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    • 1. 发明授权
    • Copolyether ester hot-melt masses
    • 共聚醚酯热熔胶
    • US5869594A
    • 1999-02-09
    • US909977
    • 1997-08-12
    • Eberhard KinkelinGerhard PoessneckerJurgen Spindler
    • Eberhard KinkelinGerhard PoessneckerJurgen Spindler
    • C08G63/672C09D5/46C09J5/06C09J167/02C08G63/66
    • C08G63/672C09J167/025
    • The invention relates to novel hot-melt masses consisting of a statistically built-up copolyether ester based on terephthalic acid and a mixture of aliphatic diols. Terephthalic acid is used as the single acid component and its molar amount, relative to the total amount of acid, is 100 molar %. A combination of butane diol, diethylene glycol, polyethylene and optionally triethylene glycol is present as diol component. The molar amount of butane diol is less than 75 molar %, the amount of diethylene glycol is between 5 and 60 molar %, the amount of triethylene glycol between 0 and 40 molar % and at least 2 and at the most 10 molar % of a higher-molecular polyethylene glycol component with a molar mass of 600-4000 g/mole is used, relative to the total acid amount and total diol amount of 100 molar % in each instance. The melting point of the copolyether ester adhesive masses is between 90.degree. and 190.degree. C.The copolyetherester hot-melt masses can be used in the hot-melt method and for the known other powder coating methods.
    • 本发明涉及由统计学上构建的基于对苯二甲酸的共聚醚酯和脂族二醇的混合物组成的热熔体。 使用对苯二甲酸作为单一酸成分,相对于酸的总量,其摩尔量为100摩尔%。 丁二醇,二甘醇,聚乙烯和任选的三甘醇的组合作为二醇组分存在。 丁二醇的摩尔量小于75摩尔%,二甘醇的量为5至60摩尔%,三甘醇的量为0至40摩尔%,至少2和至多10摩尔% 使用摩尔质量为600-4000g / mol的高分子量聚乙二醇组分,相对于总酸量和总二醇量为100摩尔%。 共聚醚酯粘合剂的熔点在90°和190℃之间。共聚醚酯热熔体可用于热熔法和已知的其它粉末涂覆方法。
    • 2. 发明授权
    • Copolyether ester hot-melt masses
    • 共聚醚酯热熔胶
    • US5767226A
    • 1998-06-16
    • US909586
    • 1997-08-12
    • Eberhard KinkelinGerhard PoessneckerJurgen Spindler
    • Eberhard KinkelinGerhard PoessneckerJurgen Spindler
    • C08G63/672C09D5/46C09J5/06C09J167/02C08G63/16
    • C08G63/672C09J167/025
    • The invention relates to novel hot-melt masses consisting of a statistically built-up copolyether ester based on terephthalic acid in a mixture of aliphatic diols. Terephthalic acid is used as the single acid component and its molar amount, relative to the total amount of acid, is 100 molar %. A combination of butane diol, triethylene glycol and polyethylene glycol is present as diol component. The molar amount of butane diol is less than 80 molar %, the amount of triethylene glycol is between 15 and 60 molar % and at least 2 and at the most 10 molar % of a higher-molecular polyethylene glycol component with a molar mass of 600-4000 g/mole is used, relative to the total acid amount and total diol amount of 100 molar % in each instance. The melting point of the copolyether ester adhesive masses is between 90.degree. and 180.degree. C. The copolyetherester hot-melt masses can be used in the hot-melt method and for other known powder coating methods.
