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1. 发明授权

US06613709B1 Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons 有权
标题翻译：包含至少一种结构类型为NES和铼的沸石的催化剂及其用于烷基芳烃的烷基转移的用途
公开(公告)号：US06613709B1
公开(公告)日：2003-09-02
申请号：US09642020
申请日：2000-08-21
申请人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
发明人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
IPC分类号： B01J2906
CPC分类号： C07C6/126 , B01J29/74 , B01J29/78 , B01J2229/16 , B01J2229/26 , B01J2229/36 , B01J2229/40 , B01J2229/42 , C07C2529/70
摘要： The present invention concerns a catalyst which contain at least one zeolite with structure type NES, preferably NU-87, comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron. Preferably, element T has been extracted so that the overall Si/T atomic ratio is more than 20. This zeolite is at least partially in its acid form. The binder is preferably alumina. The catalyst also contains at least one metal selected from the group formed by group VIIB, group VIB and iridium, preferably rhenium. Finally, the catalyst optionally also contains at least one metal selected from the group formed by elements from groups III and IV of the periodic table, preferably indium or tin. The present invention also concerns the use of the catalyst in a process for transalkylating alkylaromatic hydrocarbons such as toluene and alkylaromatic compounds containing at least 9 carbon atoms. In particular, this catalyst is highly effective in treating C9+ aromatic feeds containing more than 5% by weight of aromatic olefins containing 10 carbon atoms and more, this feed possibly also containing benzene.
摘要翻译：本发明涉及含有至少一种结构类型为NES，优选为NU-87的沸石的催化剂，其包含硅和选自由铝，铁，镓和硼形成的基团中的至少一种元素T. 优选地，提取元素T使得总Si / T原子比大于20.该沸石至少部分为其酸形式。粘合剂优选为氧化铝。该催化剂还含有选自由ⅦB族，ⅥB族和铱族，优选铼形成的族中的至少一种金属。最后，催化剂任选地还含有至少一种选自元素周期表III和IV族的元素形成的金属，优选为铟或锡。本发明还涉及催化剂在烷基化烷基芳烃如甲苯和含有至少9个碳原子的烷基芳族化合物的方法中的用途。特别地，该催化剂在处理含有大于5重量％的含有10个碳原子的芳族烯烃和更多的芳族烯烃的C9 +芳族原料方面是非常有效的，该进料还可能含有苯。

2. 发明授权

US06342200B1 Process for preparing a zeolite with structure type EUO 有权
标题翻译：制备结构型EUO的沸石的方法
公开(公告)号：US06342200B1
公开(公告)日：2002-01-29
申请号：US09432120
申请日：1999-11-02
申请人： Loic Rouleau , Sylvie Lacombe , Fabio Alario , Elisabeth Merlen , Frédéric Kolenda , Julia Magne-Drisch
发明人： Loic Rouleau , Sylvie Lacombe , Fabio Alario , Elisabeth Merlen , Frédéric Kolenda , Julia Magne-Drisch
IPC分类号： C01B3904
CPC分类号： B01J29/7023 , B01J20/18 , B01J29/04 , B01J2229/62 , C01B39/48 , C07C5/2708 , C07C2529/70 , C10G35/095 , C10G45/64 , Y02P20/588 , C07C15/067
摘要： The present invention concerns a process for preparing a zeolite with structure type EUO comprising at least one element X selected from silicon and germanium and at least one element T selected from iron, aluminium, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese, characterized in that seeds of at least one zeolitic material are used comprising at least one element X′ selected from silicon and germanium and at least one element T′ selected from iron, aluminium, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese with a ratio X′/T′ of less than 200, said seeds being different from the zeolite with structure type EUO being prepared. The present invention also concerns the use of the zeolite obtained as a catalyst in a process for converting hydrocarbon-containing feeds, as an adsorbent to control pollution and as a molecular sieve for separation, and more particularly as a catalyst in a process for isomerizing aromatic compounds containing 8 carbon atoms.
摘要翻译：本发明涉及一种制备具有结构型EUO的沸石的方法，该方法包括至少一种选自硅和锗的元素X和选自铁，铝，镓，硼，钛，钒，锆，钼，砷中的至少一种元素T ，锑，铬和锰，其特征在于使用至少一种沸石材料的种子，其包含至少一种选自硅和锗的元素X'和至少一种选自铁，铝，镓，硼，钛，钒，锆，钼，砷，锑，铬和锰，其比例X'/ T'小于200，所述种子与制备具有结构类型EUO的沸石不同。本发明还涉及在烃类进料转化方法中作为催化剂使用的沸石，作为用于控制污染的吸附剂和用于分离的分子筛，更特别地，作为用于异构化芳族化合物的方法中的催化剂含有8个碳原子的化合物。

