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    • 9. 发明授权
    • Wood-type golf club head
    • 木型高尔夫球杆头
    • US07775904B2
    • 2010-08-17
    • US12285074
    • 2008-09-29
    • Tomoya Hirano
    • Tomoya Hirano
    • A63B53/04
    • A63B53/0466A63B60/54A63B2053/0408A63B2053/0416A63B2053/0433A63B2053/0437A63B2209/00
    • A wood-type golf club head has a hollow structure comprising a face portion having a back surface and a front surface defining a club face for striking a ball, a crown portion, a sole portion, and a side portion between the crown portion and sole portion. The hollow structure is provided with a hollow and a solid part. The solid part extends forward from the backmost point of the club head by a distance of from 0.08 to 0.20 times the maximum size of the club head in the back-and-forth direction, the hollow extends between the front surface of the solid part and the back surface of the face portion. The main frame of the hollow structure integrally includes the solid part.
    • 木型高尔夫球杆头具有中空结构,该中空结构包括具有后表面的表面部分和限定用于击球的球杆表面的前表面,冠部,鞋底部分和冠部和鞋底之间的侧部 一部分。 中空结构设置有中空部和固体部。 实心部分从球杆头的最后点向前延伸距离球杆头在前后方向的最大尺寸的0.08至0.20倍,中空在实心部分的前表面和 面部的后表面。 中空结构的主框架整体地包括固体部分。
    • 10. 发明授权
    • Fluorescent probe for zinc
    • 锌荧光探针
    • US07696245B2
    • 2010-04-13
    • US10767334
    • 2004-01-30
    • Kensuke KomatsuTomoya HiranoKazuya KikuchiTetsuo Nagano
    • Kensuke KomatsuTomoya HiranoKazuya KikuchiTetsuo Nagano
    • A61K31/353C07D311/80
    • C07D405/12C07D405/14C07D493/10G01N33/582G01N33/84
    • A compound represented by the following general formula (IA) or (IB) or a salt thereof which specifically traps a zinc ion and emits fluorescence, and is useful as a fluorescent probe for zinc: wherein R1 and R2 represent a hydrogen atom or a group represented by the following formula (A): wherein X1 to X4 represent a hydrogen atom, a 2-pyridylmethyl group, a 2-pyridylethyl group, a 2-methyl-6-pyridylmethyl group, or a 2-methyl-6-pyridylethyl group, provided that at least one is the group except a 2-pyridylmethyl group, and m and n represent 0 or 1, provided that they are not simultaneously 0; provided that R1 and R2 are not simultaneously hydrogen atoms; R3 and R4 represent a hydrogen atom or a halogen atom; R5 and R6 represent a hydrogen atom, an alkylcarbonyl group, or an alkylcarbonyloxymethyl group; and R7 represents a hydrogen atom or an alkyl group.
    • 由以下通式(IA)或(IB)表示的化合物或其盐特异性捕获锌离子并发射荧光,并且可用作锌的荧光探针:其中R1和R2表示氢原子或基团 由下式(A)表示:其中X 1至X 4表示氢原子,2-吡啶基甲基,2-吡啶基乙基,2-甲基-6-吡啶基甲基或2-甲基-6-吡啶基乙基 条件是至少一个是除2-吡啶基甲基以外的基团,m和n表示0或1,条件是它们不同时为0; 条件是R1和R2不同时为氢原子; R3和R4表示氢原子或卤素原子; R5和R6表示氢原子,烷基羰基或烷基羰氧基甲基; 并且R 7表示氢原子或烷基。