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1. 发明申请

US20090023946A1 SYNTHETIC METHOD OF GLYCOL DIESTERS FROM REACTION OF GLYCOL MONOESTERS AND LINEAR ALIPHATIC CARBOXYLIC ACIDS 有权
标题翻译：甘油单体和线性二羧酸反应的甘油二酯的合成方法
公开(公告)号：US20090023946A1
公开(公告)日：2009-01-22
申请号：US12241521
申请日：2008-09-30
申请人： Donghyun KO , Kwang Ho PARK , Sang Gi LEE , Jijoong MOON , Sungshik Eom , Dae Sun Rew
发明人： Donghyun KO , Kwang Ho PARK , Sang Gi LEE , Jijoong MOON , Sungshik Eom , Dae Sun Rew
IPC分类号： C07C69/34
CPC分类号： C07C67/08 , Y02P20/127 , C07C69/003 , C07C69/28
摘要： A method of synthesizing glycol diester by reacting a linear aliphatic carboxylic acid and a glycol monoester in the presence of a Lewis acid type catalyst is provided. In the method, after introducing the glycol monoester, the linear aliphatic carboxylic acid and the Lewis acid type catalyst into a reactor, the reaction occurs to produce reaction products and water in the reactor; an excess of the linear aliphatic carboxylic acid forms an azeotrope with water during the reaction to be sent to a condenser through a distillation column; the linear aliphatic carboxylic acid and water passed through the condenser are divided into an organic layer and an aqueous layer in an oil water separator; and the organic layer is returned to the distillation column through a material cycling line and water in the aqueous layer is removed through a water removal line. By utilizing reactive distillation technique, water produced during the reaction is rapidly removed, and thus the reaction time can be significantly reduced and the yield of the glycol diester can be maximized.
摘要翻译：提供了在路易斯酸型催化剂存在下使直链脂族羧酸和二醇单酯反应合成二醇二酯的方法。在该方法中，在将二醇单酯，直链脂肪族羧酸和路易斯酸型催化剂引入反应器中之后，发生反应以在反应器中产生反应产物和水; 过量的直链脂族羧酸在反应期间与水形成共沸物，通过蒸馏塔送至冷凝器; 将通过冷凝器的直链脂肪族羧酸和水分为油水分离器中的有机层和水层; 并且有机层通过材料循环管线返回到蒸馏塔，水层中的水通过除水管线除去。通过利用反应蒸馏技术，快速除去反应期间产生的水，从而可以显着降低反应时间，并使乙二醇二酯的产率最大化。

2. 发明申请

US20090247787A1 METHOD OF PRODUCING UNSATURATED ALDEHYDE AND/OR UNSATURATED ACID 有权
标题翻译：生产不饱和醛和/或不饱和酸的方法
公开(公告)号：US20090247787A1
公开(公告)日：2009-10-01
申请号：US12415167
申请日：2009-03-31
申请人： Yeon Shick YOO , Hyun Jong SHIN , Byung Yul CHOI , Young Hyun CHOI , Young Jin CHO , Duk Ki KIM , Joo Yeon PARK , Kwang Ho PARK
发明人： Yeon Shick YOO , Hyun Jong SHIN , Byung Yul CHOI , Young Hyun CHOI , Young Jin CHO , Duk Ki KIM , Joo Yeon PARK , Kwang Ho PARK
IPC分类号： C07C51/16
CPC分类号： B01J35/0006 , B01J8/0453 , B01J8/0457 , B01J8/0496 , B01J8/067 , B01J23/002 , B01J23/8876 , B01J23/8885 , B01J23/8892 , B01J23/8898 , B01J35/10 , B01J35/1009 , B01J35/1014 , B01J2208/025 , B01J2219/0004 , B01J2523/00 , C07C45/34 , C07C45/35 , C07C51/252 , C07C47/21 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/72 , B01J2523/842 , B01J2523/845 , B01J2523/31 , B01J2523/17 , B01J2523/24 , B01J2523/55 , B01J2523/69 , B01J2523/847
摘要： Disclosed is a shell-and-tube reactor that may be used for fixed-bed catalytic partial oxidation, the reactor being characterized by including at least one reaction zone of a first-step reaction zone for mainly producing unsaturated aldehydes and a second-step reaction zone for mainly producing unsaturated acids, wherein at least one reaction zone of the above reaction zones comprises two or more catalytic layers; each of the catalytic layers is packed with a formed product of catalyst that is different in pore density and/or pore size in a catalytically active component; and the pore density and/or pore size is controlled in such a manner that specific surface area of the catalytically active component increases from the inlet of the reactor to the outlet of the reactor. A method for producing unsaturated aldehydes and/or unsaturated fatty acids from olefins using the same reactor is also disclosed. According to the present invention, it is possible to control the temperature efficiently at a hot spot, thereby permitting stable use of a catalyst, and to produce unsaturated aldehydes and/or unsaturated fatty acids with high yield.
摘要翻译：公开了一种可用于固定床催化部分氧化的管壳式反应器，该反应器的特征在于包含至少一个主要产生不饱和醛的第一步反应区的反应区和第二步反应主要生产不饱和酸的区，其中上述反应区的至少一个反应区包含两个或多个催化层; 每个催化层用催化活性组分中孔密度和/或孔径不同的催化剂形成产物填充; 并且以使得催化活性组分的比表面积从反应器的入口增加到反应器的出口的方式来控制孔密度和/或孔径。还公开了使用相同的反应器由烯烃生产不饱和醛和/或不饱和脂肪酸的方法。根据本发明，可以在热点有效地控制温度，从而可以稳定地使用催化剂，并以高产率生产不饱和醛和/或不饱和脂肪酸。

