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1. 发明授权

US09834641B2 Aminosilane adhesion promoter for urethane system 有权
公开(公告)号：US09834641B2
公开(公告)日：2017-12-05
申请号：US15103932
申请日：2014-11-25
申请人： Rohm and Haas Company , Dow Global Technologies LLC
发明人： Jorge Jimenez , Kevin K. Miyake , Pavel L. Shutov , David E. Vietti , Joseph J. Zupancic
IPC分类号： C08G63/695 , C08G18/76 , C08G18/10 , C08G18/12 , C08G18/48 , C08G18/50 , C09J175/06 , C08G18/42 , C08G18/63 , C08G18/40 , C08G18/46
CPC分类号： C08G63/6956 , C08G18/10 , C08G18/12 , C08G18/4018 , C08G18/4072 , C08G18/4211 , C08G18/4692 , C08G18/4812 , C08G18/4825 , C08G18/5096 , C08G18/632 , C08G18/7621 , C08G18/7671 , C09J175/06 , C08G18/40 , C08G18/42
摘要： A polyester polyol comprising at least one esterified unit of formula (I) wherein L is a difunctional aliphatic group having from two to six carbon atoms and R is a C1-C4 alkyl group.

2. 发明授权

US09758614B2 Polyester polyol and polyol blends and rigid polyurethane foam manufacturing 有权
公开(公告)号：US09758614B2
公开(公告)日：2017-09-12
申请号：US14914484
申请日：2014-09-20
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： Jorge Jimenez , Guiseppe Lista , Davide Micheletti
IPC分类号： C08G18/48 , C08G18/42 , C08G18/08 , C08G18/76 , C08J9/14 , C08G63/42 , C08G63/58 , C08G18/10 , C08G18/12 , C08G18/40 , C08J9/02 , C08G101/00
CPC分类号： C08G18/4883 , C08G18/10 , C08G18/12 , C08G18/14 , C08G18/4018 , C08G18/4208 , C08G18/4291 , C08G18/4294 , C08G18/7671 , C08G63/42 , C08G63/58 , C08G2101/00 , C08G2101/0025 , C08J9/02 , C08J9/141 , C08J2201/022 , C08J2203/14 , C08J2205/10 , C08J2375/06 , C08J2375/08
摘要： A polyester polyol is formed in a polycondensation reaction between an aromatic dicarboxylic acid, a polyol, and an epoxy compound having a straight chain alkyl or alkenyl group having at least six carbon atoms. The polyester polyol exhibits excellent compatibility with hydrocarbon blowing agents. As such, it is a useful component in rigid polyurethane foam formulations that are contain hydrocarbon blowing agents.

3. 发明授权

US09546307B2 Polyurethane based insulated glass sealant 有权
标题翻译：聚氨酯绝缘玻璃密封剂
公开(公告)号：US09546307B2
公开(公告)日：2017-01-17
申请号：US14423261
申请日：2012-09-26
申请人： Dow Global Technologies LLC
发明人： Bindu Krishnan , Dwight Latham , Laura A. Grier , Woo-Sung Bae , Hector Perez , Jorge Jimenez , William A. Koonce
IPC分类号： C09J175/06 , C08K5/12 , C08K3/26 , C03C27/10 , C08G18/66 , C08G18/79 , C08G18/40 , C08G18/42 , C09K3/10 , C08K5/11
CPC分类号： C09J175/06 , C03C27/10 , C08G18/4018 , C08G18/4241 , C08G18/4283 , C08G18/4286 , C08G18/4288 , C08G18/664 , C08G18/797 , C08G2190/00 , C08K3/26 , C08K5/11 , C08K5/12 , C08K2003/265 , C09K3/1021 , Y10T428/31551
摘要： Embodiments of the invention provide for polyurethane-based sealants. The sealants include a reaction product of a reaction system which includes at least one isocyanate, and at least one polyester polyol. The polyester polyol includes a reaction product of a polyester reaction mixture which includes one or more hydrophobic monomers, one or more organic diacids or methyl esters thereof, and one or more diols.
摘要翻译：本发明的实施方案提供了基于聚氨酯的密封剂。密封剂包括包含至少一种异氰酸酯的反应体系和至少一种聚酯多元醇的反应产物。聚酯多元醇包括聚酯反应混合物的反应产物，其包含一种或多种疏水性单体，一种或多种有机二酸或其甲酯，以及一种或多种二醇。

