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    • 3. 发明授权
    • System for implementing operation and start-up of a vehicle which is powered by electricity from a fuel cell power plant
    • 用于实施由燃料电池发电厂供电的车辆的操作和起动的系统
    • US06210821B1
    • 2001-04-03
    • US09221428
    • 1998-12-28
    • Roger R. LesieurLeonard J. Bonville, Jr.Jay GarowThomas J. CorriganJohn L. Preston, Jr.
    • Roger R. LesieurLeonard J. Bonville, Jr.Jay GarowThomas J. CorriganJohn L. Preston, Jr.
    • H01M806
    • H01M8/0662H01M8/0258H01M8/04223H01M8/04225H01M8/04238H01M8/04302H01M8/0612H01M2250/20Y02T90/32
    • A fuel gas processing system is operable to remove substantially all of the sulfur present in a hydrocarbon fuel supply used to power a fuel cell power plant in a mobile vehicular environment. The power plant fuel can be gasoline, diesel fuel, kerosene, fuel oil, natural gas, or another fuel which contains relatively high levels of organic sulfur compounds such as mercaptans, sulfides, disulfides, and the like. The hydrocarbon fuel supply is passed through a nickel reactant desulfurizer bed wherein essentially all of the sulfur in the organic sulfur compounds react with the nickel reactant, and are converted to nickel sulfide while the desulfurized fuel continues through the remainder of the fuel processing system. The fuel cell power plant and the processing system can be used to power a mobile vehicle, such an automobile, truck, bus, or the like. An auxiliary supply of hydrogen is provided in order to power the fuel cell power plant during start up of the fuel processing system. A second auxiliary supply of desulfurized fuel is also provided to operate the fuel cell power plant during an interim period until the highest temperature component of the fuel processing system is brought up to operational temperatures during the start up protocol.
    • 燃料气体处理系统可操作以基本上除去用于为移动车辆环境中的燃料电池发电厂供电的碳氢化合物燃料供应中基本上所有的硫。 发电厂燃料可以是汽油,柴油燃料,煤油,燃料油,天然气或含有较高水平的有机硫化合物如硫醇,硫化物,二硫化物等的另一种燃料。 烃燃料供应通过镍反应物脱硫器床,其中有机硫化合物中基本上所有的硫与镍反应物反应,并转化为硫化镍,而脱硫燃料继续通过燃料处理系统的其余部分。 燃料电池发电厂和处理系统可用于为诸如汽车,卡车,公共汽车等的移动车辆供电。 提供辅助氢气供应,以便在燃料处理系统启动期间为燃料电池发电厂供电。 还提供了第二辅助的脱硫燃料供应,以在燃料电池发电厂过渡期间操作,直到燃料处理系统的最高温度成分在启动协议期间达到工作温度。
    • 5. 发明授权
    • Compact selective oxidizer assemblage for a fuel cell power plant
    • 用于燃料电池发电厂的紧凑型选择性氧化器组合
    • US06284206B1
    • 2001-09-04
    • US09273735
    • 1999-03-22
    • Roger R. LesieurThomas J. CorriganDerek W. Hildreth
    • Roger R. LesieurThomas J. CorriganDerek W. Hildreth
    • F01N300
    • H01M8/0631C01B3/583C01B2203/044C01B2203/047F28D7/1653F28D7/1684F28F13/003H01M8/0662
    • A process gas selective oxidizer assemblage for use in a fuel cell power plant includes one or more catalyzed selective oxidizer process gas flow fields and one or more adjacent non-catalyzed heat exchanger process gas flow fields. The catalyzed selective oxidizer process gas flow fields may be formed with catalyzed pellets or with a monolithic catalyzed open cell foam component. The heat exchanger process gas flow fields are formed by non-catalyzed monolithic open cell foam components which have coolant fluid passages disposed therein. Planar metal sheets form a common wall between the selective oxidizer process gas flow fields and the heat exchanger process gas flow fields. The use of the open cell foam to form the heat exchanger process gas flow fields provides enhanced heat transfer between the reformate gas and the coolant fluid. The use of the foam components in both the heat exchange process gas flow fields and the selective oxidizer process gas flow fields enables the construction of a more compact and lighter weight selective oxidizer assemblage. The repeating components are placed side-by-side in the assemblage, so that one of the catalyzed process gas flow fields operates at a higher temperature than subsequent catalyzed process gas flow fields. The process gas enters the higher temperature catalyzed flow field after it is admixed with air that is injected into the system just prior to the higher temperature flow field. The process gas-air mixture flows through the first higher temperature catalyzed process gas flow field; thence through a non-catalyzed heat exchanger process gas flow field; thence through a lower temperature catalyzed process gas flow field; thence through another heat exchanger process gas flow field; and so on, until the selectively oxidized process gas exits the assemblage.
    • 用于燃料电池发电厂的工艺气体选择性氧化器组合包括一个或多个催化选择性氧化剂工艺气体流场和一个或多个相邻的非催化热交换器工艺气体流场。 催化的选择性氧化剂工艺气体流场可以用催化颗粒或整体催化的开孔泡沫组分形成。 热交换器工艺气体流场由其中设置有冷却剂流体通道的非催化单块开孔泡沫组件形成。 平面金属片在选择性氧化剂工艺气体流场和热交换器工艺气体流场之间形成公共壁。 使用开孔泡沫来形成热交换器工艺气体流场提供了改性气体和冷却剂流体之间的增强的热传递。 在热交换过程气体流场和选择性氧化剂处理气体流场中使用泡沫组分能够构建更紧凑和更轻重量的选择性氧化剂组合。 重复组分并排放置在组合中,使得催化过程气体流场中的一个在比随后的催化工艺气体流场更高的温度下操作。 在较高温度的流场之前,将工艺气体与注入系统的空气混合后,进入较高温度的催化流场。 工艺气体 - 空气混合物流过第一较高温度催化的工艺气体流场; 从而通过非催化热交换器工艺的气体流场; 从而通过较低温度催化的工艺气体流场; 从而通过另一个换热器工艺的气体流场; 等等,直到选择性氧化的工艺气体离开组合物。
    • 8. 发明授权
    • System and method for desulfurizing gasoline or diesel fuel to produce a
low sulfur-content fuel for use in an internal combustion engine
    • 用于将汽油或柴油燃料脱硫以产生用于内燃机的低含硫燃料的系统和方法
    • US6129835A
    • 2000-10-10
    • US221429
    • 1998-12-28
    • Roger R. LesieurLeonard J. Bonville, Jr.
