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    • 1. 发明申请
    • Flame-retardant compounded polyester materials
    • 阻燃复合聚酯材料
    • US20090088512A1
    • 2009-04-02
    • US12231237
    • 2008-08-29
    • Elke SchlosserSebastian HoeroldUte SchwarzStefan Reinemann
    • Elke SchlosserSebastian HoeroldUte SchwarzStefan Reinemann
    • C08K3/34C08L69/00C08K3/40
    • C08L67/02C08K5/0066C08K5/5313C08L69/00C08L2666/18
    • The invention relates to flame-retardant compounded polyester materials, comprising as component A, from 40 to 64.9% by weight of thermoplastic polyester, as component B, from 5 to 10% by weight of polycarbonate, as component C, from 10 to 15% by weight of phosphinic salt of the formula (I) and/or diphosphinic salt of the formula (II), and/or polymers of these in which R1 and R2 are identical or different and are H or C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, or -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; and x is from 1 to 4, as component D, from 5 to 10% by weight of melamine polyphosphate, as component E, from 15 to 30% by weight of reinforcing materials, and, as component F, from 0.1 to 2% by weight of further additives, where the total of the components by weight is 100% by weight.
    • 本发明涉及阻燃复合聚酯材料,其包含作为组分A的40至64.9重量%的热塑性聚酯,作为组分B,5至10重量%的作为组分C的聚碳酸酯,10至15重量% 重量的式(I)的次膦酸盐和/或式(II)的二膦酸盐,和/或其中R 1和R 2相同或不同且为H或C 1 -C 6 - 烷基的那些的线性或 支链和/或芳基; R 3是C 1 -C 10亚烷基,直链或支链的C 6 -C 10亚芳基或 - 亚烷基亚芳基或芳基亚烷基; M是Mg,Ca,Al,Sb,Sn,Ge,Ti,Fe,Zr,Ce,Bi,Sr,Mn,Li,Na,K和/或质子化氮碱; m为1〜4; n为1至4; 作为组分D,x为1至4,5至10重量%的三聚氰胺多磷酸盐,作为组分E,15至30重量%的增强材料,和作为组分F,为0.1至2重量% 其他添加剂的重量,其中组分的总重量为100重量%。
    • 4. 发明申请
    • Flame Retardant-Stabilizer Combination For Thermoplastic Polymers
    • 阻燃稳定剂组合热塑性聚合物
    • US20130190432A1
    • 2013-07-25
    • US13878145
    • 2011-09-30
    • Werner KrauseHarald BauerMartin SickenSebastian HoeroldWolfgang WanzkeElke Schlosser
    • Werner KrauseHarald BauerMartin SickenSebastian HoeroldWolfgang WanzkeElke Schlosser
    • C08K5/5313C08K5/3492C08K5/10C08K3/22C08K5/5317C08K5/56C08K5/52C08K3/38
    • C08K5/5313C08K3/22C08K3/38C08K5/0008C08K5/10C08K5/34922C08K5/34924C08K5/52C08K5/5317C08K5/56
    • A novel flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20 to 99% by weight of a dialkylphosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 1 to 80% by weight of a salt of the phosphorous acid with the general formula (III) [HP(═O)O2]2−Mm+ (III) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K and m is 1 to 4, as component C 0 to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus/nitrogen flame retardant, as component D 0 to 10% by weight of a zinc salt and/or of a basic or amphoteric oxide, hydroxide, carbonate, silicate, borate, stannate, mixed oxide hydroxide, oxide hydroxide carbonate, hydroxide silicate and/or hydroxide borate and/or mixtures of these substances, as component E 0 to 3% by weight of a phosphonite and/or of a mixture of a phosphonite and a phosphite, and as component F 0 to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) which typically have chain lengths of C14 to C40, where the sum of the components is always 100% by weight.