    • 本发明涉及由在脂肪族二醇的混合物中基于对苯二甲酸的统计建立的共聚醚酯组成的新型热熔体。 使用对苯二甲酸作为单一酸成分,相对于酸的总量,其摩尔量为100摩尔%。 丁二醇,三甘醇和聚乙二醇的组合作为二醇组分存在。 丁二醇的摩尔量小于80摩尔%,三甘醇的量为摩尔质量为600的高分子量聚乙二醇组分的15至60摩尔%至少2摩尔%且至多10摩尔% 使用-4000g / mol,相对于总酸量和总二醇量为100摩尔%。 共聚醚酯粘合剂的熔点在90℃和180℃之间。共聚醚酯加热熔体可用于热熔法和其它已知的粉末涂覆方法中。
    • 3. 发明授权
    • Low-melting copolyamide and their use as hot-melt adhesives
    • 低熔点共聚酰胺及其作为热熔胶的用途
    • US06590063B2
    • 2003-07-08
    • US09852218
    • 2001-05-09
    • Gerhard PoessneckerJürgen SpindlerEberhard Kinkelin
    • Gerhard PoessneckerJürgen SpindlerEberhard Kinkelin
    • C08G6902
    • C09J177/06C08G69/02C08G69/36C09J177/00D01F6/80Y10S526/935Y10T428/29Y10T428/2964Y10T428/2967Y10T428/2969Y10T428/31725
    • Copolyamides, consisting of polycondensation products of the following components: caprolactam 10 to 45 mol-%, laurolactam 30 to 55 mol-%, at least 2 dicarboxylic acids 20 to 50 mol-% of the following compounds, aliphatic &agr;,&ohgr;-dicarboxylic acids with 6 up to 14 C atoms inclusively, terephthalic acid, isophthalic acid and 2,6-naphthalene dicarboxylic acid, wherein the content of aromatic dicarboxylic acids is lower than 10 mol-%, with reference to the allover amount of the above-mentioned components, which add up to 100 mol-%, a diamine mixture in an amount that is equimolar to that of the dicarboxylic acids, chosen from the group of the following substances, hexamethylene diamine, piperazine and/or 2-methyl-1,5-diaminopentane, wherein the molar content of hexa-methylene diamine is between 75 and 95 mol-% with reference to the diamine mixture. The copolyamides according to the invention are used for the production of mono- and multifilaments, fibers, films and nets.
    • 由以下组分的缩聚产物组成的共聚酰胺:己内酰胺10至45mol%,月桂内酰胺30至55mol%,至少2个二羧酸20至50mol%的以下化合物,脂族α,ω-二羧酸 包括6至14个C原子,对苯二甲酸,间苯二甲酸和2,6-萘二甲酸,其中芳族二羧酸的含量低于10摩尔%,相对于上述组分的总量 ,其加入量为100摩尔%,二胺混合物的量等于与二羧酸等摩尔量的二胺混合物,其选自下列物质:六亚甲基二胺,哌嗪和/或2-甲基-1,5- 二氨基戊烷,其中六亚甲基二胺的摩尔含量相对于二胺混合物为75至95摩尔%。根据本发明的共聚酰胺用于生产单丝和复丝,纤维,膜和网。
    • 5. 发明授权
    • Coating system settable by heat
    • 涂层系统可通过加热设定
    • US06313234B1
    • 2001-11-06
    • US08469171
    • 1995-06-06
    • Andreas KaplanManfred HoppeEberhard Kinkelin
    • Andreas KaplanManfred HoppeEberhard Kinkelin
    • C08F2000
    • C09D167/02Y10S525/934C08L2666/36C08L63/00
    • A heat settable, coating system of carboxyl-functional polyester resins, polyfunctional epoxy compounds and/or &bgr;-hydroxy alkyl amides, as well as further customary additives, if required. The coating system contains at least one linear carboxyl-functional polyester resin of up to 10 mol-part of isophthalic acid and at least 90 mol-parts of at least a further dicarboxylic acid from the group of aromatic dicarboxylic acids with 8 to 16 C-atoms, aliphatic dicarboxylic acids with 6 to 22 C-atoms and cycloaliphatic dicarboxylic acids with 8 to 16 C-atoms, and at least 90 mol-parts of at least one branched aliphatic diol with 4 to 12 C-atoms, and up to 50 mol-parts of at least one linear aliphatic diol with 2 to 22 C-atoms and/or at least one cycloaliphatic diol with 6 to 16 C-atoms as the binder resin. Also a process for producing thermosetting coating systems of carboxyl-functional polyester resins, wherein binder resin, at least one cross-linking agent from the group of polyfunctional epoxy compounds and &bgr;-hydroxy alkyl amides and, if required, further customary additives are mixed into the melt at 90 to 130° C., extruded, removed, granulated, comminuted and screened to a size of less than 100 &mgr;m. Finally, uses of the thermosetting coating system and of a protective layer produced from this coating system.
