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    • 2. 发明授权
    • Curable silicone resin composition
    • 可固化硅树脂组合物
    • US07294682B2
    • 2007-11-13
    • US10942837
    • 2004-09-17
    • Tomoyuki GotoEiichi TabeiAkira Yamamoto
    • Tomoyuki GotoEiichi TabeiAkira Yamamoto
    • G08G77/20
    • G03F7/0757C08G77/12C08G77/16C08G77/18C08G77/20C08G77/70C08K5/54C08K5/5403C08K2201/014C08L83/04C08L83/00
    • A curable silicone resin composition is provided. It includes (A) an aromatic ring-containing hydrocarbon compound containing at least 2 silicon-bonded hydrogen atoms, in which the silicon atoms are bonded to the hydrocarbon skeleton; (B) an organopolysiloxane with a branched or three dimensional network structure, and with a viscosity at 25° C. of at least 1,000 mPa·s, having an average composition formula (1): R1xSiO{(4−x)/2}  (1) wherein, R1 independently represent a substituted or unsubstituted monovalent hydrocarbon group, a substituted or unsubstituted hydrocarbyloxy group, or a hydroxyl group, provided from 0.1 to 80 mol % of all the R1 groups are alkenyl groups, and x represents a positive number that satisfies 1≦x
    • 提供可固化的有机硅树脂组合物。 它包括(A)含有至少2个与硅键合的氢原子的含芳环的烃化合物,其中硅原子键合到烃骨架上; (B)具有支链或三维网状结构的有机聚硅氧烷,并且在25℃下的粘度为至少1,000mPa.s,具有平均组成式(1):<?in-line-formula description =“ (1-x)/ 2)(1)式(1)其中, 式中,R 1独立地表示取代或未取代的单价烃基,取代或未取代的烃氧基,或 提供0.1〜80摩尔%的全部R 1基团的羟基是烯基,x表示满足1≤x≤2的正数; 和(C)氢化硅烷化反应催化剂。 该组合物产生透明的固化产物并显示出优异的硬度和弯曲强度。
    • 4. 发明授权
    • Curable silicone resin composition
    • 可固化硅树脂组合物
    • US07291691B2
    • 2007-11-06
    • US10917280
    • 2004-08-13
    • Eiichi TabeiAkira Yamamoto
    • Eiichi TabeiAkira Yamamoto
    • C08G77/12
    • C08G77/50C08G77/42C08L83/10C08L83/00
    • Provided is a curable silicone resin composition including (A) a siloxane/polycyclic hydrocarbon-based compound containing at least 2 silicon-bonded hydrogen atoms, which is an addition reaction product of (a) a siloxane-based compound with at least 3 silicon-bonded hydrogen atoms, and (b) a polycyclic hydrocarbon with at least 2 addition reactive carbon-carbon double bonds, (B) a siloxane-based compound containing at least 2 silicon-bonded alkenyl groups, and (C) a hydrosilylation reaction catalyst. This composition is useful as a material for optical devices or parts, insulation material for electronic devices or parts, or coating material.
    • 提供一种可固化的有机硅树脂组合物,其包含(A)含有至少2个与硅键合的氢原子的硅氧烷/多环烃基化合物,其是(a)硅氧烷基化合物与至少3个硅键合氢原子的加成反应产物, 和(b)具有至少2个加成反应性碳 - 碳双键的多环烃,(B)含有至少2个与硅键合的烯基的硅氧烷基化合物,和(C)氢化硅烷化反应催化剂。 该组合物可用作光学器件或部件的材料,电子器件或部件的绝缘材料或涂层材料。
    • 7. 发明授权
    • Curable silicone resin composition
    • 可固化硅树脂组合物
    • US07019100B2
    • 2006-03-28
    • US10829282
    • 2004-04-22
    • Eiichi TabeiMitsuhiro Takarada
    • Eiichi TabeiMitsuhiro Takarada
    • C08G77/50
    • C08G77/52
    • A curable silicone resin composition is provided which is useful as a material for optical devices or parts, insulation material for electronic devices or parts, or coating material, and which produces a cured product having high hardness and strength and further having good optical transmission in the short wavelength region. The composition includes (A) an aromatic hydrocarbon compound having at least two hydrogen atoms bonded to silicon atoms with the silicon atoms being bonded to the hydrocarbon skeleton of the aromatic hydrocarbon compound, (B) a cyclic siloxane compound having at least two silicon atom-bonded alkenyl groups, and (C) a hydrosilylation reaction catalyst, or (D) an aromatic hydrocarbon compound having at least two alkenyl groups bonded to silicon atoms with the silicon atoms being bonded to the hydrocarbon skeleton of the aromatic hydrocarbon compound, (E) a cyclic siloxane compound having at least two silicon atom-bonded hydrogen atoms, and (C) a hydrosilylation reaction catalyst.
    • 提供可用作光学器件或部件的材料,电子器件或部件的绝缘材料或涂层材料的可固化的有机硅树脂组合物,并且其产生具有高硬度和强度的固化产物,并且在 短波长区域。 该组合物包括(A)具有至少两个与硅原子键合的氢原子的芳族烃化合物,其中硅原子与芳族烃化合物的烃骨架结合,(B)具有至少两个硅原子的环状硅氧烷化合物, (C)氢化硅烷化反应催化剂,或(D)具有至少两个与硅原子键合的烯基与芳族烃化合物的烃骨架键合的芳族烃化合物,(E) 具有至少两个与硅原子键合的氢原子的环状硅氧烷化合物,和(C)氢化硅烷化反应催化剂。
    • 10. 发明申请
    • CURABLE ORGANOSILICON COMPOSITION AND CURED PRODUCT THEREOF
    • 可固化有机硅组合物及其固化产品
    • US20080281056A1
    • 2008-11-13
    • US12115821
    • 2008-05-06
    • Eiichi Tabei
    • Eiichi Tabei
    • C08G77/38
    • C08K5/5425C08G77/52C08K5/0025C08K5/5419C08K5/549C08L83/04C08L83/00
    • Provided is a curable organosilicon composition comprising (A) a polycyclic hydrocarbon group-containing organosilicon compound, which comprises two hydrogen atoms bonded to silicon atoms within each molecule, and is an addition reaction product of (a) an organosilicon compound having two hydrogen atoms bonded to silicon atoms within each molecule, and (b) a polycyclic hydrocarbon compound having two hydrosilylation reactive carbon-carbon double bonds within each molecule, (B) a siloxane-based compound having two or more alkenyl groups bonded to silicon atoms within each molecule, and (C) a hydrosilylation reaction catalyst. The curable organosilicon composition yields a cured product that has a high degree of hardness and excellent transparency, crack resistance and heat resistance, and is useful as a curable silicone material, an encapsulating material for optical devices such as optical elements, an encapsulating material for other electronic devices such as semiconductor elements, and an electrically insulating coating material.
    • 本发明提供一种可固化的有机硅组合物,其包含(A)含有多环烃基的有机硅化合物,其包含在每个分子内与硅原子键合的两个氢原子,并且是(a)具有两个氢原子键合的有机硅化合物的加合反应产物 (b)在每个分子内具有两个氢化硅烷化反应性碳 - 碳双键的多环烃化合物,(B)在每个分子内具有两个或多个与硅原子键合的烯基的硅氧烷基化合物, 和(C)氢化硅烷化反应催化剂。 可固化的有机硅组合物产生具有高硬度和优异的透明度,耐裂纹性和耐热性的固化产物,并且可用作可固化的硅酮材料,用于诸如光学元件的光学装置的封装材料,用于其它的封装材料 电子器件如半导体元件和电绝缘涂层材料。