    • 一种热塑性聚合物的新型阻燃稳定剂组合物,其包含作为组分A 20至99重量%的式(I)的二烷基次膦酸盐和/或式(II)的二膦酸盐和/或其聚合物 其中R 1,R 2相同或不同,并且各自为直链或支链的C 1 -C 6烷基; R3是C1-C10-亚烷基,直链或支链的C6-C10亚芳基,C7-C20-烷基亚芳基或C7-C20-芳基亚烷基; M是Mg,Ca,Al,Sb,Sn,Ge,Ti,Zn,Fe,Zr,Ce,Bi,Sr,Mn,Li,Na,K和/或质子化氮碱; m为1〜4; n为1〜4; x为1〜4,作为成分B,通式(III)的亚磷酸盐为1〜80重量%[HP(= O)O 2] 2 -Mm +(III),其中M为Mg,Ca ,Al,Sb,Sn,Ge,Ti,Zn,Fe,Zr,Ce,Bi,Sr,Mn,Li,Na和/或K和m为1〜4,作为组分C 0〜30重量% 含氮增效剂和/或磷/氮阻燃剂,作为组分D 0至10重量%的锌盐和/或碱性或两性氧化物,氢氧化物,碳酸盐,硅酸盐,硼酸盐,锡酸盐,混合氧化物 氢氧化物,氢氧化物碳酸盐,氢氧化硅酸盐和/或氢氧化物硼酸盐和/或这些物质的混合物,作为组分E 0至3重量%的亚膦酸盐和/或亚磷酸盐和亚磷酸盐的混合物,并且作为组分F 0至3重量%的通常具有C14至C40链长度的长链脂族羧酸(脂肪酸)的酯和/或盐,其中组分的总量总是为100重量%。
    • 6. 发明申请
    • Flame-Retardant Polyester Compounds
    • 阻燃聚酯化合物
    • US20130210968A1
    • 2013-08-15
    • US13878167
    • 2011-10-25
    • Sebastian HoeroldWolfgang WanzkeElke SchlosserBernd Nass
    • Sebastian HoeroldWolfgang WanzkeElke SchlosserBernd Nass
    • C08K5/5399C08K5/3492
    • C08K5/5399C08K5/3492C08K5/34922C08K5/53
    • The invention relates to flame-retardant polyester compounds comprising as component A 40% to 89.9% by weight of thermoplastic polyesters, as component B 5% to 25% by weight of phosphinic salt of the formula (V) and/or diphosphinic salt of the formula (VI) and/or polymers thereof, in which R1 and R2 are H or C1-C6-alkyl and/or aryl; R3 is C1-C10-alkylene, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; and x is 1 to 4, and as component C 5% to 25% by weight of a phosphazene, as component D 0% to 15% by weight of reaction products of melamine with phosphoric acid and/or condensed phosphoric acids, as component E 0% to 45% by weight of reinforcing agents, and as component F 0.1% to 3% by weight of further additives, the sum of the components by weight being 100% by weight.
    • 本发明涉及阻燃聚酯化合物,其包含作为组分A 40%至89.9%重量的热塑性聚酯,作为组分B 5%至25%重量的式(V)的次膦酸盐和/或二 式(VI)和/或其聚合物,其中R 1和R 2是H或C 1 -C 6 - 烷基和/或芳基; R3是C1-C10-亚烷基,C6-C10-亚芳基, - - 烷基亚芳基或 - 芳基亚烷基; M是Mg,Ca,Al,Sb,Sn,Ge,Ti,Fe,Zr,Ce,Bi,Sr,Mn,Li,Na,K和/或质子化氮碱; m为1〜4; n为1〜4; x为1〜4,作为成分C 5〜25重量%的磷腈,作为成分D的组分D为0〜15重量%的三聚氰胺与磷酸和/或缩合磷酸的反应产物,作为组分E 0〜45重量%的增强剂,作为成分F为0.1〜3重量%的其他添加剂,其重量份数为100重量%。
    • 7. 发明申请
    • Flame Retardant-Stabilizer Combination For Thermoplastic Polymers
    • 阻燃稳定剂组合热塑性聚合物
    • US20130109792A1
    • 2013-05-02
    • US13809716
    • 2011-07-06
    • Sebastian HoeroldWolfgang WanzkeElke Schlosser
    • Sebastian HoeroldWolfgang WanzkeElke Schlosser
    • C08K13/02
    • C08K13/02C08K5/0066C08K5/16C08K5/34922C08K5/524C08K5/5313
    • Flame retardant-stabilizer combination for thermoplastic polymersThe invention relates to a flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 30 to 79.9% by weight of a phosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each H, C1-C18-alkyl, C6-C18-aryl, C7-C18-arylalkyl and/or C7-C18-alkylaryl; R3 is linear or branched C1-C10-alkylene, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 20 to 50% by weight of a nitrogen-containing synergist or of a phosphorus/nitrogen flame retardant and as component C 0.1 to 20% by weight of a metal oxide and/or metal hydroxide coated with a metal salt, component C comprising 50 to 95% by weight of metal oxide and/or metal hydroxide and 5 to 50% by weight of metal salt and the sum of components A to C always being 100% by weight.
    • 用于热塑性聚合物的阻燃稳定剂组合物本发明涉及一种用于热塑性聚合物的阻燃剂 - 稳定剂组合物,其包含作为组分A 30至79.9重量%的式(I)的次膦酸盐和/或二 其中R 1,R 2相同或不同并且各自为H,C 1 -C 18 - 烷基,C 6 -C 18 - 芳基,C 7 -C 18 - 芳烷基和/或C 7 -C 18烷基芳基的式(II)和/或其聚合物 ; R3是直链或支链C1-C10-亚烷基,C6-C10-亚芳基, - 烷基亚芳基或 - 芳基亚烷基; M是Mg,Ca,Al,Sb,Sn,Ge,Ti,Zn,Fe,Zr,Ce,Bi,Sr,Mn,Li,Na,K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4,作为组分B 20至50重量%的含氮增效剂或磷/氮阻燃剂和作为组分C的0.1至20重量%的涂覆有金属氧化物和/或金属氢氧化物的组分 金属盐,包含50-95重量%的金属氧化物和/或金属氢氧化物和5-50重量%的金属盐的组分C,组分A至C的总和总是100重量%。