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1. 发明授权

US5344623A Process for the extraction of strontium from acidic solutions 失效
标题翻译：从酸性溶液中萃取锶的工艺
公开(公告)号：US5344623A
公开(公告)日：1994-09-06
申请号：US76881
申请日：1993-06-15
申请人： E. Philip Horwitz , Mark L. Dietz
发明人： E. Philip Horwitz , Mark L. Dietz
IPC分类号： C01B21/46 , C22B26/20 , C01F13/00
CPC分类号： C01B21/46 , C22B26/20
摘要： The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid.
摘要翻译：本发明是从含有这些和其它裂变产物值的含水硝酸废液中选择性提取锶值的方法。萃取剂溶液是含有相改性剂的脂族烃稀释剂中的大环聚醚。该方法将选择性地从在硝酸中高达6摩尔的硝酸溶液中提取锶值。

2. 发明授权

US5851401A Method for the chromatographic separation of cations from aqueous samples 失效
标题翻译：从水性样品中分离阳离子的方法
公开(公告)号：US5851401A
公开(公告)日：1998-12-22
申请号：US853593
申请日：1997-05-09
申请人： E. Philip Horwitz , Renato Chiarizia , Mark L. Dietz
发明人： E. Philip Horwitz , Renato Chiarizia , Mark L. Dietz
IPC分类号： B01D15/08 , B01J20/32 , G21F9/06 , G21F9/12 , G21F9/30
CPC分类号： B01D15/08 , B01D15/36 , B01J20/286 , B01J20/3092 , B01J20/3204 , B01J20/321 , B01J20/3212 , B01J20/3246 , G21F9/06 , G21F9/12 , G21F9/30 , B01J2220/54 , B01J2220/56
摘要： An extraction chromatographic material for extracting metal cations from a liquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methanediphosphonic acid on an inert particulate support.
摘要翻译：用于从液体流中提取金属阳离子的提取色谱材料。萃取色谱材料通过将二酯化甲基二膦酸吸附在惰性颗粒载体上来制备。

3. 发明授权

US5346618A Liquid chromatographic extraction medium 失效
标题翻译：液相色谱提取介质
公开(公告)号：US5346618A
公开(公告)日：1994-09-13
申请号：US51608
申请日：1993-04-23
申请人： E. Philip Horwitz , Mark L. Dietz
发明人： E. Philip Horwitz , Mark L. Dietz
IPC分类号： B01D15/00 , B01D15/08 , B01J20/281 , C01F11/00 , C07D323/00 , G01N30/50 , G01N30/88 , G21F9/06
CPC分类号： B01D15/08 , G21F9/06 , Y10S423/14 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： A method and apparatus for extracting strontium and technetium values from biological, industrial and environmental sample solutions using a chromatographic column is described. An extractant medium for the column is prepared by generating a solution of a diluent containing a Crown ether and dispersing the solution on a resin substrate material. The sample solution is highly acidic and is introduced directed to the chromatographic column and strontium or technetium is eluted using deionized water.
摘要翻译：描述了使用色谱柱从生物，工业和环境样品溶液中提取锶和锝值的方法和装置。通过产生含有冠醚的稀释剂溶液并将溶液分散在树脂基材上制备柱的萃取剂介质。样品溶液是高度酸性的并被导入色谱柱，并使用去离子水洗脱锶或锝。

4. 发明授权

US5110474A Method for liquid chromatographic extraction of strontium from acid solutions 失效
标题翻译：从酸溶液中液体色谱提取锶的方法
公开(公告)号：US5110474A
公开(公告)日：1992-05-05
申请号：US507419
申请日：1990-04-09
申请人： E. Philip Horwitz , Mark L. Dietz
发明人： E. Philip Horwitz , Mark L. Dietz
IPC分类号： B01D15/00 , B01D15/08 , B01J20/281 , C01F11/00 , C07D323/00 , G01N30/50 , G01N30/88 , G21F9/06
CPC分类号： B01D15/08 , G21F9/06 , Y10S423/14 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： A method and apparatus for extracting strontium and technetium values from biological, industrial and environmental sample solutions using a chromatographic column is described. An extractant medium for the column is prepared by generating a solution of a diluent containing a Crown ether and dispersing the solution on a resin substrate material. The sample solution is highly acidic and is introduced directed to the chromatographic column and strontium or technetium is eluted using deionized water.
摘要翻译：描述了使用色谱柱从生物，工业和环境样品溶液中提取锶和锝值的方法和装置。通过产生含有冠醚的稀释剂溶液并将溶液分散在树脂基材上制备柱的萃取剂介质。样品溶液是高度酸性的并被导入色谱柱，并使用去离子水洗脱锶或锝。

