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1. 发明授权

US5260094A Preparing densified low porosity titania sol-gel forms 失效
标题翻译：制备致密的低孔隙二氧化钛溶胶 - 凝胶形式
公开(公告)号：US5260094A
公开(公告)日：1993-11-09
申请号：US966439
申请日：1992-10-26
申请人： Emmanuel P. Giannelis , Joseph L. Keddie
发明人： Emmanuel P. Giannelis , Joseph L. Keddie
IPC分类号： C01G23/053 , B05D5/12 , B05D5/06
CPC分类号： C01G23/053 , C01P2004/03
摘要： Low porosity titania forms containing only a small amount of hydroxyl groups and possessing a high refractive index which are property stable regardless of humidity level and which prohibit electrical and gas leakage and optical loss, are obtained in a sol-gel process by rapidly heating to curing temperature, e.g. at a rate of 8000.degree. C./min. One application provides more stable, longer-lasting sol-gel prepared optical interference filters. Other applications provide capacitors with high capacitance and optical planar waveguides.
摘要翻译：通过快速加热固化，可以在溶胶 - 凝胶法中获得低含量二氧化钛形式，其仅含有少量羟基并且具有与溶剂 - 凝胶法相同的性质稳定的高湿度水平的高折射率，并且阻止电气和气体的泄漏和光学损耗温度，例如以8000℃/分钟的速度。一种应用提供更稳定，更持久的溶胶 - 凝胶制备的光学干涉滤光片。其他应用提供具有高电容和光学平面波导的电容器。

2. 发明授权

US5202152A Synthesis of titanium nitride films 失效
标题翻译：合成氮化钛膜
公开(公告)号：US5202152A
公开(公告)日：1993-04-13
申请号：US782401
申请日：1991-10-25
申请人： Emmanuel P. Giannelis , Joseph L. Keddie , Y. Y. Shacham-Diamond
发明人： Emmanuel P. Giannelis , Joseph L. Keddie , Y. Y. Shacham-Diamond
IPC分类号： H01L21/288
CPC分类号： H01L21/288
摘要： A substantially stoichiometric film of titanium nitride is provided by heating a substrate upon which a solution containing titanium has been applied at a substantially ambient temperature to provide a gel-film containing titanium on the surface of the substrate in an ammonia atmosphere. The substrate is heated to a temperature at which the titanium in the titanium-containing gel-film is substantially completely transformed to a substantially stoichiometric titanium nitride film, and at a rate of temperature change that is great enough to prevent the formation of nonstoichiometric titanium nitride compounds or other undesired titanium compounds in the resulting titanium nitride film. The invention is particularly suited for use in microelectronic devices.
摘要翻译：通过加热在基本上环境温度下涂覆有钛的溶液的基底来提供基本上化学计量的氮化钛膜，以在氨气氛中在基板的表面上提供含有钛的凝胶膜。将基板加热到含钛凝胶膜中的钛基本上完全转变为基本上为化学计量的氮化钛膜的温度，并且以足以防止形成非化学计量的氮化钛的温度变化速率化合物或其它不需要的钛化合物。本发明特别适用于微电子器件。

3. 发明授权

US5219611A Preparing densified low porosity titania sol gel forms 失效
标题翻译：制备致密的低孔隙二氧化钛溶胶凝胶形式
公开(公告)号：US5219611A
公开(公告)日：1993-06-15
申请号：US767471
申请日：1991-09-30
申请人： Emmanuel P. Giannelis , Joseph L. Keddie
发明人： Emmanuel P. Giannelis , Joseph L. Keddie
IPC分类号： C04B35/46 , C01G23/053 , G02B1/00 , G02B6/13
CPC分类号： C01G23/053 , G02B6/13 , C01P2004/03
摘要： Low porosity titania forms containing only a small amount of hydroxyl groups and possessing a high refractive index which are property stable regardless of humidity level and which prohibit electrical and gas leakage and optical loss, are obtained in a sol-gel process by rapidly heating to curing temperature, e.g. at a rate of 8000.degree. C./min. One application provides more stable, longer-lasting sol-gel prepared optical interference filters. Other applications provide capacitors with high capacitance and optical planar waveguides.
摘要翻译：通过快速加热固化，可以在溶胶 - 凝胶法中获得低含量二氧化钛形式，其仅含有少量羟基并且具有与溶剂 - 凝胶法相同的性质稳定的高湿度水平的高折射率，并且阻止电气和气体的泄漏和光学损耗温度，例如以8000℃/分钟的速度。一种应用提供更稳定，更持久的溶胶 - 凝胶制备的光学干涉滤光片。其他应用提供具有高电容和光学平面波导的电容器。