3. 发明授权

US06486372B1 Catalyst based on dealuminated mordenite containing at least one metal from groups VI, VII or VIII, and its use for dismutation and/or transalkylation of aromatic hydrocarbons 失效
标题翻译：基于含有至少一种VI，VII或VIII族金属的脱铝丝光沸石的催化剂及其用于芳族烃的歧化和/或烷基转移的用途
公开(公告)号：US06486372B1
公开(公告)日：2002-11-26
申请号：US09056741
申请日：1998-04-08
申请人： Elisabeth Merlen , Fabio Alario
发明人： Elisabeth Merlen , Fabio Alario
IPC分类号： C07C268
CPC分类号： C07C6/123 , B01J29/18 , C07C6/126 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/16 , C07C2523/08 , C07C2523/14 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/755 , C07C2527/167 , C07C2529/22 , C07C2529/24 , Y02P20/52
摘要： A catalyst for transforming aromatic hydrocarbons, preferably for dismutation of toluene to produce benzene and xylenes and transalkylation of toluene and aromatic compounds containing at least 9 carbon atoms per molecule to produce xylenes, contains 40% to 90% by weight of a mordenite in its acid form in a proportion of and 10% to 60% by weight of binders. The mordenite comprises less than 0.1% by weight of sodium and has a Si02/A2O3 molar ratio of over 70. The catalyst also contains at least one metal from groups VI, VII or VIII and optionally an additional metal from groups III or IV.
摘要翻译：用于转化芳族烃的催化剂，优选用于歧化甲苯以产生苯和二甲苯，并且每分子含有至少9个碳原子的甲苯和芳族化合物的烷基转移以产生二甲苯，其在其酸中含有40重量％至90重量％的丝光沸石以10％至60％重量的粘合剂形式。丝光沸石包含小于0.1重量％的钠，SiO 2 / A 2 O 3的摩尔比为70以上。催化剂还含有至少一种VI，VII或VIII族金属和任选的III或IV族金属。

4. 发明授权

US06465705B1 Process for isomerizing aromatic C8 cuts in the presence of a catalyst based on mordenite containing at least one group VIII metal and at least one group III metal 有权
标题翻译：在基于含有至少一种VIII族金属和至少一种III族金属的丝光沸石的催化剂存在下异构化芳族C 8馏分的方法
公开(公告)号：US06465705B1
公开(公告)日：2002-10-15
申请号：US09630812
申请日：2000-08-02
申请人： Elisabeth Merlen , Fabio Alario
发明人： Elisabeth Merlen , Fabio Alario
IPC分类号： C07C522
CPC分类号： B01J29/20 , C07C5/2724 , C07C2521/04 , C07C2523/08 , C07C2523/14 , C07C2523/40 , C07C2523/42 , C07C2523/44 , C07C2523/74 , C07C2523/755 , C07C2529/22 , C07C2529/24 , Y02P20/52 , C07C15/067
摘要： The present invention relates to a process for isomerizing aromatic C8 cuts in the presence of a catalyst containing a mordenite which is slightly or not dealuminated and a binder. This mordenite is generally present at least in part in its acid form and its Si/Al atomic ratio is less than 20, preferably in the range 5 to 15, and more preferably in the range 5 to 10. The catalyst also contains at least one metal from group VIII of the periodic table, preferably selected from the group formed by palladium and platinum. Finally, the catalyst further contains at least one metal from group III of the periodic table, namely gallium, indium or thallium, preferably indium, and optionally at least one metal from group IV of the periodic table, namely germanium, tin or lead, preferably tin. The present invention also relates to the catalyst used in the isomerization process and to a process for its preparation.
摘要翻译：本发明涉及在含有轻微或不脱铝的丝光沸石的催化剂存在下使芳族C8馏分异构化的方法和粘合剂。该丝光沸石通常至少部分地以其酸形式存在，其Si / Al原子比小于20，优选在5至15范围内，更优选在5至10范围内。催化剂还含有至少一种元素周期表第VIII族的金属，优选选自钯和铂形成的基团。最后，催化剂还含有至少一种元素周期表III族金属，即镓，铟或铊，优选铟，以及任选的至少一种元素周期表IV族金属，即锗，锡或铅，优选锡。本发明还涉及用于异构化方法的催化剂及其制备方法。

