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    • 1. 发明授权
    • Borosilicate glass of high chemical resistance and low viscosity which
contains zirconium oxide and lithium oxide
    • 含有氧化锆和氧化锂的高耐化学性和低粘度的硼硅酸盐玻璃
    • US5736476A
    • 1998-04-07
    • US722668
    • 1996-09-30
    • Eckhart WatzkeAndrea KampferPeter BrixFranz Ott
    • Eckhart WatzkeAndrea KampferPeter BrixFranz Ott
    • A61J1/06B01L3/14C03C3/093C03C3/112C03C4/20
    • B01L3/5082C03C3/093A61J1/06
    • The invention relates to a borosilicate glass of high chemical resistance and low viscosity which contains zirconium oxide and lithium oxide. The borosilicate glass has hydrolytic resistance (in accordance with DIN ISO 719), class 1 acid resistance (in accordance with DIN 12116), and class 1 alkali resistance (in accordance with DIN ISO 659), and with a low operating temperature V.sub.A of between 1180.degree. C. to 1230.degree. C. and a coefficient of thermal expansion .alpha..sub.20/300 of 4.9.times.10.sup.-6 K.sup.-1. The borosilicate glass has the composition (in % by weight, based on oxide): SiO.sub.2 73-75; B.sub.2 0.sub.3 7-10; Al.sub.2 0.sub.3 5-7; ZrO.sub.2 1-3; Li.sub.2 0 0.5-1.5; Na.sub.2 0 0-10; K.sub.2 0 0-10; MgO 0-3; CaO 0-3; BaO 0-3; SrO 0-3; ZnO 0-3; ratio of SiO.sub.2 /B.sub.2 0.sub.3 .gtoreq.7.5; .SIGMA. SiO.sub.2 +Al.sub.2 0.sub.3 +ZrO.sub.2 80-83 and .SIGMA. MgO+CaO+BaO+SrO+ZnO.ltoreq.3, and fluorides 0-3. The glass is particularly suitable for use as a versatile primary packaging material for pharmaceuticals, for example as ampule glass.
    • 本发明涉及含有氧化锆和氧化锂的高耐化学性和低粘度的硼硅酸盐玻璃。 硼硅酸盐玻璃具有耐水解性(符合DIN ISO 719),1级耐酸性(符合DIN 12116)和1级耐碱性(符合DIN ISO 659标准),并具有低的工作温度VA 1180℃至1230℃,热膨胀系数α20/300为4.9×10 -6 K -1。 硼硅酸盐玻璃的组成(以重量%计,基于氧化物):SiO 2 73-75; B203 7-10; Al203 5-7; ZrO2 1-3; Li20 0.5-1.5; Na20 0-10; K20 0-10; MgO 0-3; CaO 0-3; BaO 0-3; SrO 0-3; ZnO 0-3; SiO 2 / B 2 O 3的比例> = 7.5; SIGMA SiO 2 + Al 2 O 3 + ZrO 2 80-83和SIGMA MgO + CaO + BaO + SrO + ZnO 3,氟化物0-3。 该玻璃特别适合用作药物的通用初级包装材料,例如作为安瓿玻璃。
    • 2. 发明授权
    • Reducing melt borosilicate glass having improved UV transmission
properties and water resistance and methods of use
    • 减少具有改善的UV透射性能和耐水性的熔融硼硅酸盐玻璃以及使用方法
    • US5610108A
    • 1997-03-11
    • US319969
    • 1994-10-07
    • Eckhart WatzkeThomas KlossPeter BrixFranz Ott
    • Eckhart WatzkeThomas KlossPeter BrixFranz Ott
    • G01D11/26C03C3/091C03C3/118C03C4/00C03C4/10C03C4/08
    • C03C4/0085C03C3/091Y10S501/905
    • Reducing melt borosilicate glass having a UV transmittance of at least 85% for ultraviolet radiation having a wavelength of 254 nm for a sample thickness of 1 mm and a water-resistance of less than 100 micrograms, advantageously less than 62 micrograms, Na.sub.2 O per gram of glass powder according to ISO 719 and a thermal expansion coefficient .alpha..sub.20/300 of from 5 to 6.times.10.sup.-6 K.sup.-1 and comprising from 58 to 65% by weight SiO.sub.2, from 18 to 20.5% by weight B.sub.2 O.sub.3, from 8.1 to 10.4% by weight Al.sub.2O.sub.3, from 0 to 1% by weight CaO, from 0 to 2% by weight BaO, from 0 to 2% by weight SrO, from 0 to 1.5% by weight Li.sub.2 O, from 5.5 to 8.5% by weight Na.sub.2 O, from 0 to 3% by weight K.sub.2 O and from 0 to 2% by weight fluorine. The sum total content of all of the alkali metal oxides present in the glass is not greater than 10% and the sum total content of the CaO, BaO and SrO is not greater than 3% and the molar ratio of Al.sub.2 O.sub.3 : Na.sub.2 O is from 0.6 to 1. The glass is particularly suitable for EPROM windows, UV lamps, photomultipliers, spectrophotometers under difficult climatic conditions and protective tubes for UV lamps immersed in water in waste water treatment operations.