    • 羧基官能聚酯树脂的热固化涂料体系,多官能环氧化合物和/或β-羟基烷基酰胺,以及如果需要的其它常规添加剂。 该涂料体系含有至多一种至多10摩尔间苯二甲酸的直链羧基官能聚酯树脂和至少90摩尔份的至少一种另外的二羧酸,该芳族二羧酸与8至16 C- 具有6至22个碳原子的脂族二羧酸和具有8至16个C原子的脂环族二羧酸,以及至少90摩尔份至少一种具有4至12个碳原子的支链脂肪族二醇和至多50个 至少一个具有2至22个碳原子的直链脂族二醇的摩尔份数和/或至少一种具有6至16个碳原子的脂环族二醇作为粘合剂树脂。 还有一种制备羧基官能聚酯树脂的热固性涂料体系的方法,其中粘合剂树脂,至少一种多官能环氧化合物和β-羟基烷基酰胺的交联剂,以及如果需要,将其它常规添加剂混合 将熔体在90〜130℃下挤出,除去,造粒,粉碎并筛分至小于100μm的尺寸。 最后,使用热固性涂层系统和由该涂层系统制成的保护层。
    • 7. 发明授权
    • Low-melting copolyester and copolyetherester hot-melt adhesives
    • 低熔点共聚酯和共聚醚酯热熔胶
    • US06255443B1
    • 2001-07-03
    • US09352998
    • 1999-07-13
    • Eberhard KinkelinJürgen SpindlerGerhard Pössenecker
    • Eberhard KinkelinJürgen SpindlerGerhard Pössenecker
    • C08G6302
    • C09J167/02C08G63/16
    • Novel, quick-crystallizing hot-melt adhesive masses having a melting point between 60° and 100° C. comprise a statistically-proportioned copolyester or copolyetherester based on terephthalic acid, adipic acid and a mixture of aliphatic diols; the molar proportion of terephthalic acid is between 55 and 85 mole %, relative to the total acid quantity; and the molar proportion of adipic acid is between 15 and 40 mole %. A combination of butane diol and hexane diol is used as the diol component; the molar component of butane diol is between 40 and 55 mole %; and the molar proportion of hexane diol is between 40 and 60 mole %. Up to 15 mole % of a dimer acid having a molar mass between 400 and 800 g/mole, or up to 10 mole % of a higher-molecular polyethylene glycol having a molecular mass of 600 to 4000 g/mole, can be used to increase the flexibility. The copolyester or copolyetherester hot-melt adhesive masses of the invention can be used in the hot-melt method, and in powder-form coating methods.
    • 具有熔点在60-100℃之间的新型快速结晶热熔粘合剂组合物包含基于对苯二甲酸,己二酸和脂族二醇的混合物的统计学比例的共聚酯或共聚醚酯; 相对于总酸量,对苯二甲酸的摩尔比例为55-85摩尔% 己二酸的摩尔比例为15〜40摩尔%。 丁二醇和己二醇的组合用作二醇组分; 丁二醇的摩尔成分为40〜55摩尔%。 己二醇的摩尔比例为40〜60摩尔%。 高达15摩尔%的摩尔质量为400至800克/摩尔或高达10摩尔%的分子量为600至4000克/摩尔的高分子量聚乙二醇的二聚酸可用于 增加灵活性。 本发明的共聚聚酯或共聚醚酯热熔粘合剂可用于热熔融方法,粉末形式的涂布方法