5. 发明授权

US06313363B1 Process for isomerizing aromatic compounds containing eight carbon atoms 有权
标题翻译：异构化含有8个碳原子的芳族化合物的方法
公开(公告)号：US06313363B1
公开(公告)日：2001-11-06
申请号：US09289655
申请日：1999-04-12
申请人： Jean-François Joly , Julia Magne-Drisch , Fabio Alario , Elisabeth Merlen , Eric Benazzi , Sylvie Lacombe
发明人： Jean-François Joly , Julia Magne-Drisch , Fabio Alario , Elisabeth Merlen , Eric Benazzi , Sylvie Lacombe
IPC分类号： C07C522
CPC分类号： B01J29/7023 , B01J29/068 , B01J29/18 , B01J29/22 , B01J29/74 , B01J29/7446 , B01J33/00 , B01J37/20 , B01J2229/26 , B01J2229/42 , C07C5/2702 , Y02P20/52 , Y02P20/582 , Y10S585/906 , C07C15/08
摘要： The present invention relates to a process for isomerizing aromatic compounds containing 8 carbon atoms, the catalysts containing at least one group VIII metal, comprising at least one sulfurization step and at least one passivation step using ammonia.
摘要翻译：本发明涉及使含有8个碳原子的芳族化合物异构化的方法，含有至少一种第Ⅷ族金属的催化剂，其包括至少一个硫化步骤和至少一个使用氨的钝化步骤。

6. 发明申请

US20050256355A1 Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons 审中-公开
标题翻译：包含至少一种结构类型为NES和铼的沸石的催化剂及其用于烷基芳烃的烷基转移的用途
公开(公告)号：US20050256355A1
公开(公告)日：2005-11-17
申请号：US11048751
申请日：2005-02-03
申请人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
发明人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
IPC分类号： B01J29/06 , B01J29/78 , C07C6/12 , C10G45/64
CPC分类号： B01J29/78 , B01J2229/42 , C07C6/126 , C07C2523/28 , C07C2529/70 , C07C2529/78 , C10G45/64
摘要： The present invention concerns catalysts which contain at least one zeolite with structure type NES, preferably NU-87, comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron. Preferably, element T has been extracted so that the overall Si/T atomic ratio is more than 20. This zeolite is at least partially in its acid form. The binder is preferably alumina. The catalyst also contains at least one metal selected from the group formed by group VIIB, group VIB and iridium, preferably molybdenum. Finally, the catalyst optionally also contains at least one metal selected from the group formed by elements from groups IIIA and IVA of the periodic table, preferably indium or tin. The present invention also concerns the use of the catalyst in a process for transalkylating alkylaromatic hydrocarbons such as toluene and alkylaromatic compounds containing at least 9 carbon atoms. In particular, this catalyst is highly effective in treating C9+ aromatic feeds containing more than 5% by weight of aromatic olefins containing 10 carbon atoms and more, this feed possibly also containing benzene.
摘要翻译：本发明涉及含有至少一种结构类型NES，优选NU-87的沸石的催化剂，其包含硅和至少一种选自由铝，铁，镓和硼形成的基团的元素T. 优选地，提取元素T使得总Si / T原子比大于20.该沸石至少部分为其酸形式。粘合剂优选为氧化铝。该催化剂还含有至少一种选自由ⅦB族，ⅥB族和铱族化合物形成的金属，优选为钼。最后，催化剂任选地还含有选自元素周期表IIIA和IVA族元素形成的族中的至少一种金属，优选为铟或锡。本发明还涉及催化剂在烷基化烷基芳烃如甲苯和含有至少9个碳原子的烷基芳族化合物的方法中的用途。特别地，该催化剂在处理含有大于5重量％的含有10个碳原子的芳族烯烃和更多的芳族烯烃的C9 +芳族原料方面是非常有效的，该进料还可能含有苯。