4. 发明申请

US20160108166A1 HYBRID POLYOLS 审中-公开
标题翻译：混合聚合物
公开(公告)号：US20160108166A1
公开(公告)日：2016-04-21
申请号：US14893214
申请日：2014-05-08
申请人： ROHM AND HAAS COMPANY , DOW GLOBAL TECHNOLOGIES LLC
发明人： Joseph J. Zupancic , William H. Heath , Jorge Jimenez , Amira A. Marine , Pavel L. Shutov , David E. Vietti
IPC分类号： C08G18/48 , C08G18/72
CPC分类号： C08G18/4879 , C08G18/10 , C08G18/4261 , C08G18/4866 , C08G18/4887 , C08G18/72 , C09J175/04 , C08G18/7657 , C08G18/73
摘要： Provided is a two-component composition comprising one or more polyisocyanate and one or more hybrid polyol comprising reaction residues of (i). one initiator polyol having N hydroxyl groups, wherein N is 2 or greater, and wherein the number-average molecular weight of said initiator polyol is 900 or lower, (ii). one or more anhydride, and (iii). two or more alkylene oxides having the structure wherein said R3 is hydrogen or an alkyl group, wherein the mole ratio of said reaction residues of anhydride to said reaction residues of initiator polyol is N:1 or less; and wherein the mole ratio of said reaction residues (iii) to said reaction residues of initiator polyol is 20:1 or less wherein at least one said reaction residue of an anhydride is attached directly to one of said reaction residues of a higher-alkylene oxide.
摘要翻译：提供了包含一种或多种多异氰酸酯和一种或多种包含（i）的反应残基的杂化多元醇的双组分组合物。一种具有N个羟基的引发剂多元醇，其中N为2或更大，并且其中所述引发剂多元醇的数均分子量为900或更低，（ii）。一种或多种酸酐，和（ⅲ）。两个或多个具有其中所述R 3为氢或烷基的结构的环氧烷烃，其中酸酐与引发剂多元醇的所述反应残余物的摩尔比为N：1或更小; 并且其中所述反应残余物（iii）与所述引发剂多元醇的所述反应残基的摩尔比为20:1或更低，其中至少一个所述酸酐的所述反应残基直接连接在所述高级环氧烷的所述反应残基之一。

5. 发明申请

US20150018512A1 SINGLE-POT PROCESS FOR THE PRODUCTION OF POLYESTER-CO-CARBONATE POLYOLS 有权
标题翻译：用于生产聚碳酸酯多元醇的单一工艺
公开(公告)号：US20150018512A1
公开(公告)日：2015-01-15
申请号：US14373955
申请日：2013-02-04
申请人： Dow Global Technologies LLC
发明人： William H. Heath , Harpreet Singh , Amarnath Singh , Jorge Jimenez , Qiuyun Xu
IPC分类号： C08G64/30
CPC分类号： C08G64/305 , C08G63/64
摘要： Polyester-co-carbonate polyols and methods for producing the same are provided. The method comprises reacting one or more alcohols having an OH functionality of two or more with one or more organic diacids to form a reaction mixture, adding a first amount of dialkyl carbonate to the reaction mixture to remove water remaining from the reaction mixture by azeotropic drying, adding a transesterification catalyst to the dialkyl carbonate containing reaction mixture and adding a second amount of dialkyl carbonate to the catalyst containing reaction mixture.
摘要翻译：提供了聚酯 - 碳酸酯多元醇及其制备方法。该方法包括将一种或多种具有两个或多个OH官能团的醇与一种或多种有机二酸反应以形成反应混合物，向反应混合物中加入第一量的碳酸二烷基酯以通过共沸干燥除去残留在反应混合物中的水向含碳酸二烷基酯的反应混合物中加入酯交换催化剂，并向含催化剂的反应混合物中加入第二量的碳酸二烷基酯。

6. 发明申请

US20180186919A1 LAMINATING ADHESIVE - POLYESTER-POLYCARBONATE-POLYOL SYSTEMS 审中-公开
公开(公告)号：US20180186919A1
公开(公告)日：2018-07-05
申请号：US15740993
申请日：2016-05-31
申请人： Dow Global Technologies LLC , Rohm and Haas Company
发明人： Joseph J. Zupancic , Jorge Jimenez , Amira A. Marine , David E. Vietti , Qiuyun Xu
IPC分类号： C08G18/44 , C08G18/79 , C08G63/64 , C09J175/06 , B32B7/12 , B32B27/08 , B32B27/32 , B32B27/36 , B32B27/34 , B32B15/088 , B32B15/09 , B32B15/085 , B32B15/20
摘要： The instant invention provides a curable formulation suitable for laminating adhesive applications, and laminating adhesives made therefrom.