3. 发明申请

US20090043127A1 COMPLEX METAL OXIDE CATALYST WITH HIGH (METH) ACRYLIC ACID SELECTIVITY 有权
标题翻译：具有高（甲基）丙烯酸选择性的复合金属氧化物催化剂
公开(公告)号：US20090043127A1
公开(公告)日：2009-02-12
申请号：US12252914
申请日：2008-10-16
申请人： Hyun Jong SHIN , Byung Yul CHOI , Yeon Shick YOO , Young Hyun CHOE , Young Jin CHO , Duk Ki KIM , Kwang Ho PARK , Joo Yeon PARK
发明人： Hyun Jong SHIN , Byung Yul CHOI , Yeon Shick YOO , Young Hyun CHOE , Young Jin CHO , Duk Ki KIM , Kwang Ho PARK , Joo Yeon PARK
IPC分类号： C07C51/16
CPC分类号： B01J23/002 , B01J23/31 , B01J23/8876 , B01J23/8877 , B01J23/8885 , B01J27/0576 , B01J37/0009 , B01J37/0236 , B01J2523/00 , C07C51/215 , C07C51/252 , C07C57/04 , B01J2523/13 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/56 , B01J2523/64 , B01J2523/17 , B01J2523/24 , B01J2523/55 , B01J2523/69
摘要： Disclosed are a Mo—Bi—Nb—Te based composite metal oxide; and a process for producing (meth)acrylic acid from at least one reaction material selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, wherein the Mo—Bi—Nb—Te based composite metal oxide is used as a catalyst. Also, disclosed is a process for producing (meth)acrylic acid comprising a first step of producing (meth)acrolein as a main product from at least one reaction material selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, and a second step of producing (meth)acrylic acid from the (meth)acrolein, wherein yield of (meth)acrylic acid in the product of the first step is 20 mole % or higher.
摘要翻译：公开了一种Mo-Bi-Nb-Te基复合金属氧化物; 和由选自丙烯，丙烷，异丁烯，叔丁醇和甲基叔丁基醚中的至少一种反应材料生产（甲基）丙烯酸的方法，其中Mo-Bi-Nb-Te基复合金属氧化物用作催化剂。还公开了一种生产（甲基）丙烯酸的方法，该方法包括以下步骤：从选自丙烯，丙烷，异丁烯，叔丁醇的至少一种反应材料和甲基叔丁基醚，以及由（甲基）丙烯醛制备（甲基）丙烯酸的第二步，其中第一步产物中（甲基）丙烯酸的收率为20摩尔％以上。

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