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1. 发明授权

US5599753A Borosilicate glass weak in boric acid 失效
标题翻译：硼酸玻璃薄弱的硼酸
公开(公告)号：US5599753A
公开(公告)日：1997-02-04
申请号：US521325
申请日：1995-08-30
申请人： Eckhart Watzke , Andrea Kampfer , Thomas Kloss , Gerhard Kemmler
发明人： Eckhart Watzke , Andrea Kampfer , Thomas Kloss , Gerhard Kemmler
IPC分类号： C03C3/089 , C03C3/091 , C03C3/093 , C03C4/00
CPC分类号： C03C3/093 , C03C3/091 , Y10S501/905
摘要： Borosilicate glass weak in boric acid having a high chemical stability with an alkali resistance according to DIN 52 322 of LBK-Class 1, a thermal expansion .alpha..sub.20/300 between 4.0 to 5.3.times.10.sup.-6 K.sup.-1, a ratio .alpha.'/.alpha. of thermal expansion coefficients above T.sub.g (.alpha.') to below T.sub.g (.alpha.) of 4 to 8, a glass transformation temperature between 500.degree. C. and 600.degree. C., high radiation transmittance and a UV transmission .tau..sub.250 nm/1 mm of 0 to 70% or .tau..sub.300 nm/1 mm of 0 to 91% of the composition in percent by weight on oxide basis of: SiO.sub.2 >75; B.sub.2 O.sub.3 1 to 83; SiO.sub.2 :B.sub.2 O.sub.3 >8; SiO.sub.2 +Al.sub.2 O.sub.3 +ZrO.sub.2 >83; Li.sub.2 O+Na.sub.2 O+K.sub.2 O 5 to 10; MgO+CaO+BaO+SrO+ZnO>3.
摘要翻译：具有高耐化学稳定性的硼酸硼酸玻璃，具有根据LBK-Class 1的DIN 52 322的耐碱性，4.0〜5.3×10-6K-1之间的热膨胀α20/300，α= 高于Tg（α'）至低于Tg（α）的热膨胀系数为4至8，玻璃化转变温度在500℃至600℃之间，高透射率和UV透射率为250nm / 1mm的0 至70％或tau 300nm / 1mm，基于氧化物的重量百分比为0至91％的组成：SiO 2> 75; B2O3 1〜<9; Al2O3 3〜6; Li2O 0〜4; Na2O 0至8; K2O 0〜6; MgO 0〜3; CaO 0〜3; BaO 0〜2; SrO 0〜2; ZnO 0〜3; ZrO2 0〜3; SnO2 0〜3; SnO 0〜3; TiO2 0〜2; CeO2 0〜2; Fe2O3 0〜1; SiO2 + B2O3> 83; SiO2：B2O3> 8; SiO2 + Al2O3 + ZrO2> 83; Li2O + Na2O + K2O 5〜10; MgO + CaO + BaO + SrO + ZnO> 3。

2. 发明授权

US5627115A Colored borosilicate glass 失效
标题翻译：彩色硼硅酸盐玻璃
公开(公告)号：US5627115A
公开(公告)日：1997-05-06
申请号：US512157
申请日：1995-08-07
申请人： Eckhart Watzke , Andrea Kampfer , Thomas Kloss , Gerhard Kemmler
发明人： Eckhart Watzke , Andrea Kampfer , Thomas Kloss , Gerhard Kemmler
IPC分类号： C03C3/091 , C03C4/02 , C03C4/08
CPC分类号： C03C4/02 , C03C3/091 , C03C4/082 , Y10S501/905
摘要： The invention relates to brownish, brown to black colored borosilicate glasses which have stepped grades of transmission in the NIR range or are fully non-transmitting. The borosilicate glass, primarily the borosilicate glass 3.3, is melted with defined additives of titanium carbide and/or metallic silicon. The glasses produced in accordance with the invention are to be used as filters, glass vessels and/or decorative colored glass in construction and for decorating because of their absorption/transmission characteristics. On the other hand, the glasses produced in accordance with the invention can also be used as absorbers in solar technology when the light transmissibility in the NIR/IR range is sufficiently low.
摘要翻译：本发明涉及棕色，棕色至黑色的硼硅酸盐玻璃，其在NIR范围内具有阶梯级传播或完全不透射。硼硅酸盐玻璃（主要是硼硅酸盐玻璃3.3）用限定的碳化钛和/或金属硅添加剂熔化。根据本发明生产的玻璃由于其吸收/传输特性而被用作施工中的过滤器，玻璃容器和/或装饰性有色玻璃并进行装饰。另一方面，当在NIR / IR范围内的透光率足够低时，根据本发明生产的玻璃也可用作太阳能技术中的吸收剂。