4. 发明申请

US20140004583A1 MESOPOROUS CATALYSTS OF MAGNETIC NANOPARTICLES AND FREE-RADICAL-PRODUCING ENZYMES, AND METHODS OF USE 有权
标题翻译：磁性纳米粒子和自由生产酶的多孔催化剂及其使用方法
公开(公告)号：US20140004583A1
公开(公告)日：2014-01-02
申请号：US14004311
申请日：2012-03-09
申请人： Stephane C. Corgie , Patarawan Kahawong , Emmanuel P. Giannelis , Larry P. Walker
发明人： Stephane C. Corgie , Patarawan Kahawong , Emmanuel P. Giannelis , Larry P. Walker
IPC分类号： B01J31/00 , C02F3/34
CPC分类号： C12N11/14 , B01J31/003 , B01J35/0033 , B82Y30/00 , C02F3/342 , C02F2305/08 , C08H6/00 , C12N9/0004 , C12N9/0065 , C12P17/181 , C12P2201/00 , C12Y111/01007 , C12Y111/01013 , C12Y111/01014 , C12Y111/01016 , Y02P20/52
摘要： A composition comprising mesoporous aggregates of magnetic nanoparticles and free-radical producing enzyme (i.e., enzyme-bound mesoporous aggregates), wherein the mesoporous aggregates of magnetic nanoparticles have mesopores in which the free-radical-producing enzyme is embedded. Methods for synthesizing the enzyme-bound mesoporous aggregates are also described. Processes that use said enzyme-bound mesoporous aggregates for depolymerizing lignin, removing aromatic contaminants from water, and polymerizing monomers polymerizable by a free-radical reaction are also described.
摘要翻译：一种包含磁性纳米颗粒和自由基产生酶（即酶结合的介孔聚集体）的介孔聚集体的组合物，其中磁性纳米颗粒的介孔聚集体具有嵌入自由基产生酶的介孔。还描述了合成酶结合介孔聚集体的方法。还描述了使用所述酶结合的介孔聚集体解聚木质素，从水中除去芳族污染物和聚合通过自由基反应可聚合的单体的方法。

5. 发明授权

US08124230B2 Non-aggregating nanoparticles and the use thereof 失效
标题翻译：非聚集性纳米粒子及其用途
公开(公告)号：US08124230B2
公开(公告)日：2012-02-28
申请号：US12583078
申请日：2009-08-13
申请人： Paul A. Zimmerman , Aristeidis Bakandritsos , Michael F. Zettel , Markos Trikeriotis , Robert Rodriguez , Emmanuel P. Giannelis , Woo Jin Bae , Christopher K. Ober
发明人： Paul A. Zimmerman , Aristeidis Bakandritsos , Michael F. Zettel , Markos Trikeriotis , Robert Rodriguez , Emmanuel P. Giannelis , Woo Jin Bae , Christopher K. Ober
IPC分类号： B32B5/66
CPC分类号： C01G25/02 , B82Y30/00 , C01G23/047 , C01G27/00 , C01G27/02 , C01P2002/82 , C01P2004/64 , C01P2004/84 , C01P2006/22 , C01P2006/60 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/2996 , Y10T428/2998
摘要： The present invention relates generally to non-aggregating nanoparticles, including ligand capped metal oxide nanoparticles. Methods for their synthesis and methods for their use, for example, for improved immersion lithography processes, are also disclosed.
摘要翻译：本发明一般涉及非聚集纳米颗粒，包括配体封端的金属氧化物纳米颗粒。还公开了它们的合成方法及其使用方法，例如用于改进的浸没式光刻工艺。

