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1. 发明授权

US5716592A Cerous chloride-chromic oxide catalyst for producing chlorine, methods for producing the same and a method for producing chlorine 失效
标题翻译：用于生产氯的氯化铈 - 氧化铬催化剂，其制备方法和氯生产方法
公开(公告)号：US5716592A
公开(公告)日：1998-02-10
申请号：US711226
申请日：1996-09-09
申请人： Byoung Sung Ahn , Dong Ju Moon , Kun You Park , Moon Jo Chung
发明人： Byoung Sung Ahn , Dong Ju Moon , Kun You Park , Moon Jo Chung
IPC分类号： B01J23/26 , B01J27/132 , B01J27/138 , C01B7/04
CPC分类号： B01J27/132 , B01J23/26 , B01J27/138 , Y10S423/12
摘要： A process for producing chlorine by reaction of gaseous hydrogen chloride with oxygen in the presence of a catalyst prepared by reaction of chromium trioxide and cerous chloride with ethanol and calcination of the resulting reaction product, or, alternatively, prepared by reaction of chromium trioxide with ethanol, and calcination and impregnation of the resulting chromic oxide with aqueous solution of cerous chloride.
摘要翻译：在三氧化二砷和氯化铈与乙醇反应制备的催化剂存在下，通过气态氯化氢与氧反应生成氯的方法，煅烧所得反应产物，或者通过三氧化铬与乙醇的反应制备氯的方法，并用氯化铈水溶液煅烧和浸渍所得到的氧化铬。

2. 发明授权

US06306349B1 Catalyst characterization apparatus 有权
标题翻译：催化剂表征装置
公开(公告)号：US06306349B1
公开(公告)日：2001-10-23
申请号：US09449467
申请日：1999-11-29
申请人： Dong Ju Moon , Kun You Park , Moon Jo Chung , Byoung Sung Ahn
发明人： Dong Ju Moon , Kun You Park , Moon Jo Chung , Byoung Sung Ahn
IPC分类号： G01N3110
CPC分类号： G01N15/0893 , G01N31/10 , G01N2015/0833
摘要： The present invention relates to a catalyst characterization apparatus, and in particular to an improved catalyst characterization apparatus which is capable of characterizing the surface of a catalyst more accurately by a volumetric method without requiring a pre-treatment step which may vary the characteristics of the catalyst as well as without exposing the catalyst in air, by combining a dynamic flow type reactor with a volumetric type adsorption apparatus, whereby it is possible to accurately characterize the catalyst during an actual reaction. It is possible to accurately characterize the various catalysts and to characterize the catalyst during the reaction, alternately and/or continuously, by combining a dynamic flow type reactor with a volumetric type characterization apparatus as well as a dynamic flow type characterization apparatus.
摘要翻译：本发明涉及一种催化剂表征装置，特别涉及一种改进的催化剂表征装置，其能够通过体积法更准确地表征催化剂的表面，而不需要可改变催化剂特性的预处理步骤以及通过将动态流动型反应器与体积型吸附装置组合而不使空气中的催化剂暴露，由此可以在实际反应期间精确地表征催化剂。可以通过组合动态流动型反应器与体积型表征装置以及动态流动型表征装置来交替地和/或连续地精确地表征各种催化剂并且在反应期间表征催化剂。

3. 发明授权

US5663112A Cerous chloride-chromic oxide catalyst for producing chlorine, methods for producing the same and a method for producing chlorine 失效
标题翻译：用于生产氯的氯化铈 - 氧化铬催化剂，其制备方法和氯生产方法
公开(公告)号：US5663112A
公开(公告)日：1997-09-02
申请号：US346519
申请日：1994-11-29
申请人： Byoung Sung Ahn , Dong Ju Moon , Kun You Park , Moon Jo Chung
发明人： Byoung Sung Ahn , Dong Ju Moon , Kun You Park , Moon Jo Chung
IPC分类号： B01J23/26 , B01J27/132 , B01J27/138 , B01J23/00
CPC分类号： B01J27/132 , B01J23/26 , B01J27/138 , Y10S423/12
摘要： A novel cerous chloride-chromium oxide catalyst useful for oxidizing hydrogen chloride to chlorine. The catalyst is prepared by the reaction of chromium trioxide and cerous chloride with ethanol and calcining the reaction product. The catalyst is also prepared by the reaction of chromium trioxide with ethanol, then calcination and impregnation of the resultant chromic oxide with aqueous solution of cerous chloride. The obtained catalyst exhibits high activity at low reaction temperature.
摘要翻译：一种用于将氯化氢氧化成氯的新型氯化铈 - 氧化铬催化剂。催化剂通过三氧化铬和氯化铈与乙醇的反应制备，并煅烧反应产物。催化剂也可以通过三氧化铬与乙醇的反应制备，然后用氯化铈水溶液煅烧和浸渍所得到的氧化铬。所得催化剂在低反应温度下表现出高活性。