3. 发明授权

US5736476A Borosilicate glass of high chemical resistance and low viscosity which contains zirconium oxide and lithium oxide 失效
标题翻译：含有氧化锆和氧化锂的高耐化学性和低粘度的硼硅酸盐玻璃
公开(公告)号：US5736476A
公开(公告)日：1998-04-07
申请号：US722668
申请日：1996-09-30
申请人： Eckhart Watzke , Andrea Kampfer , Peter Brix , Franz Ott
发明人： Eckhart Watzke , Andrea Kampfer , Peter Brix , Franz Ott
IPC分类号： A61J1/06 , B01L3/14 , C03C3/093 , C03C3/112 , C03C4/20
CPC分类号： B01L3/5082 , C03C3/093 , A61J1/06
摘要： The invention relates to a borosilicate glass of high chemical resistance and low viscosity which contains zirconium oxide and lithium oxide. The borosilicate glass has hydrolytic resistance (in accordance with DIN ISO 719), class 1 acid resistance (in accordance with DIN 12116), and class 1 alkali resistance (in accordance with DIN ISO 659), and with a low operating temperature V.sub.A of between 1180.degree. C. to 1230.degree. C. and a coefficient of thermal expansion .alpha..sub.20/300 of 4.9.times.10.sup.-6 K.sup.-1. The borosilicate glass has the composition (in % by weight, based on oxide): SiO.sub.2 73-75; B.sub.2 0.sub.3 7-10; Al.sub.2 0.sub.3 5-7; ZrO.sub.2 1-3; Li.sub.2 0 0.5-1.5; Na.sub.2 0 0-10; K.sub.2 0 0-10; MgO 0-3; CaO 0-3; BaO 0-3; SrO 0-3; ZnO 0-3; ratio of SiO.sub.2 /B.sub.2 0.sub.3 .gtoreq.7.5; .SIGMA. SiO.sub.2 +Al.sub.2 0.sub.3 +ZrO.sub.2 80-83 and .SIGMA. MgO+CaO+BaO+SrO+ZnO.ltoreq.3, and fluorides 0-3. The glass is particularly suitable for use as a versatile primary packaging material for pharmaceuticals, for example as ampule glass.
摘要翻译：本发明涉及含有氧化锆和氧化锂的高耐化学性和低粘度的硼硅酸盐玻璃。硼硅酸盐玻璃具有耐水解性（符合DIN ISO 719），1级耐酸性（符合DIN 12116）和1级耐碱性（符合DIN ISO 659标准），并具有低的工作温度VA 1180℃至1230℃，热膨胀系数α20/300为4.9×10 -6 K -1。硼硅酸盐玻璃的组成（以重量％计，基于氧化物）：SiO 2 73-75; B203 7-10; Al203 5-7; ZrO2 1-3; Li20 0.5-1.5; Na20 0-10; K20 0-10; MgO 0-3; CaO 0-3; BaO 0-3; SrO 0-3; ZnO 0-3; SiO 2 / B 2 O 3的比例> = 7.5; SIGMA SiO 2 + Al 2 O 3 + ZrO 2 80-83和SIGMA MgO + CaO + BaO + SrO + ZnO 3，氟化物0-3。该玻璃特别适合用作药物的通用初级包装材料，例如作为安瓿玻璃。

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