7. 发明授权

US06864400B2 Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons 失效
标题翻译：包含至少一种结构类型为NES和铼的沸石的催化剂及其用于烷基芳烃的烷基转移的用途
公开(公告)号：US06864400B2
公开(公告)日：2005-03-08
申请号：US10428033
申请日：2003-05-02
申请人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
发明人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
IPC分类号： B01J29/076 , B01J23/16 , B01J23/46 , B01J29/06 , B01J29/74 , B01J29/78 , C07B61/00 , C07C5/22 , C07C5/52 , C07C6/06 , C07C6/12 , C07C15/08
CPC分类号： C07C6/126 , B01J29/74 , B01J29/78 , B01J2229/16 , B01J2229/26 , B01J2229/36 , B01J2229/40 , B01J2229/42 , C07C2529/70
摘要： The present invention concerns a catalyst which contain at least one zeolite with structure type NES, preferably NU-87, comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron. Preferably, element T has been extracted so that the overall Si/T atomic ratio is more than 20. This zeolite is at least partially in its acid form. The binder is preferably alumina. The catalyst also contains at least one metal selected from the group formed by group VIIB, group VIB and iridium, preferably rhenium. Finally, the catalyst optionally also contains at least one metal selected from the group formed by elements from groups III and IV of the periodic table, preferably indium or tin. The present invention also concerns the use of the catalyst in a process for transalkylating alkylaromatic hydrocarbons such as toluene and alkylaromatic compounds containing at least 9 carbon atoms. In particular, this catalyst is highly effective in treating C9+ aromatic feeds containing more than 5% by weight of aromatic olefins containing 10 carbon atoms and more, this feed possibly also containing benzene.
摘要翻译：本发明涉及含有至少一种结构类型为NES，优选为NU-87的沸石的催化剂，其包含硅和选自由铝，铁，镓和硼形成的基团中的至少一种元素T. 优选地，提取元素T使得总Si / T原子比大于20.该沸石至少部分为其酸形式。粘合剂优选为氧化铝。该催化剂还含有选自由ⅦB族，ⅥB族和铱族，优选铼形成的族中的至少一种金属。最后，催化剂任选地还含有至少一种选自元素周期表III和IV族的元素形成的金属，优选为铟或锡。本发明还涉及催化剂在烷基化烷基芳烃如甲苯和含有至少9个碳原子的烷基芳族化合物的方法中的用途。特别地，该催化剂在处理含有大于5重量％的含有10个碳原子的芳族烯烃和更多的芳族烯烃的C9 +芳族原料方面是非常有效的，该进料还可能含有苯。

8. 发明授权

US06528695B1 Process for the production of an isomer of xylenes in three stages: separation, isomerization in the presence of a catalyst based on an EUO zeolite and transalkylation 有权
标题翻译：在三阶段生产二甲苯异构体的方法：在基于EUO沸石和烷基转移反应的催化剂存在下进行分离，异构化
公开(公告)号：US06528695B1
公开(公告)日：2003-03-04
申请号：US09598486
申请日：2000-06-22
申请人： Julia Magne-Drisch , Gérard Hotier , Jean-François Joly , Elisabeth Merlen , Fabio Alario
发明人： Julia Magne-Drisch , Gérard Hotier , Jean-François Joly , Elisabeth Merlen , Fabio Alario
IPC分类号： C07C1512
CPC分类号： C07C15/08 , C07C5/2724 , C07C6/126 , C07C7/13 , C07C2529/18 , C07C2529/74 , Y02P20/52 , C07C15/067
摘要： The invention relates to a process for the production of at least one isomer of xylenes, preferably paraxylene, as well as benzene, starting from a C8-aromatic fraction, whereby said process comprises a zone for separation of xylenes, a zone for isomerization of aromatic compounds with 8 carbon atoms used in the presence of a catalyst that comprises at least one EUO-structural-type zeolite that is selected from among the EU-1, TPZ-3, ZSM-50 zeolites and at least one metal of group VIII of the periodic table, and finally a transalkylation zone of C7- and C9-aromatic compounds. The invention makes it possible to produce paraxylene and benzene with a high yield, starting from a C8-aromatic fraction that comprises a large amount of ethylbenzene with improved performance levels of the isomerization stage and a good conversion of ethylbenzene in the transalkylation stage.
摘要翻译：本发明涉及从C8-芳族馏分开始生产二甲苯，优选对二甲苯以及苯的至少一种异构体的方法，其中所述方法包括用于分离二甲苯的区域，芳族异构化区在催化剂存在下使用的具有8个碳原子的化合物，其包含至少一种选自EU-1，TPZ-3，ZSM-50沸石和至少一种VIII族金属的EUO结构型沸石周期表，最后是C7-和C9-芳族化合物的烷基转移区。本发明使得可以从包含大量乙苯的C8芳族馏分开始以高产率制备对二甲苯和苯，具有改进的异构化阶段的性能水平和乙烷在烷基转移反应阶段中的良好转化率。

