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1. 发明申请

US20180029025A1 Catalyst System and Use in Heavy Aromatics Conversion Processes 审中-公开
公开(公告)号：US20180029025A1
公开(公告)日：2018-02-01
申请号：US15714204
申请日：2017-09-25
申请人： ExxonMobil Chemical Patents Inc.
发明人： Christine N. Elia , Shifang L. Luo , Hari Nair , Wenyih F. Lai , Robert G. Tinger
IPC分类号： B01J29/80 , C07C15/06 , B01J29/44 , B01J29/24 , B01J29/22 , B01J35/10 , B01J29/76 , C01B39/26 , B01J35/02 , B01J35/00 , B01J29/74 , B01J29/68 , B01J29/67 , B01J37/18 , C07C6/12 , C07C4/18 , B01J8/04 , B01J29/46
CPC分类号： B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , Y02P20/52
摘要： Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m2/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.

2. 发明申请

US20150266793A1 METHODS OF PRODUCING PARA-XYLENE AND TEREPHTHALIC ACID 审中-公开
标题翻译：生产对二甲苯和十二烷酸的方法
公开(公告)号：US20150266793A1
公开(公告)日：2015-09-24
申请号：US14428339
申请日：2013-09-13
申请人： MICROMIDAS, INC.
发明人： Makoto N. Masuno , Ryan L. Smith , John Bissell, II , Marc Foster , Patrick B. Smith , Dennis A. Hucul , Edmund J. Stark , Daniel R. Henton , Adina Dumitrascu , Katherine Brune
IPC分类号： C07C2/86
CPC分类号： C07C2/867 , C07C6/04 , C07C2521/04 , C07C2521/18 , C07C2523/08 , C07C2523/10 , C07C2523/72 , C07C2527/122 , C07C2527/125 , C07C2527/126 , C07C2527/128 , C07C2527/133 , C07C2527/135 , C07C2527/138 , C07C2527/18 , C07C2527/19 , C07C2529/14 , C07C2529/24 , C07C2531/025 , C07C2531/04 , C07C2531/22 , C07C15/08
摘要： The present disclosure provides methods to produce para-xylene, toluene, and other compounds from renewable sources (e.g., cellulose, hemicellulose, starch, sugar) and ethylene in the presence of a catalyst. For example, cellulose and/or hemicellulose may be converted into 2,5-dimethylfuran (DMF), which may be converted into para-xylene by cycloaddition of ethylene to DMF. Para-xylene can then be oxidized to form terephthalic acid.
摘要翻译：本公开提供了在催化剂存在下从可再生来源（例如纤维素，半纤维素，淀粉，糖）和乙烯生产对二甲苯，甲苯和其它化合物的方法。例如，纤维素和/或半纤维素可以转化成2,5-二甲基呋喃（DMF），其可以通过乙烯与DMF的加成转化成对二甲苯。然后可以将对二甲苯氧化形成对苯二甲酸。

3. 发明授权

US07393989B2 Shaped catalysts for transalkylation of aromatics for enhanced xylenes production 有权
标题翻译：用于芳族化合物烷基转移用于增强二甲苯生产的成型催化剂
公开(公告)号：US07393989B2
公开(公告)日：2008-07-01
申请号：US11678857
申请日：2007-02-26
申请人： Antoine Negiz , Edwin P. Boldingh , Gregory J. Gajda , Sergey V. Gurevich
发明人： Antoine Negiz , Edwin P. Boldingh , Gregory J. Gajda , Sergey V. Gurevich
IPC分类号： C07C6/10
CPC分类号： C07C6/126 , B01J29/18 , B01J29/40 , B01J29/80 , B01J35/026 , B01J37/0009 , B01J2229/37 , B01J2229/42 , C07C2521/04 , C07C2521/12 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2529/78 , C07C2529/80 , Y02P20/52 , C07C15/08 , C07C15/067
摘要： A catalyst, a process for using the catalyst whereby the catalyst effectively transalkylates C7, C9, and C10 aromatics to C8 aromatics are disclosed. The catalyst comprises a support such as mordenite plus a metal component. The catalyst provides an enhanced life and activity for carrying out the transalkylation reactions at relatively low temperatures. This is achieved by reducing the maximum particle diameter of cylindrical pellets to 1/32 inch (0.08 cm) or a trilobe to 1/16 inch (0.16 cm).
摘要翻译：催化剂，使用催化剂的方法，其中催化剂有效地使C 7，C 9和C 10芳烷烃基烷基化至C 1 -C 10烷基，公开了8种芳族化合物。催化剂包括支链如丝光沸石加金属组分。催化剂提供了在较低温度下进行烷基转移反应的寿命和活性。这是通过将圆柱形丸粒的最大粒径减小到1/32英寸（0.08cm）或三叶至1/16英寸（0.16cm）来实现的。