7. 发明申请

US20160200856A1 Polyester Polyol and Polyol Blends and Rigid Polyurethane Foam Manufacturing 有权
标题翻译：聚酯多元醇和多元醇混合物和刚性聚氨酯泡沫制造
公开(公告)号：US20160200856A1
公开(公告)日：2016-07-14
申请号：US14914484
申请日：2014-09-20
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： Jorge Jimenez , Guiseppe Lista , Davide Micheletti
IPC分类号： C08G18/48 , C08J9/14 , C08G18/08 , C08G18/76 , C08G18/42
CPC分类号： C08G18/4883 , C08G18/10 , C08G18/12 , C08G18/14 , C08G18/4018 , C08G18/4208 , C08G18/4291 , C08G18/4294 , C08G18/7671 , C08G63/42 , C08G63/58 , C08G2101/00 , C08G2101/0025 , C08J9/02 , C08J9/141 , C08J2201/022 , C08J2203/14 , C08J2205/10 , C08J2375/06 , C08J2375/08
摘要： A polyester polyol is formed in a polycondensation reaction between an aromatic dicarboxylic acid, a polyol, and an epoxy compound having a straight chain alkyl or alkenyl group having at least six carbon atoms. The polyester polyol exhibits excellent compatibility with hydrocarbon blowing agents. As such, it is a useful component in rigid polyurethane foam formulations that are contain hydrocarbon blowing agents.
摘要翻译：在芳族二羧酸，多元醇和具有至少6个碳原子的直链烷基或烯基的环氧化合物之间的缩聚反应中形成聚酯多元醇。聚酯多元醇与烃发泡剂显示出优异的相容性。因此，它是含有烃发泡剂的硬质聚氨酯泡沫制剂中的有用组分。

8. 发明申请

US20150031815A1 ESTER CARBONATE POLYOLS FOR HYDROLYTICALLY STABLE ADHESIVES 有权
标题翻译：用于水解稳定粘合剂的酯类碳酸酯
公开(公告)号：US20150031815A1
公开(公告)日：2015-01-29
申请号：US14357262
申请日：2012-12-04
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： Harpreet Singh , Viviano Bertolone , Orazio Rubulotta , Jorge Jimenez , William H. Heath , Amarnath Singh , William A. Koonce
IPC分类号： C09J175/06 , C09J163/04
CPC分类号： C09J175/06 , C08G18/10 , C08G18/12 , C08G18/4009 , C08G18/4018 , C08G18/4045 , C08G18/4202 , C08G18/44 , C08G63/64 , C09J163/04 , C09J175/04
摘要： A two-component curable adhesive or sealant composition is provided. The first component may comprise a mixture of at least one polyol selected from the group comprising a polyester polyol, a polyester-polycarbonate copolymer polyol, and combinations thereof, a resin, and optionally a solvent. The second component may comprise a prepolymer obtained by reacting a polyester-polycarbonate copolymer polyol which is the reaction product of a polyester polyol which is the reaction product of one or more organic acids, and one or more glycols having a functionality of two or more and one or more polycarbonate polyols, at least one organic polyisocyanate component, and at least one chain extending agent and optionally a solvent. Alternatively, the first component may comprise a polyester-polycarbonate copolymer polyol, a resin, and optionally a solvent. The second component may comprise a polyisocyanate curative and optionally a solvent. The cured adhesive exhibits improved hydrolytic properties while maintaining excellent processability and adhesive properties.
摘要翻译：提供了双组分可固化的粘合剂或密封剂组合物。第一组分可以包含选自包含聚酯多元醇，聚酯 - 聚碳酸酯共聚物多元醇及其组合的组中的至少一种多元醇，树脂和任选的溶剂的混合物。第二组分可以包含通过使作为一种或多种有机酸的反应产物的聚酯多元醇与一种或多种具有两个或多个官能度的二元醇的反应产物的聚酯 - 聚碳酸酯共聚物多元醇和一种或多种聚碳酸酯多元醇，至少一种有机多异氰酸酯组分和至少一种扩链剂和任选的溶剂。或者，第一组分可以包含聚酯 - 聚碳酸酯共聚物多元醇，树脂和任选的溶剂。第二组分可以包含多异氰酸酯固化剂和任选的溶剂。固化的粘合剂表现出改善的水解性能，同时保持优异的加工性能和粘合性能。