6. 发明授权

US07148282B2 Composite of high melting polymer and nanoclay with enhanced properties 有权
标题翻译：具有增强性能的高熔点聚合物和纳米粘土的复合材料
公开(公告)号：US07148282B2
公开(公告)日：2006-12-12
申请号：US10739534
申请日：2003-12-19
申请人： Emmanuel P. Giannelis , Jin Zhu , Byoungkyeu Park , Kyung Hoon Seo
发明人： Emmanuel P. Giannelis , Jin Zhu , Byoungkyeu Park , Kyung Hoon Seo
IPC分类号： C08K9/00 , C08K9/06 , C08K3/34 , B32B27/36 , B32B27/18
CPC分类号： C08K3/346 , B82Y30/00 , C08F8/44 , C08K2201/011 , Y10T428/31507 , C08F212/08
摘要： A composite of a polyester, e.g., a polycarbonate, and a nanoclay (layered silicate) cation exchanged with a quaternized copolymer of styrene and 2-(dimethylamine) ethyl methacrylate is provided, the composite being useful for preparing injection molded objects and after injection molding being transparent and without coloration and has enhanced modulus and strength compared to neat polyester and does not have loss of elongation and toughness compared to neat polyester.
摘要翻译：提供了聚酯，例如聚碳酸酯和与苯乙烯和甲基丙烯酸2-（二甲胺）乙酯的季铵化共聚物交换的纳米粘土（层状硅酸盐）阳离子的复合物，该复合物可用于制备注射成型物体和注射成型透明且无着色，并且与纯聚酯相比具有增强的模量和强度，并且与纯聚酯相比不具有伸长和韧性损失。

7. 发明授权

US5032547A Organic-inorganic composites 失效
标题翻译：有机 - 无机复合材料
公开(公告)号：US5032547A
公开(公告)日：1991-07-16
申请号：US486335
申请日：1990-02-28
申请人： Emmanuel P. Giannelis , Vivek Mehrota
发明人： Emmanuel P. Giannelis , Vivek Mehrota
IPC分类号： C03C10/04 , C08F292/00 , C08K3/16 , C08K3/34 , C08K3/38 , C09C1/00 , H01B1/12 , H01B3/00 , H01B3/04
CPC分类号： H01B3/04 , C08F292/00 , C08K3/16 , C08K3/346 , C08K3/38 , C09C1/0081 , H01B1/128 , H01B3/006 , C01P2006/32 , C01P2006/40 , C01P2006/80 , C01P2006/90
摘要： This invention is principally directed to the production of an organic-inorganic composite body demonstrating electrical insulating behavior consisting essentially of lithium and/or sodium water-swelling mica crystals selected from the group of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally-compatible species selected from the group of talc, fluortalc, polyithionite, fluorpolylithionite, phlogopite, and fluorphlogopite, wherein the Li.sup.+ and/or Na.sup.+ ions from the interlayer of said lithium and/or sodium water-swelling mica crystals have been exchanged with ions of a transition metal having multiple oxidation states, the galleries of said crystals containing an organic polymer exhibiting very low permittivity. The preferred organic polymer exhibiting very low permittivity is the emeraldine base form of polyaniline. Where desired, an organic-inorganic composite body can be produced wherein the galleries of the crystals contain an organic polymer exhibiting electrical conductivity, that polymer being the protonated poly(semiquinone) form of polyaniline.
摘要翻译：本发明主要针对有机 - 无机复合体的制造，其表现出绝缘性能，主要由锂和/或钠水溶性云母晶体组成，该晶体选自氟代锂蒙脱石，羟基锂蒙脱石，氟氟云母，羟基硼金云母和那些和那些与其它结构上相容的物质之间的固体溶液，其选自滑石粉，氟软脂，多连结半硅氧烷，氟磷酸亚铁锂，金云母和荧光晶体，其中来自所述锂和/或钠水的中间层的Li +和/或Na +离子已经用具有多种氧化态的过渡金属的离子交换云母晶体，所述晶体的画廊含有显示非常低介电常数的有机聚合物。显示非常低的介电常数的优选的有机聚合物是聚苯胺的翠绿亚胺碱形式。在需要的地方，可以制备有机 - 无机复合体，其中晶体的画廊含有表现导电性的有机聚合物，聚合物是质子化的聚（半醌）形式的聚苯胺。