5. 发明授权

US5651883A Method for the chromatographic separation of cations from aqueous samples 失效
标题翻译：从水性样品中分离阳离子的方法
公开(公告)号：US5651883A
公开(公告)日：1997-07-29
申请号：US467402
申请日：1995-06-06
申请人： E. Philip Horwitz , Renato Chiarizia , Mark L. Dietz
发明人： E. Philip Horwitz , Renato Chiarizia , Mark L. Dietz
IPC分类号： B01D15/08 , B01J20/32 , G21F9/06 , G21F9/12 , G21F9/30
CPC分类号： B01D15/08 , B01D15/36 , B01J20/286 , B01J20/3092 , B01J20/3204 , B01J20/321 , B01J20/3212 , B01J20/3246 , G21F9/06 , G21F9/12 , G21F9/30 , B01J2220/54 , B01J2220/56
摘要： An extraction chromatographic material for extracting metal cations from aiquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methanediphosphonic acid on an inert particulate support.
摘要翻译：用于从液体流中提取金属阳离子的提取色谱材料。萃取色谱材料通过将二酯化甲基二膦酸吸附在惰性颗粒载体上来制备。

6. 发明授权

US4835107A Method for the concentration and separation of actinides from biological and environmental samples 失效
标题翻译：从生物和环境样品中浓缩和分离锕系元素的方法
公开(公告)号：US4835107A
公开(公告)日：1989-05-30
申请号：US921282
申请日：1986-10-21
申请人： E. Philip Horwitz , Mark L. Dietz
发明人： E. Philip Horwitz , Mark L. Dietz
IPC分类号： B01D11/04 , C01G56/00 , C22B3/38 , G21F9/00
CPC分类号： G21F9/007 , C01G56/001 , C22B3/0043 , C22B3/24 , Y02P10/234 , Y10T436/25125
摘要： A method and apparatus for the quantitative recover of actinide values from biological and environmental sample by passing appropriately prepared samples in a mineral acid solution through a separation column of a dialkyl(phenyl)-N,N-dialylcarbamoylmethylphosphine oxide dissolved in tri-n-butyl phosphate on an inert substrate which selectively extracts the actinide values. The actinide values can be eluted either as a group or individually and their presence quantitatively detected by alpha counting.
摘要翻译：通过将适当制备的样品通过溶解在三正丁基中的二烷基（苯基）-N，N-二甲酰基氨基甲酰基甲基氧化膦的分离柱，在无机酸溶液中通过适当制备的样品定量回收生物和环境样品中锕系元素值的方法和装置。磷酸盐在选择性提取锕系元素值的惰性底物上。锕系元素值可以作为一组或单独洗脱，并通过α计数定量检测其存在。

7. 发明授权

US5888398A Composition and process for separating cesium ions from an acidic aqueous solution also containing other ions 失效
标题翻译：从含有其他离子的酸性水溶液中分离铯离子的组成和方法
公开(公告)号：US5888398A
公开(公告)日：1999-03-30
申请号：US789653
申请日：1997-01-27
申请人： Mark L. Dietz , E. Philip Horwitz , Richard A. Bartsch , Richard E. Barrans, Jr. , David Rausch
发明人： Mark L. Dietz , E. Philip Horwitz , Richard A. Bartsch , Richard E. Barrans, Jr. , David Rausch
IPC分类号： C07D323/00 , C22B3/26 , C22B26/10 , B01D11/00 , B01D11/02 , C01D17/00
CPC分类号： C07D323/00 , C22B26/10 , C22B3/002 , Y02P10/234
摘要： A crown ether cesium ion extractant is disclosed as is its synthesis. The crown ether cesium ion extractant is useful for the selective purification of cesium ions from aqueous acidic media, and more particularly useful for the isolation of radioactive cesium-137 from nuclear waste streams. Processes for isolating cesium ions from aqueous acidic media using the crown ether cesium extractant are disclosed as are processes for recycling the crown ether cesium extractant and processes for recovering cesium from a crown ether cesium extractant solution.
摘要翻译：公开了冠醚铯离子提取剂的合成。冠醚铯离子萃取剂可用于从酸性水溶液中选择性纯化铯离子，更特别适用于从核废料流中分离放射性铯-137。公开了使用冠醚铯提取剂从含水酸性介质中分离铯离子的方法，用于回收冠醚铯提取剂的方法和从冠醚铯提取剂溶液回收铯的方法。