4. 发明授权

US5841007A Process for manufacturing 1,1,1,2-tetrafluoroethane 失效
标题翻译：制备1,1,1,2-四氟乙烷的方法
公开(公告)号：US5841007A
公开(公告)日：1998-11-24
申请号：US630678
申请日：1996-04-12
申请人： Byoung Sung Ahn , Young Soo Kwon , Kun You Park , Moon Jo Chung
发明人： Byoung Sung Ahn , Young Soo Kwon , Kun You Park , Moon Jo Chung
IPC分类号： C07C17/20 , C07C17/21 , C07C19/08 , C07C17/00
CPC分类号： C07C19/08 , C07C17/206 , C07C17/21
摘要： The present invention relates to a process for manufacturing 1,1,1,2-tetrafluoroethane (HFC-134a) from trichloroethylene (TCE) and hydrogen fluoride (HF) by reacting the HCFC-133a with the HF to produce the HFC-134a and reacting the TCE with the HF to produce 1-choro-2,2,2-trifluoroethane (HCFC-133a), characterized by that a part of said HF is mixed with the mixture containing the HFC-134a and the remaining portion of said HF is fed with said TCE in portions to at least two sections of a reactor for producing said HCFC-133a. According the present process, the temperature change in the reactor for producing HCFC-133a is maintained within a narrow range over the whole reaction procedures, and the catalytic activity is well maintained. Further, the formation of by-products is considerably prevented and thus the productivity is remarkably enhanced.
摘要翻译：本发明涉及通过使HCFC-133a与HF反应生成HFC-134a，从三氯乙烯（TCE）和氟化氢（HF）制备1,1,1,2-四氟乙烷（HFC-134a）使TCE与HF反应以产生1-氯-2,2,2-三氟乙烷（HCFC-133a），其特征在于，将所述HF的一部分与含有HFC-134a和所述HF的剩余部分的混合物混合与所述TCE一起供给至用于生产所述HCFC-133a的反应器的至少两个部分。根据本方法，生产HCFC-133a的反应器中的温度变化在整个反应过程中保持在窄范围内，并且催化活性得到很好的维持。此外，可以显着地防止副产物的形成，从而显着提高生产率。

5. 发明授权

US06566567B2 Catalyst and method for producing 1,1-difluoroethane 失效
公开(公告)号：US06566567B2
公开(公告)日：2003-05-20
申请号：US09897899
申请日：2001-07-05
申请人： Byoung Sung Ahn , Jung Hwan Song , Dong Ju Moon , Kun You Park
发明人： Byoung Sung Ahn , Jung Hwan Song , Dong Ju Moon , Kun You Park
IPC分类号： C07C1710
CPC分类号： B01J37/22 , B01J21/18 , B01J23/44 , C07C17/23 , C07C19/08
摘要： The present invention relates to a catalyst for producing 1,1-difluoroethane (HCFC-152a) and producing method thereof. More particularly, it is to provide the catalyst prepared by impregnating palladium on the active carbon pretreated with an aqueous hydrogen fluoride solution and an aqueous hydrogen chloride solution in series and its use in the production of 1,1-difluoroethane (HCFC-142b) by dehydrochlorinating 1,1-difluoro-1-chloroethane at 240-300° C. in the supplying molar ratio of 2-6 (H2/HCFC-142b) with maximizing a selectivity toward the product of HCFC-152a.