    • 将具有254nm波长的紫外线辐射的紫外线透射率至少为85%的熔融硼硅酸盐玻璃减少到样品厚度为1mm,耐水性小于100微克,有利地小于62微克,Na 2 O /克 根据ISO 719的玻璃粉末和5至6×10-6K-1的热膨胀系数α20/300,并且包含58至65重量%的SiO 2,18至20.5重量%的B 2 O 3,8.1至10.4重量%的 0〜1重量%的CaO,0〜2重量%的BaO,0〜2重量%的SrO,0〜1.5重量%的Li 2 O,5.5〜8.5重量%的Na 2 O,0 至3重量%的K 2 O和0至2重量%的氟。 玻璃中存在的所有碱金属氧化物的总含量不大于10%,CaO,BaO和SrO的总含量不大于3%,Al 2 O 3 :Na 2 O的摩尔比为0.6 该玻璃特别适用于恶劣气候条件下的EPROM窗口,UV灯,光电倍增管,分光光度计,以及在废水处理操作中浸入水中的紫外线灯的保护管。
    • 10. 发明授权
    • Magnetic disk comprising a substrate
    • 包含基片的磁盘
    • US06217971B1
    • 2001-04-17
    • US09432663
    • 1999-11-03
    • Silke WolffBurkhard SpeitPeter Brix
    • Silke WolffBurkhard SpeitPeter Brix
    • B32B302
    • C03C3/062C03C3/068Y10S428/90
    • Magnetic disks comprising a substrate and glass materials which are used in the manufacture of hard disc substrates. The glasses can have the following compositions (in per cent by weight on an oxide basis): SiO2 10-30, Al2O3 0-5, B2O3 0-8, Li2O 0-8, Na2O 1-10, with Li2O+Na2O 5-10, K2O 0-3, MgO 5-16, CaO 0-15, with MgO+CaO>15-25, SrO+BaO 0-8, ZrO2 0-8, TiO2 7-25, La2O3 0-10, Nb2O5 5-20, V2O5 0-10, CeO2 0-1, As2O3+Sb2O3+F 0.1-1. These glasses can have high dimensional stability as a result of their high specific modulus of elasticity, to be especially suited for hard disk substrates.
    • 包括用于制造硬盘基板的基板和玻璃材料的磁盘。 玻璃可以具有以下组成(以氧化物为基准的重量百分比):SiO 2 10-30,Al 2 O 3 0-5,B 2 O 3 0-8,Li 2 O 0-8,Na 2 O 1-10与Li 2 O + Na 2 O 5 - 10,K2O 0-3,MgO 5-16,CaO 0-15,MgO + CaO> 15-25,SrO + BaO 0-8,ZrO 2 0-8,TiO 2 7-25,La 2 O 3 0-10,Nb 2 O 5 5 -20,V2O5 0-10,CeO2 0-1,As2O3 + Sb2O3 + F 0.1-1。 这些玻璃由于其高比弹性模量而具有高的尺寸稳定性,特别适用于硬盘基片。