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    • 5. 发明授权
    • Method for growing epitaxial layers of III-V compound semiconductors
    • 生长III-V族化合物半导体外延层的方法
    • US5900056A
    • 1999-05-04
    • US769242
    • 1996-12-18
    • Sung-Woo ChoiJong-Hyeob BaekBun Lee
    • Sung-Woo ChoiJong-Hyeob BaekBun Lee
    • H01L21/20C30B25/10C30B25/14
    • C30B25/105C30B29/40
    • The present invention relates to a method for growing new binary, ternary and quaternary epitaxial layers of III-V compound semiconductors which have the characteristics of low temperature growth, good stability and high-purity, using remote plasma, comprising the steps of converting H.sub.2 and He mixed gas into a plasma state; heating a high-purity of solid source to generate a vaporized source; reacting the vaporized source with H.sub.2 under the H.sub.2 and He plasma environment to produce V-hydrides in situ; introducing the V-hydrides directly into group III source without passing through the plasma; and reacting V-hydrides with group III source on a substrate to form an epitaxial thin layer of III-V compound semiconductors. According to the present invention, high-purity of epitaxial thin layer can be formed at a low temperature, an economical process that does not require an ultrahigh vacuum, a stabilized process that does not need to handle poisonous gas for the reaction with gropu V, and a simple process for manufacturing the various binary, ternary and quaternary compound semiconductor alloys can be provided. Thus, the method of the present invention can be applied to the future information and communication industry, for example, high speed, high frequency optical communication system with (Ga, In, Al)--(As, P, Sb) based on III-V compound semiconductor electronic and optical devices, and the circuitry thereof including heterojunction bipolar transistors, high electron mobility transistors, semiconductor lasers and optical switches.
    • 本发明涉及一种利用远程等离子体生长具有低温生长特性,稳定性好,高纯度等特点的III-V族化合物半导体二元,三元和四元外延层的方法,包括以下步骤:将H 2和 他将气体混合成等离子体状态; 加热高纯度固体源以产生蒸发源; 在H 2和He等离子体环境下使蒸发源与H 2反应,原位产生V-氢化物; 将V型氢化物直接引入III族源而不通过等离子体; 并将V型氢化物与III族源反应在衬底上以形成III-V族化合物半导体的外延薄层。 根据本发明,可以在低温下形成高纯度的外延薄层,不需要超高真空的经济工艺,不需要处理有毒气体用于与gropu V反应的稳定过程, 并且可以提供制造各种二元,三元和四元化合物半导体合金的简单方法。 因此,本发明的方法可以应用于将来信息通信行业,例如具有(Ga,In,Al) - (As,P,Sb)的高速,高频光通信系统, V化合物半导体电子和光学器件,其电路包括异质结双极晶体管,高电子迁移率晶体管,半导体激光器和光开关。
    • 6. 发明授权
    • Method for two-dimensional epitaxial growth of III-V compound
semiconductors
    • III-V化合物半导体的二维外延生长方法
    • US5456206A
    • 1995-10-10
    • US350451
    • 1994-12-07
    • Bun LeeMee-Young YoonJong-Hyeob Baek
    • Bun LeeMee-Young YoonJong-Hyeob Baek
    • H01L21/20
    • H01L21/02502H01L21/02395H01L21/02463H01L21/02546H01L21/0262
    • A method for growing a thin InGaAs or InAlAs layer with heavy lattice mismatching on a GaAs substrate by a MOCVD process is described. A first material gas is injected by a MOCVD process to grow a buffer layer on a GaAs substrate to a prescribed thickness. After stopping the injection of the first material gas for a few seconds, a second material gas containing a column III element is injected at a prescribed temperature. A third material gas containing a column V element is injected to grow, on the buffer layer, a thin metallic layer of a binary compound containing the column III element of a high concentration to a thickness of 2 nm or less. After a prescribed time from the injection of the third material gas, In and Ga gases or In and Al gases, mixed in the prescribed proportion are injected in an atmosphere of said third material gas to grow a thin InGaAs or InAlAs layer on the thin metallic layer.
    • 描述了通过MOCVD工艺在GaAs衬底上生长具有重晶格失配的薄InGaAs或InAlAs层的方法。 通过MOCVD法注入第一材料气体,以在GaAs衬底上生长规定厚度的缓冲层。 在停止喷射第一原料气体几秒钟后,在规定温度下注入含有III族元素的第二原料气体。 注入含有V族元素的第三材料气体,在缓冲层上生长含有高浓度的III族元素的二元化合物的薄金属层,厚度为2nm以下。 在注入第三原料气体的规定时间后,在所述第三原料气体的气氛中注入以规定比例混合的In和Ga气体或In和Al气体,以在薄金属上生长薄的InGaAs或InAlAs层 层。
    • 8. 发明授权
    • Method for fabricating grating coupler
    • 光栅耦合器的制作方法
    • US5855669A
    • 1999-01-05
    • US842872
    • 1997-04-17
    • Jong-Hyeob BaekBun Lee
    • Jong-Hyeob BaekBun Lee
    • G02B6/293C30B25/02G02B5/18G02B6/122G02B6/124G02B6/34H01L21/203C30B25/16
    • C30B25/02C30B29/40G02B6/124G02B6/34
    • A grating coupler is formed by growing an optical waveguide layer on a substrate by an epitaxial growing process such as a metalorganic chemical vapor deposition and a molecular beam deposition. The optical waveguide layer has a surface on which a cross-hatch pattern serving as the grating is continuously formed. The optical waveguide layer is formed with a material having a reflective index greater than a reflective index of the substrate or an atmosphere. Specifically, the substrate is formed with GaAs and the optical waveguide layer is formed with InGaAs. Further, the substrate is an on-substrate having an orientation coinciding with a �100! plane, so as to form the optical waveguide layer having continuous cross-hatch patterns on the surface thereof. The spacing between the cross-hatch patterns can be varied according to variation of a growth temperature of the optical waveguide layer.
    • 通过外延生长工艺如金属有机化学气相沉积和分子束沉积在衬底上生长光波导层来形成光栅耦合器。 光波导层具有连续形成用作光栅的交叉影线图案的表面。 光波导层由具有大于基板的反射率或大气的反射率的材料形成。 具体地,基板由GaAs形成,并且光波导层由InGaAs形成。 此外,基板是具有与[100]面重合的取向的基板,从而在其表面上形成具有连续交叉图案的光波导层。 交叉线图案之间的间隔可以根据光波导层的生长温度的变化而变化。