6. 发明授权

US06231780B1 Refrigerant mixture substitute for chlorodifluoromethane 失效
标题翻译：制冷剂混合物代替氯二氟甲烷
公开(公告)号：US06231780B1
公开(公告)日：2001-05-15
申请号：US09410058
申请日：1999-10-01
申请人： Byung Gwon Lee , Jong Sung Lim , Kun You Park , Byoung Sung Ahn , Sang Deuk Lee
发明人： Byung Gwon Lee , Jong Sung Lim , Kun You Park , Byoung Sung Ahn , Sang Deuk Lee
IPC分类号： C09K504
CPC分类号： C09K5/045 , C09K2205/112 , C09K2205/12 , C09K2205/128 , C09K2205/43
摘要： A refrigerant composition useful as a substitute for chlorodifluoromethane (CHCIF2, HCFC-22). The refrigerant mixture has a first constituent of difluoromethane (CH2F2, HFC-32); a second constituent selected from perfluoropropane (C3F8, PFC-218), cyclopropane (C3H6, RC-270) and butane (C4H10, R-600); and a third constituent selected from 1,1-difluoroethane (CH3CHF2, HFC-152a), 1,1,1,2,2-pentafluoropropane (CH3CF2CF3, HFC-245cb) and bis(difluoromethyl)ether (CHF2OCHF2, HFE-134).
摘要翻译：用作氯代二氟甲烷（CHCIF2，HCFC-22）的替代物的制冷剂组合物。制冷剂混合物具有二氟甲烷的第一组分（CH 2 F 2，HFC-32）; 选自全氟丙烷（C3F8，PFC-218），环丙烷（C3H6，RC-270）和丁烷（C4H10，R-600）的第二种成分; 和选自1,1-二氟乙烷（CH 3 CHF 2，HFC-152a），1,1,1,2,2-五氟丙烷（CH 3 CF 2 CF 3，HFC-245cb）和双（二氟甲基）醚（CHF 2 OCH 2，HFE-134）。

7. 发明授权

US06841087B2 Refrigerant composition comprising difluoromethane, 1,1,1-trifluoroethane and 1,1,1,2-tetrafluoroethane 失效
标题翻译：包含二氟甲烷，1,1,1-三氟乙烷和1,1,1,2-四氟乙烷的制冷剂组合物
公开(公告)号：US06841087B2
公开(公告)日：2005-01-11
申请号：US10127217
申请日：2002-04-19
申请人： Byung-Gwon Lee , Jong-Sung Lim , Byoung Sung Ahn , Kun You Park , Chang-Nyeon Kim
发明人： Byung-Gwon Lee , Jong-Sung Lim , Byoung Sung Ahn , Kun You Park , Chang-Nyeon Kim
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/12 , C09K2205/22
摘要： A refrigerant composition that can be a substitute for chlorodifluoromethane (HCFC-22) comprises: (a) a first constituent of difluoromethane, (b) a second constituent of 1,1,1-trifluoroethane, (c) a third constituent of 1,1,1,2-tetrafluoroethane, and (d) a fourth constituent selected from the group consisting of 1,1-difluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, 1,1,1,2,3,3-hexafluropropane and butane.
摘要翻译：可以代替氯二氟甲烷（HCFC-22）的制冷剂组合物包括：（a）二氟甲烷的第一组分，（b）1,1,1-三氟乙烷的第二组分，（c）1的第三组分， 1,1,2-四氟乙烷，和（d）选自1,1-二氟乙烷，1,1,1,2,3,3,3-七氟丙烷，1,1,1,2 ，3,3-己基丙烷和丁烷。

8. 发明授权

US06592773B2 Refrigerant mixture comprising difluromethane, pentafluroethane and 1,1,1-trifluoroethane 失效
公开(公告)号：US06592773B2
公开(公告)日：2003-07-15
申请号：US10338139
申请日：2003-01-08
申请人： Byung Gwon Lee , Jong Sung Lim , Kun You Park , Moon Jo Chung , Seong Joon Cho
发明人： Byung Gwon Lee , Jong Sung Lim , Kun You Park , Moon Jo Chung , Seong Joon Cho
IPC分类号： C09K504
CPC分类号： C09K5/045 , C09K2205/112 , C09K2205/12 , C09K2205/22 , C09K2205/43
摘要： A novel refrigerant composition useful as a substitute for HCFC-22, comprising a first constituent of difluoromethane (CH2F2, HFC-32); a second constituent of pentafluoroethane (CHF2CF3, HFC-125); a third constituent of 1,1,1-trifluoroethane (CH3CF3, HFC-143a); a fourth constituent selected from the group consisting of cyclopropane (C3H6, RC-270), 1,1,1,2,3,3,3-heptafluoropropane (CF3CHFCF3, HFC-227ea), 1,1,1,2,2-pentafluoropropane (CH3CF2CF3, HFC-245cb), isobutane (CH(CH3)2CH3, R-600a), octafluorocyclobutane (C4F8, RC-318), 1,1,1,2,3,3-hexafluoropropane (CHF2CHFCF3, HFC-236ea), butane (C4H10, R-600), bis(difluoromethyl)ether (CHF2OCHF2, HFE-134) and pentafluoroethylmethylether (CF3CF2OCH3, HFE-245).