4. 发明授权

US06815570B1 Shaped catalysts for transalkylation of aromatics for enhanced xylenes production 失效
标题翻译：用于芳族化合物烷基转移用于增强二甲苯生产的成型催化剂
公开(公告)号：US06815570B1
公开(公告)日：2004-11-09
申请号：US10141294
申请日：2002-05-07
申请人： Antoine Negiz , Edwin P. Boldingh , Gregory J. Gajda , Surgey V. Gurevich
发明人： Antoine Negiz , Edwin P. Boldingh , Gregory J. Gajda , Surgey V. Gurevich
IPC分类号： C07C500
CPC分类号： C07C6/126 , B01J29/18 , B01J29/40 , B01J29/80 , B01J35/026 , B01J37/0009 , B01J2229/37 , B01J2229/42 , C07C2521/04 , C07C2521/12 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2529/78 , C07C2529/80 , Y02P20/52 , C07C15/08 , C07C15/067
摘要： A catalyst, a process for using the catalyst whereby the catalyst effectively transalkylates C7, C9, and C10 aromatics to C8 aromatics are disclosed. The catalyst comprises a support such as mordenite plus a metal component. The catalyst provides an enhanced life and activity for carrying out the transalkylation reactions at relatively low temperatures. This is achieved by reducing the maximum particle diameter of cylindrical pellets to {fraction (1/32)} inch (0.08 cm) or a trilobe to {fraction (1/16)} inch (0.16 cm).
摘要翻译：一种催化剂，一种使用该催化剂的方法，其中该催化剂有效地将C7，C9和C10芳族化合物烷基化为C8芳族化合物。催化剂包括支链如丝光沸石加金属组分。催化剂提供了在较低温度下进行烷基转移反应的寿命和活性。这通过将圆柱形丸粒的最大粒径减小到{部分（1/32英寸（0.08cm））或三叶形至{部分（1/16英寸（0.16cm））而实现。

5. 发明申请

US20030229258A1 CONVERSION OF AROMATIC HYDROCARBONS 失效
标题翻译：芳烃转化
公开(公告)号：US20030229258A1
公开(公告)日：2003-12-11
申请号：US10167096
申请日：2002-06-11
发明人： Xin Xiao , James R. Butler
IPC分类号： C07C005/22 , C07C005/52
CPC分类号： C07C6/123 , C07C6/126 , C07C2529/24
摘要： A process for the transalkylation of an aromatic feedstock containing a benzene component and a polyalkylated aromatic component comprising at least one polyalkyl aromatic compound of at least nine carbon atoms. The feedstock is supplied to a reaction zone containing a metal modified zeolite transalkylation catalyst. The reaction zone is operated under conditions providing an equivalent conversion of pure toluene in the presence of the catalyst within the range of 40-55%, resulting in a transalkylated product with a reduced polyalkyl benzene content and an enhance monoalkyl benzene content relative to the transalkylation feedstock. In continued operation of the transalkylation reaction zone, at least one of the reaction conditions of temperature, pressure, and space velocity is adjusted in order to maintain a constant reaction severity to provide a desired equivalent conversion of toluene within a tolerance range of null2%. Specifically, the temperature is progressively increased while continuing the operation of the transalkylation zone to maintain a condition of constant reaction severity.
摘要翻译：包含苯组分和多烷基化芳族组分的芳族原料的烷基转移的方法，其包含至少一种具有至少9个碳原子的多烷基芳族化合物。将原料供给到含有金属改性沸石烷基转移催化剂的反应区。在催化剂存在下，在40-55％范围内提供纯甲苯当量转化的条件下操作反应区，得到相对于烷基转移反应的多烷基苯含量降低和烷基苯含量增加的烷基转移产物原料。在烷基转移反应区的继续操作中，调节温度，压力和空间速度的至少一个反应条件以保持恒定的反应强度，以在±2％的公差范围内提供所需的甲苯等效转化率，。具体地，温度逐渐增加，同时继续进行烷基转移区的操作，以保持反应持续的严重程度。

6. 发明授权

US06359184B1 Process for production of xylene 有权
标题翻译：二甲苯生产工艺
公开(公告)号：US06359184B1
公开(公告)日：2002-03-19
申请号：US09487538
申请日：2000-01-19
申请人： Hajime Kato , Hitoshi Tanaka , Kazuyoshi Iwayama , Ryoji Ichioka
发明人： Hajime Kato , Hitoshi Tanaka , Kazuyoshi Iwayama , Ryoji Ichioka
IPC分类号： C07C600
CPC分类号： B01J29/26 , B01J29/20 , C07C6/126 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/16 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , Y02P20/52
摘要： Disclosed herein is a catalyst composition for transalkylation of alkylaromatic hydrocarbons which exhibits the percent conversion of ethyltoluene higher than 50 wt %, is composed of mordenite (100 pbw), inorganic oxide and/or clay (25-150 pbw), and at least one metal component of rhenium, platinum, and nickel, and contains mordenite such that the maximum diameter of secondary particles of mordenite is smaller than 10 &mgr;m. Disclosed also herein is a process for producing xylene by the aid of said catalyst from alkylaromatic hydrocarbons containing C9 alkylaromatic hydrocarbons containing more than 5 wt % ethyltoluene and less than 0.5 wt % naphthalene, in the presence of hydrogen.
摘要翻译：本文公开了烷基芳族烃的烷基转移催化剂组合物，其表现出高于50重量％的乙基甲苯的转化百分比，由丝光沸石（100pbw），无机氧化物和/或粘土（25-150pbw）组成，并且至少一个铼，铂和镍的金属成分，并含有丝光沸石，使得丝光沸石的二次粒子的最大直径小于10μm。本文还公开了在氢气存在下，借助于所述催化剂从含有大于5重量％乙基甲苯和小于0.5重量％萘的C 9烷基芳族烃的烷基芳烃生产二甲苯的方法。

7. 发明授权

US5557029A Isomerization of saturated hydrocarbons 失效
标题翻译：饱和烃的异构化
公开(公告)号：US5557029A
公开(公告)日：1996-09-17
申请号：US523978
申请日：1995-09-06
申请人： Fan-Nan Lin , Nak J. Sung , Stephen L. Ege , Thomas A. Lessard
发明人： Fan-Nan Lin , Nak J. Sung , Stephen L. Ege , Thomas A. Lessard
IPC分类号： C07C5/27 , C07C5/13
CPC分类号： C07C5/2724 , C07C2523/42 , C07C2529/24
摘要： In a process for isomerizing saturated C.sub.4- C.sub.10 hydrocarbons (preferably n-pentane) in the presence of a platinum/zeolite catalyst, wherein sulfur compounds are present in the feed as impurities and cause catalyst deactivating, at least one volatile chlorine compound (preferably tetrachloroethylene or carbon tetrachloride) is added to the feed in an amount sufficient to counteract the catalyst deactivation. A correlation between effective amounts of chloride additive(s) required to counteract the catalyst deactivating effect caused by specific sulfur compound(s) and a specific parameter of various sulfur compounds has been established. The water content in the isomerization feed is not to exceed about 60 ppm H.sub.2 O (based on the weight of the at least one feed hydrocarbons.
摘要翻译：在铂/沸石催化剂存在下异构化饱和C 4 -C 10烃（优选正戊烷）的方法中，其中硫化合物作为杂质存在于进料中并引起催化剂失活，至少一种挥发性氯化合物（优选四氯乙烯或四氯化碳）以足以抵消催化剂失活的量加入进料中。已经确定了抵消由特定硫化合物引起的催化剂失活效应所需的氯化物添加剂的有效量与各种硫化合物的具体参数之间的相关性。异构化进料中的水含量不超过约60ppm H 2 O（基于至少一种原料烃的重量）。