8. 发明授权

US5169609A Combined transuranic-strontium extraction process 失效
标题翻译：组合超铀萃取法
公开(公告)号：US5169609A
公开(公告)日：1992-12-08
申请号：US717426
申请日：1991-06-19
申请人： E. Philip Horwitz , Mark L. Dietz
发明人： E. Philip Horwitz , Mark L. Dietz
IPC分类号： C01F11/00 , C01G56/00 , C22B3/40 , G21F9/06 , G21F9/12
CPC分类号： C22B3/0095 , C01F11/005 , C01G56/001 , G21F9/125 , Y02P10/234
摘要： The transuranic (TRU) elements neptunium, plutonium and americium can be separated together with strontium from nitric acid waste solutions in a single process. An extractant solution of a crown ether and an alkyl(phenyl)-N,N-dialkylcarbanylmethylphosphine oxide in an appropriate diluent will extract the TRU's together with strontium, uranium and technetium. The TRU's and the strontium can then be selectively stripped from the extractant for disposal.
摘要翻译：铀，钚，铀，铀，铀和铀都可以在单一工艺中与硝酸废物溶液与锶分离。冠醚和烷基（苯基）-N，N-二烷基羰基甲基氧化膦在合适的稀释剂中的萃取剂溶液将与锶，铀和锝一起萃取TRU。然后可以将TRU和锶从萃取剂中选择性剥离以进行处理。

9. 发明授权

US5100585A Process for the recovery of strontium from acid solutions 失效
标题翻译：从酸溶液中回收锶的工艺
公开(公告)号：US5100585A
公开(公告)日：1992-03-31
申请号：US506125
申请日：1990-04-09
申请人： E. Philip Horwitz , Mark L. Dietz
发明人： E. Philip Horwitz , Mark L. Dietz
IPC分类号： C22B3/26 , C22B26/20 , C22B61/00 , G21C19/46
CPC分类号： C22B61/00 , C22B26/20 , C22B3/0018 , G21C19/46 , Y02P10/234 , Y02W30/883
摘要： The invention is a process for selectively extracting strontium and technetium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant is a macrocyclic polyether in a diluent which is insoluble in water, but which will itself dissolve a small amount of water. The process will extract strontium and technetium values from nitric acid solutions which are up to 6 molar in nitric acid.
摘要翻译：本发明是从含有这些和其它裂变产物值的含水硝酸废液中选择性提取锶和锝值的方法。萃取剂是稀释剂中的大环聚醚，其不溶于水，但其本身可溶解少量的水。该过程将从在硝酸中高达6摩尔的硝酸溶液中提取锶和锝的值。

10. 发明授权

US08507284B2 Method and apparatus for extraction of strontium from urine 有权
标题翻译：从尿中提取锶的方法和装置
公开(公告)号：US08507284B2
公开(公告)日：2013-08-13
申请号：US13182873
申请日：2011-07-14
申请人： Michael D. Kaminski , Carol J. Mertz , Ilya A. Shkrob , Mark L. Dietz , Cory A. Hawkins
发明人： Michael D. Kaminski , Carol J. Mertz , Ilya A. Shkrob , Mark L. Dietz , Cory A. Hawkins
IPC分类号： G01N33/20 , B01D15/00 , B01D37/02 , C01F11/00
CPC分类号： B01D15/1871 , B01D15/363 , B01D15/3847 , C01F11/005 , C01F11/36 , G01N33/493 , G01N33/84
摘要： The present invention provides an apparatus and rapid methods for extracting strontium ions from urine to provide a concentrated and purified strontium-90 extract suitable for scintillation measurements. The methods remove organic compounds, pigments, and alkali metal ions that can interfere with quantitative determination of strontium-90 in urine. A method of the invention comprises acidifying urine and removing organic pigments therefrom, loading a known quantity of so-treated urine onto a diphosphonic acid-based ion-exchange resin; flowing aqueous methanesulfonic acid through the diphosphonic acid-based ion-exchange resin to elute alkali metal ions therefrom; eluting strontium ions off of the diphosphonic acid-based resin and on to a strontium extraction chromatographic resin with a concentrated aqueous nitric acid solution; subsequently flowing water or a dilute acid stripping solution through the strontium extraction resin to strip the strontium from the strontium extraction resin; and collecting the strontium-containing stripping solution eluting from the strontium extraction resin.
摘要翻译：本发明提供了一种用于从尿提取锶离子以提供适用于闪烁测量的浓缩和纯化的锶-90提取物的装置和快速方法。这些方法可以去除可能干扰尿液中锶-90的定量测定的有机化合物，颜料和碱金属离子。本发明的方法包括酸化尿液并从其中除去有机颜料，将已知量的如此处理的尿液加载到基于二膦酸的离子交换树脂上; 通过二膦酸离子交换树脂将甲磺酸水溶液从其中洗脱出碱金属离子; 从二膦酸类树脂中洗脱锶离子，并用浓硝酸水溶液萃取锶萃取色谱树脂; 随后将水或稀酸剥离溶液通过锶萃取树脂从锶萃取树脂中剥离锶; 并收集从锶萃取树脂洗脱的含锶剥离液。

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