    • Roger R. LesieurLeonard J. Bonville, Jr.
    • C10G25/00C10G29/04C10G45/00
    • C10G29/04C10G25/003
    • A fuel processing system is operable to remove substantially all of the sulfur present in gasoline or diesel fuel used for operating an internal combustion engine. The fuel supply is passed through a nickel reactant desulfurizer bed wherein essentially all of the sulfur in organic sulfur compounds in the fuel combine with the nickel reactant in the desulfurizer bed, and are converted to nickel sulfide. The desulfurizing system can operate at ambient or elevated pressures. The fuel can be treated either in a liquid phase or in a vapor phase. The sulfur scrubbing operation can be performed either in a vehicle while the latter is being operated, or at the fueling station (gas station) prior to sale to the end user. The amount of sulfur in the fuel can be lowered to less than about 0.05 ppm. This extends the life of the catalytic converters in vehicles, reduces corrosion of parts of the internal combustion engine, and provides an environmentally compatible system.
    • 燃料处理系统可操作以基本上除去用于操作内燃机的汽油或柴油燃料中基本上所有的硫。 燃料供应通过镍反应物脱硫器床,其中燃料中有机硫化合物中的基本上所有的硫与脱硫器床中的镍反应物组合,并转化为硫化镍。 脱硫系统可以在环境压力或高压下运行。 燃料可以在液相或气相中进行处理。 硫洗涤操作可以在车辆操作期间在车辆中执行,或者在向最终用户销售之前在加油站(加油站)执行。 燃料中的硫的量可以降低到小于约0.05ppm。 这延长了车辆中催化转化器的使用寿命,减少了内燃机部件的腐蚀,并提供了一个环保的系统。
    • 9. 发明授权
    • Compact fuel gas reformer assemblage
    • 紧凑型燃气改质机组合
    • US06203587B1
    • 2001-03-20
    • US09233223
    • 1999-01-19
    • Roger R. LesieurThomas J. Corrigan
    • Roger R. LesieurThomas J. Corrigan
    • B01J700
    • C01B3/384B01J19/2485B01J19/249B01J2219/00117B01J2219/00157B01J2219/2453B01J2219/2458B01J2219/2462B01J2219/2479B01J2219/2485C01B3/48C01B3/583C01B2203/0233C01B2203/0283C01B2203/044C01B2203/047C01B2203/066C01B2203/0811C01B2203/0844C01B2203/0866C01B2203/0883C01B2203/1023C01B2203/1052C01B2203/1064C01B2203/1082H01M8/0631
    • A fuel gas reformer assemblage for use in a fuel cell power plant is formed from a composite plate assembly which includes spaced-apart divider plates with interposed monolithic open cell sponge-like members which form gas passages. The monolithic members have a lattice of internal open cells which are both laterally and longitudinally interconnected so as to provide for a diffuse gas flow. The entire surface area of the monolithic components is wash coated with a porous alumina layer, and selected areas of the wash coat are also catalyzed. The reformer assemblage is constructed from a series of repeating sub-assemblies, each of which includes a core of separate regenerator/heat exchanger gas passages. The core in each sub-assembly is sandwiched between a pair of reformer gas passage skins, which complete the subassembly. Adjacent reformer gas/regenerator/reformer gas passage sub-assemblies in the composite plate assembly are separated from each other by burner gas passages. The regenerator/heat exchanger gas passages and the reformer gas passages in each sub-assembly are connected by gas flow return manifolds which form a part of each sub-assembly. The fuel gases flow in one end of the assemblage, through the reformer gas passages, and then reverse their direction of flow in the return manifolds so as to exit the reformer assemblage through the regenerator gas flow passages. The burner gases flow in one end of the reformer assemblage and out the other end.
    • 用于燃料电池发电厂的燃料气体重整器组件由复合板组件形成,复合板组件包括间隔开的分隔板,其具有形成气体通道的插入的整体开放式海绵状构件。 整体构件具有内部开孔的格子,其横向和纵向相互连接,以提供扩散气流。 单块组件的整个表面积用多孔氧化铝层进行洗涤,并且洗涤涂层的选定区域也被催化。 重整器组合由一系列重复子组件构成,每个重复组件包括单独的再生器/热交换器气体通道的核心。 每个子组件中的芯子夹在一对完成子组件的重整器气体通道皮之间。 复合板组件中相邻的重整器气体/再生器/重整器气体通道子组件通过燃烧器气体通道相互分离。 每个子组件中的再生器/热交换器气体通道和重整器气体通道通过形成每个子组件的一部分的气流返回歧管连接。 燃料气体通过重整器气体通道在组合件的一端中流动,然后在回流歧管中反转它们的流动方向,从而通过再生器气体流动通道离开重整器组件。 燃烧器气体在重整器组合的一端流动,另一端流出。