8. 发明授权

US4269783A Conversion of syngas to high octane olefinic naphtha 失效
标题翻译：合成气转化为高辛烷值的烯烃石脑油
公开(公告)号：US4269783A
公开(公告)日：1981-05-26
申请号：US775129
申请日：1977-03-07
申请人： James A. Brennan , Philip D. Caesar , Julius Ciric , William E. Garwood , Robert E. Holland
发明人： James A. Brennan , Philip D. Caesar , Julius Ciric , William E. Garwood , Robert E. Holland
IPC分类号： C07C1/02 , C07C27/06
CPC分类号： C07C1/02 , C07C2521/12 , C07C2521/14 , C07C2523/745 , C07C2529/14 , C07C2529/24 , C07C2529/56 , C07C2529/76
摘要： A method is disclosed for the conversion of a syngas to a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90% overhead and being a predominantly olefinic product, wherein the olefins have substantially internal double bonds. The method for accomplishing this stated result involves an improvement in the method for the conversion of synthesis gas by contacting the same with a catalyst composite comprising a mixture of a Fischer-Tropsch catalyst and a volume excess of an acidic catalyst, e.g., silica-alumina or a crystalline aluminosilicate zeolite and wherein the activity of the acidic component is balanced with the activity of the Fischer-Tropsch component so as to maximize the yield of desired olefinic product.
摘要翻译：公开了一种在90％塔顶馏分将合成气转化为沸点低于400°F的液体烃产物并且主要是烯烃产物的方法，其中烯烃具有基本上内部的双键。实现所述结果的方法涉及通过使合成气与包含费 - 托催化剂和体积过量的酸性催化剂的混合物的催化剂复合物接触来改进合成气的方法，例如二氧化硅 - 氧化铝或结晶硅铝酸盐沸石，并且其中酸性组分的活性与费 - 托组分的活性相平衡，以使所需烯属产物的产率最大化。

9. 发明授权

US3763260A Hydrocarbon conversion catalyst 失效
标题翻译：碳氢转化催化剂
公开(公告)号：US3763260A
公开(公告)日：1973-10-02
申请号：US3763260D
申请日：1971-11-10
申请人： UNIVERSAL OIL PROD CO
发明人： POLLITZER E
IPC分类号： B01J29/18 , B01J29/20 , B01J29/22 , B01J29/24 , C07B61/00 , C07C1/00 , C07C2/66 , C07C4/18 , C07C5/27 , C07C6/12 , C07C15/00 , C07C15/02 , C07C15/08 , C07C67/00 , C07C3/62
CPC分类号： C07C6/126 , B01J29/18 , B01J29/20 , B01J29/22 , B01J29/24 , B01J2229/16 , C07C2/66 , C07C6/123 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C15/02
摘要： A CATALYTIC COMPOSITE COMPRISING A MORDENITE COMPONENT HAVING A SIO2/AL2/3 MOLE RATIO OF AT LEAST 40:1 PREPARED BY ACID EXTRACTING AL2O3 FROM MORDENITE PREPARED WITH AN INITIAL SIO2/AL2O3 MOLE RATIO OF ABOUT 12:1 TO ABOUT 30:1 AND A METAL COMPONENT SELECTED FROM COPPER, SILVER AND ZIRCONIUM. THE COMPOSITE IS PARTICULARLY USEFUL FOR THE TRANSALKYLATION OF ALKYLAROMATIC HYDROCARBONS AND THE ALKYLATION OF AROMATIC HYDROCARBONS.

10. 发明授权

US10058854B2 Catalyst system and use in heavy aromatics conversion processes 有权
公开(公告)号：US10058854B2
公开(公告)日：2018-08-28
申请号：US15714204
申请日：2017-09-25
申请人： ExxonMobil Chemical Patents Inc.
发明人： Christine N. Elia , Shifang L. Luo , Hari Nair , Wenyih F. Lai , Robert G. Tinger
IPC分类号： B01J29/06 , B01J29/80 , C07C15/06 , B01J29/46 , B01J29/44 , B01J29/24 , B01J29/22 , B01J35/10 , B01J29/76 , C01B39/26 , B01J35/02 , B01J35/00 , B01J29/74 , B01J29/68 , B01J29/67 , B01J37/18 , C07C4/18 , C07C6/12 , B01J8/04 , B01J37/30 , B01J37/02
CPC分类号： B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , C10G45/62 , C10G45/64 , C10G45/70 , C10G2300/1096 , C10G2300/70 , C10G2400/30 , Y02P20/52
摘要： Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m2/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.

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