9. 发明授权

US5959166A Method for concurrently producing different hydrofluoro carbons 失效
标题翻译：同时生产不同氢氟碳的方法
公开(公告)号：US5959166A
公开(公告)日：1999-09-28
申请号：US966093
申请日：1997-11-07
申请人： Hoon Sik Kim , Moon Jo Chung , Kun You Park , Young Soo Kwon
发明人： Hoon Sik Kim , Moon Jo Chung , Kun You Park , Young Soo Kwon
IPC分类号： B01J23/26 , B01J27/125 , B01J27/132 , B01J27/138 , C07B61/00 , C07C17/20 , C07C17/21 , C07C19/08 , C07C19/10 , C07C17/08
CPC分类号： C07C17/206 , C07C17/21 , Y02P20/582
摘要： A method for concurrently producing different hydrofluoro carbons, comprising the reaction of halocarbon or hydrohalocarbon with hydrogen fluoride in a reaction system consisting of a series of at least two discrete reactors, in the presence of catalysts, said reactors each being provided with different reactant materials and differing in reaction conditions including the catalysts and/or reaction temperature, thereby flexibly controlling their production rates in accordance with fluctuations in their demand, and eliminating the risk of constructing large scale plants responsible for individual hydrofluorocarbons.
摘要翻译：一种同时生产不同氢氟碳的方法，包括在由一系列至少两个不连续的反应器组成的反应体系中，在催化剂存在下，卤代烃或氢卤化碳与氟化氢的反应，所述反应器各自具有不同的反应物料和包括催化剂和/或反应温度在内的反应条件不同，从而根据其需求的波动灵活地控制其生产率，并消除构建负责单个氢氟碳化物的大型设备的风险。

10. 发明授权

US06524495B1 Refrigerant mixture comprising difluromethane, pentafluroethane and 1,1,1-trifluoroethane 失效
标题翻译：包含二氟甲烷，五氟乙烷和1,1,1-三氟乙烷的制冷剂混合物
公开(公告)号：US06524495B1
公开(公告)日：2003-02-25
申请号：US09710578
申请日：2000-11-09
申请人： Byung Gwon Lee , Jong Sung Lim , Kun You Park , Moon Jo Chung , Seong Joon Cho
发明人： Byung Gwon Lee , Jong Sung Lim , Kun You Park , Moon Jo Chung , Seong Joon Cho
IPC分类号： C09K504
CPC分类号： C09K5/045 , C09K2205/112 , C09K2205/12 , C09K2205/22 , C09K2205/43
摘要： A novel refrigerant composition useful as a substitute for HCFC-22, comprising a first constituent of difluoromethane (CH2F2, HFC-32); a second constituent of pentafluoroethane (CHF2CF3, HFC-125); a third constituent of 1,1,1-trifluoroethane (CH3CF3, HFC-143a); a fourth constituent selected from the group consisting of cyclopropane (C3H6, RC-270), 1,1,1,2,3,3,3-heptafluoropropane (CF3CHFCF3, HFC-227ea), 1,1,1,2,2-pentafluoropropane (CH3CF2CF3, HFC-245cb), isobutane (CH(CH3)2CH3, R-600a), octafluorocyclobutane (C4F8, RC-318), 1,1,1,2,3,3-hexafluoropropane (CHF2CHFCF3, HFC-236ea), butane (C4H10, R-600), bis(difluoromethyl)ether (CHF2OCHF2, HFE-134) and pentafluoroethylmethylether (CF3CF2OCH3, HFE-245).
摘要翻译：一种可用作HCFC-22替代物的新型制冷剂组合物，其包含二氟甲烷（CH 2 F 2，HFC-32）的第一组分; 五氟乙烷（CHF 2 CF 3，HFC-125）的第二组分; 1,1,1-三氟乙烷（CH 3 CF 3，HFC-143a）的第三组分; 选自环丙烷（C 3 H 6，RC-270），1,1,1,2,3,3,3-七氟丙烷（CF 3 CHFCF 3，HFC-227ea），1,1,1,2,2 （CH 3 CF 2 CF 3，HFC-245cb），异丁烷（CH（CH 3）2 CH 3，R-600a），八氟环丁烷（C 4 F 8，RC-318），1,1,1,2,3,3-六氟丙烷（CHF 2 CHFCF 3， 236EA），丁烷（C4H10，R-600），双（二氟甲基）醚（CHF2OCHF2，HFE-134）和五氟乙基甲基醚（CF3CF2OCH3，HFE-245）。

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