的α-烯烃，α-烯烃彼此和/或与乙烯的混合物的立构规整聚合的催化剂的新的固体催化剂形成组分，所述组分通过使（ a）至少一种烃溶性卤化Ti化合物; （b）通过将至少二氢卤化镁的加合物和加合物中存在的电子给体化合物的摩尔量相对于每摩尔二卤化镁至少为0.5摩尔的量分解得到的二卤化镁的产物，分解产物的特征在于因为在其X射线粉末光谱中，代替在正常Mg二卤化物的X射线粉末光谱中出现的最大强度的衍射线，出现其强度最大值相对于所述线移动的晕圈，（ c）不含活性氢原子的电子给体化合物。电子给体化合物（c）可以在（a）和（b）的反应之前与（a）或（b）反应。还公开了制备新催化剂形成组分的方法，由其获得的催化剂，以及用于生产α-烯烃的结晶均聚物和共聚物的催化剂的用途。

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