9. 发明授权

US06376734B1 Process for the production of at least one isomer of xylenes that comprise an adsorption stage and an isomerization stage with an euo-structural-type catalyst 有权
标题翻译：用于生产包含吸附阶段和异构化阶段的至少一种二甲苯异构体与二元结构型催化剂的方法
公开(公告)号：US06376734B1
公开(公告)日：2002-04-23
申请号：US09598646
申请日：2000-06-22
申请人： Julia Magne-Drisch , Gérard Hotier , Alain Methivier , Jean-Francois Joly , Fabio Alario , Elisabeth Merlen
发明人： Julia Magne-Drisch , Gérard Hotier , Alain Methivier , Jean-Francois Joly , Fabio Alario , Elisabeth Merlen
IPC分类号： C07C700
CPC分类号： C07C15/08 , C07C5/2724 , C07C7/13 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2521/12 , C07C2521/16 , C07C2527/167 , C07C2529/74
摘要： A process for the production of at least one isomer of xylenes comprising a simulated moving-bed adsorption (8) of a C8-aromatic feedstock (1) that delivers a paraxylene-rich fraction (9) that is optionally purified after a distillation (16) by at least one high-temperature crystallization (5) and a fraction (10) that is low in paraxylene is described. Fraction (10) is distilled and then isomerized (21) in the presence of an EUO-structural-type catalyst. The lightest hydrocarbons are removed from the isomerization effluent in a first distillation (23) then naphthenes in a second distillation (26), and distilled isomerization effluent (2) that results therefrom is recycled at least in part in adsorption (8). A mother liquor (3) that results from the crystallization stage is recycled at least in part in adsorption (8).
摘要翻译：一种用于生产二甲苯的至少一种异构体的方法，包括C8-芳族原料（1）的模拟移动床吸附（8），其传送富含对二甲苯的级分（9），其在蒸馏后任选地进行纯化（16 ）通过至少一种低温结晶（5）和低对二甲苯的馏分（10）进行了描述。馏分（10）蒸馏，然后在EUO结构型催化剂存在下异构化（21）。在第一蒸馏（23）中将最轻的烃从异构化流出物中除去，然后在第二蒸馏（26）中的环烷烃，并且由此产生的蒸馏异构化流出物（2）至少部分地再循环至吸附（8）。由结晶阶段产生的母液（3）至少部分地被再吸收（8）。

10. 发明授权

US06616910B2 Process for preparation of an EUO-structural-type zeolite, the zeolite that is obtained and its use as catalyst for isomerization of C8-aromatic compounds 有权
标题翻译：制备EUO结构型沸石的方法，所获得的沸石及其作为C8-芳族化合物异构化催化剂的用途
公开(公告)号：US06616910B2
公开(公告)日：2003-09-09
申请号：US09849483
申请日：2001-05-07
申请人： Loïc Rouleau , Frédéric Kolenda , Elisabeth Merlen , Fabio Alario
发明人： Loïc Rouleau , Frédéric Kolenda , Elisabeth Merlen , Fabio Alario
IPC分类号： C01B3904
CPC分类号： B01J29/7023 , B01J29/7446 , C01B39/06 , C01B39/48
摘要： This invention relates to a process for synthesis of an EUO-structural-type zeolite that comprises at least one element X that is selected from among silicon and germanium and at least one element T that is selected from among aluminum, iron, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese, whereby said process is carried out in the presence of an organic structuring agent that is derived from dibenzyldimethylammonium (DBDMA) or its precursors and in the presence of nuclei of at least one zeolitic material of the same structure as the zeolite that is to be synthesized. The zeolite that is thus obtained has an X/T ratio of between 5 and 50. It is used in particular as a catalyst, for example in a process for isomerization of aromatic compounds with 8 carbon atoms per molecule.
摘要翻译：本发明涉及一种合成EUO结构型沸石的方法，该方法包括选自硅和锗中的至少一种元素X和至少一种元素T，其选自铝，铁，镓，硼，钛，钒，锆，钼，砷，锑，铬和锰，由此所述方法在衍生自二苄基二甲基铵（DBDMA）或其前体的有机结构剂存在下，并且在至少存在核的存在下进行一种沸石材料与待合成的沸石具有相同的结构。由此获得的沸石的X / T比为5〜50。特别是作为催化剂使用，例如在每分子具有8个碳原子的芳族化合物异构化的方法中。

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