9. 发明申请

US20140186611A1 POLYOL FORMULATIONS FOR IMPROVED GREEN STRENGTH OF POLYISOCYANURATE RIGID FOAMS 审中-公开
标题翻译：用于改善聚异氰酸酯刚性纤维素的强度的多酚配方
公开(公告)号：US20140186611A1
公开(公告)日：2014-07-03
申请号：US14119199
申请日：2012-05-21
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： Michael J. Skowronski , Kelly R. Flaherty , Jorge Jimenez , Woo-Sung Bae , Giuseppe Lista
IPC分类号： C08G63/668 , B32B5/20 , C08G18/00
CPC分类号： C08G63/668 , B32B5/20 , C08G18/00 , C08G18/092 , C08G18/1816 , C08G18/225 , C08G18/4018 , C08G18/4252 , C08G18/48 , C08G18/4829 , C08G2101/0025 , C08G2101/005 , C08G2105/02 , C08J9/146 , C08J2375/06 , Y10T428/249953
摘要： Polyesters and polyol formulations comprising polyesters used in the preparation of polyisocyanurate rigid foams with improved green strength properties are provided. In some embodiments, a polyester which is the reaction product of (a) an aromatic component comprising 80 mole percent or greater of terephthalic acid, (b) at least one polyether polyol having a nominal functionality of 2, a molecular weight of 150 to 1,000 and a polyoxyethylene content of at least 70% by weight of the polyether polyol, (c) at least one glycol different than (b) having a nominal functionality of 2 and a molecular weight from 60 to 250, and (d) at least one polyol having a molecular weight of 60 to 250 and a nominal functionality of at least 3, wherein (a), (b), (c), and (d) are present in the reaction on a percent weight basis of 20 to 60 weight percent of (a), 20 to 50 weight percent of (b), 10 to 30 weight percent of (c), and 5 to 20 weight percent of (d) is provided.
摘要翻译：提供了包含用于制备具有改善的生坯强度性能的聚异氰脲酸酯刚性泡沫体的聚酯的聚酯和多元醇配方。在一些实施方案中，聚酯是（a）包含80摩尔％或更多对苯二甲酸的芳族组分的反应产物，（b）至少一种标称官能度为2的聚醚多元醇，分子量为150至1,000 和聚醚多元醇的至少70重量％的聚氧乙烯含量，（c）至少一种不同于具有标称官能度为2且分子量为60至250的（b）的二元醇，和（d）至少一种分子量为60〜250，标称官能度为3以上的多元醇，其中（a），（b），（c）和（d）以20〜60重量％的重量％存在于反应中（a）的百分比，（b）的20〜50重量％，（c）的10〜30重量％和（d）的5〜20重量％。

10. 发明授权

US10519269B2 Laminating adhesive—polyester-polycarbonate-polyol systems 有权
公开(公告)号：US10519269B2
公开(公告)日：2019-12-31
申请号：US15740993
申请日：2016-05-31
申请人： Dow Global Technologies LLC , Rohm and Haas Company
发明人： Joseph J. Zupancic , Jorge Jimenez , Amira A. Marine , David E. Vietti , Qiuyun Xu
IPC分类号： C08G18/44 , B32B7/12 , C08G18/79 , C08G63/64 , C09J175/06 , B32B15/20 , B32B27/08 , C08G18/42 , B32B27/06 , B32B27/16 , B32B15/08 , B32B15/088 , B32B15/09 , B32B27/32 , B32B27/34 , B32B27/36
摘要： The instant invention provides a curable formulation suitable for laminating adhesive applications, and laminating adhesives made therefrom.

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