8. 发明申请

US20140319044A1 NANOPARTICLE-FUNCTIONALIZED MEMBRANES, METHODS OF MAKING SAME, AND USES OF SAME 审中-公开
标题翻译：纳米官能化膜，其制备方法及其用途
公开(公告)号：US20140319044A1
公开(公告)日：2014-10-30
申请号：US14122535
申请日：2012-05-29
申请人： Emmanuel P. Giannelis , Yue Wang , Menachem Elimelech , Alberto Tiraferri , Meagan S. Mauter
发明人： Emmanuel P. Giannelis , Yue Wang , Menachem Elimelech , Alberto Tiraferri , Meagan S. Mauter
IPC分类号： B01D71/68 , C02F3/12 , B01D61/00 , B01D61/14 , B01D69/12 , B01D61/02
CPC分类号： B01D71/68 , B01D61/002 , B01D61/025 , B01D61/027 , B01D61/145 , B01D61/147 , B01D65/08 , B01D67/009 , B01D67/0093 , B01D69/02 , B01D69/12 , B01D69/127 , B01D69/148 , B01D71/022 , B01D71/025 , B01D71/60 , B01D2321/16 , B01D2323/30 , B01D2325/48 , C02F1/44 , C02F1/441 , C02F1/442 , C02F1/444 , C02F1/445 , C02F3/1268 , C02F2305/08 , Y02W10/15
摘要： Nanoparticle functionalized membranes, where the surface of the membranes is nanoparticle functionalized. The nanoparticles closest to the membrane surface are covalently bonded to the membrane surface. For example, the membranes are forward osmosis, reverse osmosis, or ultrafiltration membranes. The membranes can be used in devices or water purification methods.
摘要翻译：纳米颗粒官能化膜，其中膜的表面是纳米颗粒官能化的。最接近膜表面的纳米颗粒共价键合到膜表面。例如，膜是正向渗透，反渗透或超滤膜。膜可用于装置或水净化方法。

9. 发明授权

US6010805A Ion conducting electrolyte material containing a lithium porphyrin complex 失效
标题翻译：含有卟啉络合物的离子导电电解质材料
公开(公告)号：US6010805A
公开(公告)日：2000-01-04
申请号：US87691
申请日：1998-05-26
申请人： Lawrence G. Scanlon, Jr. , Wlodzimierz T. Krawiec , Emmanuel P. Giannelis
发明人： Lawrence G. Scanlon, Jr. , Wlodzimierz T. Krawiec , Emmanuel P. Giannelis
IPC分类号： H01M6/18 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M2/14
CPC分类号： H01M10/052 , H01M10/0565 , H01M4/382 , H01M10/0525 , H01M6/181
摘要： New lithium ion conducting materials comprise porphyrin rings. These materials function as sites through which the lithium ion passes. In one aspect of the invention, an electrolyte composition consists essentially of a major amount of a lithium porphyrin complex and a minor amount of a polymer binder. In another aspect, an electrolyte composition consists essentially of aligned and spaced lithium porphyrin complex rings, wherein alignment and spacing of the porphyrin rings is achieved through the use of ladder type polymers, comb-like polymers, or crystalline polymers.
摘要翻译：新的锂离子导电材料包括卟啉环。这些材料用作锂离子通过的位置。在本发明的一个方面，电解质组合物主要由主要量的卟啉卟啉络合物和少量的聚合物粘合剂组成。在另一方面，电解质组合物基本上由对准和间隔开的卟啉络合环组成，其中通过使用梯型聚合物，梳状聚合物或结晶聚合物来实现卟啉环的取向和间隔。

10. 发明授权

US09849451B2 Nanoscale ionic material (NIM) compositions via acid/base reaction 有权
公开(公告)号：US09849451B2
公开(公告)日：2017-12-26
申请号：US14006395
申请日：2012-03-21
申请人： Emmanuel P. Giannelis , Nikhil Fernandes
发明人： Emmanuel P. Giannelis , Nikhil Fernandes
IPC分类号： B01J43/00 , C01B33/12 , C01B33/158 , C01B33/18 , B82Y30/00
CPC分类号： B01J43/00 , B82Y30/00 , C01B33/12 , C01B33/158 , C01B33/18 , C01P2004/62 , C01P2004/64
摘要： A nanoscale ionic material composition, such as but not limited to a nanoscale ionic solid material composition, a nanoscale ionic gel material composition or a nanoscale ionic liquid material composition, may be prepared using an acid/base reaction directly between: (1) one of an acid functional and a base functional inorganic metal oxide nanoparticle core absent an organofunctional corona; and (2) a corresponding complementary one of a basic and acidic functional organic polymer material canopy. Desirably, the nanoscale ionic material composition is formed absent an intervening chemical functionalization process step with respect to the inorganic metal oxide nanoparticle core that provides the corona, such as but not limited to a silane coupling agent chemical functionalization process step with respect to the inorganic metal oxide nanoparticle core to provide the corona.

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