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    • 2. 发明授权
    • Certain phosphorus-containing thiomorpholinones
    • 含有含磷酸的三羟基磷灰石
    • US3691163A
    • 1972-09-12
    • US3691163D
    • 1970-08-03
    • EXXON RESEARCH ENGINEERING CO
    • SZABO KAROLY
    • A01N57/08C07F9/165C07F9/6544C07D93/10
    • C07F9/6544A01N57/08
    • Organophosphorus compounds containing the thiomorpholinone moiety have been found to be highly active both as contact and systemic insecticides and miticides. These compounds also possess excellent acaricidal activity. These compounds are represented by one of the following structural formulas:

      WHEREIN R and R1 may be the same or different and are selected from the group consisting of C1 to C6 alkoxy, C1 to C6 alkyl, C2 to C6 alkoxymethyl, and C1 to C6 alkylthio; provided that at least one of them is alkoxy; R2 and R3 may be the same or different and are selected from the group consisting of hydrogen and C1 to C6 alkyl; R4 is one selected from the group consisting of hydrogen, C1-C6 alkyl, C1-C6 alkylthio, C1-C6 alkoxyl and C1C6 alkyl optionally substituted with hydroxyl, amino, cyano, C1C6 N alkyl carbamoyl, C1-C6 alkoxycarbamido, substituted and unsubstituted phenyl, C1-C6 carboalkoxyalkyl and acetoxyl; R5 is one selected from the group consisting of (CH2)n and CH2-CHR6, wherein R6 is one selected from the group consisting of hydrogen, C1 to C6 alkyl, C1 to C6 alkylthio; X is O or S, n is an integer ranging from 1 to 6 and p is 0-2.
    • 已经发现含有硫代吗啉酮部分的有机磷化合物作为接触和全身的杀虫剂和杀螨剂是高活性的。 这些化合物也具有优异的杀螨活性。 这些化合物由以下结构式之一表示: