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1. 发明申请

US20130150541A1 Vinyl Terminated Higher Olefin Copolymers and Methods to Produce Thereof 有权
标题翻译：乙烯基封端的高级烯烃共聚物及其生产方法
公开(公告)号：US20130150541A1
公开(公告)日：2013-06-13
申请号：US13754422
申请日：2013-01-30
申请人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
发明人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
IPC分类号： C08F232/08 , C08F210/14
CPC分类号： C08F232/08 , C08F210/14 , Y10S526/943 , C08F210/06 , C08F2500/02
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。

2. 发明申请

US20120245310A1 Vinyl Terminated Higher Olefin Copolymers and Methods to Produce Thereof 有权
标题翻译：乙烯基封端的高级烯烃共聚物及其生产方法
公开(公告)号：US20120245310A1
公开(公告)日：2012-09-27
申请号：US13072249
申请日：2011-03-25
申请人： Donna J. CROWTHER , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
发明人： Donna J. CROWTHER , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
IPC分类号： C08F10/00 , C08F4/42 , C08F10/14
CPC分类号： C08F232/08 , C08F210/14 , Y10S526/943 , C08F210/06 , C08F2500/02
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。

3. 发明授权

US08399724B2 Vinyl terminated higher olefin copolymers and methods to produce thereof 有权
标题翻译：乙烯基封端的较高级烯烃共聚物及其制备方法
公开(公告)号：US08399724B2
公开(公告)日：2013-03-19
申请号：US13072249
申请日：2011-03-25
申请人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
发明人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
IPC分类号： C08F210/06 , C08F210/14 , C08F4/6592 , C10M107/06
CPC分类号： C08F232/08 , C08F210/14 , Y10S526/943 , C08F210/06 , C08F2500/02
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。

4. 发明授权

US08426659B2 Vinyl terminated higher olefin polymers and methods to produce thereof 有权
标题翻译：乙烯基封端的较高级烯烃聚合物及其生产方法
公开(公告)号：US08426659B2
公开(公告)日：2013-04-23
申请号：US13072288
申请日：2011-03-25
申请人： Matthew W. Holtcamp , Charles J. Ruff , Donna J. Crowther , John R. Hagadorn , Patrick Brant
发明人： Matthew W. Holtcamp , Charles J. Ruff , Donna J. Crowther , John R. Hagadorn , Patrick Brant
IPC分类号： C10M107/10 , C10M143/08
CPC分类号： C08F10/14 , C08F4/65908 , C08F4/65925 , C08F110/14 , C08F210/14 , C08F4/65927
摘要： This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by 1H NMR) including of one or more C4 to C40 higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.
摘要翻译：本发明涉及具有至少200g / mol（通过1 H NMR测量）的Mn的高级烯烃乙烯基封端聚合物，其包含一个或多个C 4至C 40高级烯烃衍生单元，其中高级烯烃乙烯基封端聚合物基本上不含丙烯单位; 并且其中所述较高级烯烃聚合物具有至少5％的烯丙基链末端及其生产方法。这些乙烯基封端的较高级烯烃聚合物可以任选地包括乙烯衍生的单元。

5. 发明申请

US20120245312A1 Vinyl Terminated Higher Olefin Polymers and Methods to Produce Thereof 有权
标题翻译：乙烯基终止的高级烯烃聚合物及其生产方法
公开(公告)号：US20120245312A1
公开(公告)日：2012-09-27
申请号：US13072288
申请日：2011-03-25
申请人： Matthew W. Holtcamp , Charles J. Ruff , Donna J. Crowther , John R. Hagadorn , Patrick Brant
发明人： Matthew W. Holtcamp , Charles J. Ruff , Donna J. Crowther , John R. Hagadorn , Patrick Brant
IPC分类号： C08F10/14 , C08F4/76
CPC分类号： C08F10/14 , C08F4/65908 , C08F4/65925 , C08F110/14 , C08F210/14 , C08F4/65927
摘要： This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by 1H NMR) including of one or more C4 to C40 higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.
摘要翻译：本发明涉及具有至少200g / mol（通过1 H NMR测量）的Mn的高级烯烃乙烯基封端聚合物，其包含一个或多个C 4至C 40高级烯烃衍生单元，其中高级烯烃乙烯基封端聚合物基本上不含丙烯单位; 并且其中所述较高级烯烃聚合物具有至少5％的烯丙基链末端及其生产方法。这些乙烯基封端的较高级烯烃聚合物可以任选地包括乙烯衍生的单元。

6. 发明授权

US08283419B2 Olefin functionalization by metathesis reaction 有权
标题翻译：烯烃通过复分解反应进行功能化
公开(公告)号：US08283419B2
公开(公告)日：2012-10-09
申请号：US12488093
申请日：2009-06-19
申请人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, Jr. , Donna J. Crowther , Patrick Brant
发明人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, Jr. , Donna J. Crowther , Patrick Brant
IPC分类号： C08F255/00 , C08F255/02 , C08F210/06 , C08F110/06
CPC分类号： C08F210/06 , C08F210/16 , C08F220/06 , C08F220/14 , C08F255/02 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)−83), when 70 to 90 mol % ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum.
摘要翻译：本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（加入的乙烯的摩尔％）+100），当共聚物中存在10至60mol％的乙烯时 - 低聚物，和2）X = 45，当共聚低聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83×（摩尔乙烯加入）-83），当70〜共聚低聚物中存在90mol％的乙烯。本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

7. 发明申请

US20090318647A1 Olefin Functionalization By Metathesis Reaction 有权
标题翻译：烯烃功能化通过复分解反应
公开(公告)号：US20090318647A1
公开(公告)日：2009-12-24
申请号：US12488093
申请日：2009-06-19
申请人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, JR. , Donna J. Crowther , Patrick Brant
发明人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, JR. , Donna J. Crowther , Patrick Brant
IPC分类号： C08F4/80 , C08F118/02 , C08F210/02 , C08F220/06 , C08F4/72
CPC分类号： C08F210/06 , C08F210/16 , C08F220/06 , C08F220/14 , C08F255/02 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)−83), when 70 to 90 mol % ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum.
摘要翻译：本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（加入的乙烯的摩尔％）+100），当共聚物中存在10至60mol％的乙烯时 - 低聚物，和2）X = 45，当共聚低聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83×（摩尔乙烯加入）-83），当70〜共聚低聚物中存在90mol％的乙烯。本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

8. 发明授权

US08809456B2 Polyolefin compositions and methods of production thereof 有权
标题翻译：聚烯烃组合物及其生产方法
公开(公告)号：US08809456B2
公开(公告)日：2014-08-19
申请号：US13449939
申请日：2012-04-18
申请人： Mun F. Tse , Aspy K. Mehta , Joann M. Canich , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff
发明人： Mun F. Tse , Aspy K. Mehta , Joann M. Canich , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff
IPC分类号： C08L53/00 , C08L53/02 , C08F8/00
CPC分类号： C08F290/048 , C08F8/50 , C08F290/044 , C08F299/00 , C08F2800/20 , C08F2810/30 , C08F2810/40 , C08K5/134 , C08K5/526 , C08L23/0815 , C08L27/12 , C08L51/06 , C08F297/04 , C08F210/02
摘要： This invention relates to methods for producing an alkene terminated polystyrene, including: contacting a styrenic block copolymer and an alkene in the presence of a metathesis catalyst under conditions sufficient to produce an alkene terminated polystyrene having an unsaturation functionality of at least 0.7 and a MWD of about 1.5 or less. Methods for producing functionalized polymers and polyethylene blend composition comprising these functionalized polymers are also disclosed.
摘要翻译：本发明涉及烯烃封端聚苯乙烯的制备方法，包括：在复分解催化剂存在下，使苯乙烯嵌段共聚物和烯烃接触，条件是足以产生不饱和官能度至少为0.7的烯烃封端聚苯乙烯，MWD为约1.5以下。还公开了制备官能化聚合物的方法和包含这些官能化聚合物的聚乙烯共混组合物。

9. 发明申请

US20130281626A1 Polyolefin Compositions and Methods of Production Thereof 有权
标题翻译：聚烯烃组合物及其生产方法
公开(公告)号：US20130281626A1
公开(公告)日：2013-10-24
申请号：US13449939
申请日：2012-04-18
申请人： Mun F. Tse , Aspy K. Mehta , Joann M. Canich , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff
发明人： Mun F. Tse , Aspy K. Mehta , Joann M. Canich , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff
IPC分类号： C08L53/00 , C08F8/00
CPC分类号： C08F290/048 , C08F8/50 , C08F290/044 , C08F299/00 , C08F2800/20 , C08F2810/30 , C08F2810/40 , C08K5/134 , C08K5/526 , C08L23/0815 , C08L27/12 , C08L51/06 , C08F297/04 , C08F210/02
摘要： This invention relates to methods for producing an alkene terminated polystyrene, including: contacting a styrenic block copolymer and an alkene in the presence of a metathesis catalyst under conditions sufficient to produce an alkene terminated polystyrene having an unsaturation functionality of at least 0.7 and a MWD of about 1.5 or less. Methods for producing functionalized polymers and polyethylene blend composition comprising these functionalized polymers are also disclosed.
摘要翻译：本发明涉及烯烃封端聚苯乙烯的制备方法，包括：在复分解催化剂存在下，使苯乙烯嵌段共聚物和烯烃接触，条件是足以产生不饱和官能度至少为0.7的烯烃封端聚苯乙烯，MWD为约1.5以下。还公开了制备官能化聚合物的方法和包含这些官能化聚合物的聚乙烯共混组合物。

10. 发明授权

US08604148B2 Functionalization of vinyl terminated polymers by ring opening cross metathesis 有权
标题翻译：乙烯基封端聚合物通过开环交叉复分解的功能化
公开(公告)号：US08604148B2
公开(公告)日：2013-12-10
申请号：US13306263
申请日：2011-11-29
申请人： Matthew W. Holtcamp , Donna J. Crowther , Caol P. Huff , Patrick Brant , Jacqueline A. Lovell
发明人： Matthew W. Holtcamp , Donna J. Crowther , Caol P. Huff , Patrick Brant , Jacqueline A. Lovell
IPC分类号： C08F293/00 , C08F285/00
CPC分类号： C08F222/04 , C08F293/00 , C08G61/08 , C08G61/124 , C08G61/125 , C08G61/126 , C08G2261/3324 , C08G2261/3342 , C08G2261/418
摘要： This invention relates to a polymer of a cyclic olefin and a vinyl terminated macromonomer, and processes for the production thereof.
摘要翻译：本发明涉及环烯烃和乙烯基封端的大分子单体的聚合物及其生产方法。

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