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1. 发明授权

US06403848B1 Preparation of hexafluoropropylene from the pyrolysis of trifluoromethane and tetrafluoroethylene 失效
标题翻译：从三氟甲烷和四氟乙烯的热解制备六氟丙烯
公开(公告)号：US06403848B1
公开(公告)日：2002-06-11
申请号：US09820631
申请日：2001-03-30
申请人： Dong Ju Moon , Hong Gon Kim , Byoung Sung Ahn , Moon Jo Chung , Young Soo Kwon
发明人： Dong Ju Moon , Hong Gon Kim , Byoung Sung Ahn , Moon Jo Chung , Young Soo Kwon
IPC分类号： C07C1702
CPC分类号： C07C17/269 , C07C21/18
摘要： The present invention relates to a process for preparing hexafluoropropylene(CF3CF═CF2, HFP) from the pyrolysis of trifluoromethane(CHF3, R23) and tetrafluoroethylene(C2F4, TFE) and more particularly, to the process for preparing hexafluoropropylene from the pyrolysis of an admixture of R23 and TFE mixed in an appropriate molar ratio at below 900 which is lower than the conventional reaction temperature and longer residence time, after investigating the pyrolysis reaction of R23 and TFE by the computer simulation. The process for preparing HFP is performed by carefully controlling reaction temperature with heat balance resulted from an endothermic pyrolysis of R23 and an exothermic dimerization of TFE to prevent from carbon formation, recycling unreacted R23 and TFE in the product separated and purified from distillation column, adding fresh R23 additionally to keep an appropriate molar ratio of R23 and TFE, to improve a total yield of HFP and to minimize heat supply from outside.
摘要翻译：本发明涉及从三氟甲烷（CHF 3，R 23）和四氟乙烯（C 2 F 4，TFE）的热解制备六氟丙烯（CF 3 CF = CF 2，HFP）的方法，更具体地说，涉及从混合物的热解制备六氟丙烯的方法通过计算机模拟研究R23和TFE的热解反应后，R23和TFE以适合的摩尔比混合在900以下，低于常规反应温度和较长的停留时间。制备HFP的过程是通过仔细控制反应温度和由R23的吸热热解产生的热平衡和TFE的放热二聚反应来防止形成碳，循环未反应的R23和TFE，从蒸馏塔中分离和纯化，加入新鲜的R23另外保持适当的R23和TFE的摩尔比，以提高HFP的总产率并最小化从外部的供热。

2. 发明授权

US06710215B2 Method of a simultaneous preparation of hexafluoropropylene and octafluorocyclobutane 失效
标题翻译：同时制备六氟丙烯和八氟环丁烷的方法
公开(公告)号：US06710215B2
公开(公告)日：2004-03-23
申请号：US10218362
申请日：2002-08-14
申请人： Dong Ju Moon , Moon Jo Chung , Young Soo Kwon , Byoung Sung Ahn
发明人： Dong Ju Moon , Moon Jo Chung , Young Soo Kwon , Byoung Sung Ahn
IPC分类号： C07C1700
CPC分类号： C07C23/06 , C07C17/269 , C07C17/281 , C07C21/185
摘要： A method of simultaneous and selective prepararation of hexafluoropropylene and octafluorocyclebutane comprising the steps of: (a) thermally decomposing difluorochloromethane to obtain tetrafluoroethylene and then supplying the resulting tetrafluoroethylene into a fluidized bed reactor equipped with a distributor for supplying steam; and (b) supplying steam into a flow of tetrafluoroethylene supplied into the fluidized bed reactor, through a distributor for supplying steam at a certain molar ratio of tetrafluoroethylene/stream, and then performing dimerization of tetrafluoroethylene in the fluidized bed reactor under an atmospheric pressure.
摘要翻译：一种同时和选择性制备六氟丙烯和八氟环丁烷的方法，包括以下步骤：（a）热分解二氟氯甲烷以获得四氟乙烯，然后将所得的四氟乙烯供给到装有用于供应蒸汽的分配器的流化床反应器中; 和（b）通过用于以一定摩尔比的四氟乙烯/料流供给蒸汽的分配器供应蒸汽供入到流化床反应器中的四氟乙烯流中，然后在大气压下在流化床反应器中进行四氟乙烯的二聚。

3. 发明授权

US5716592A Cerous chloride-chromic oxide catalyst for producing chlorine, methods for producing the same and a method for producing chlorine 失效
标题翻译：用于生产氯的氯化铈 - 氧化铬催化剂，其制备方法和氯生产方法
公开(公告)号：US5716592A
公开(公告)日：1998-02-10
申请号：US711226
申请日：1996-09-09
申请人： Byoung Sung Ahn , Dong Ju Moon , Kun You Park , Moon Jo Chung
发明人： Byoung Sung Ahn , Dong Ju Moon , Kun You Park , Moon Jo Chung
IPC分类号： B01J23/26 , B01J27/132 , B01J27/138 , C01B7/04
CPC分类号： B01J27/132 , B01J23/26 , B01J27/138 , Y10S423/12
摘要： A process for producing chlorine by reaction of gaseous hydrogen chloride with oxygen in the presence of a catalyst prepared by reaction of chromium trioxide and cerous chloride with ethanol and calcination of the resulting reaction product, or, alternatively, prepared by reaction of chromium trioxide with ethanol, and calcination and impregnation of the resulting chromic oxide with aqueous solution of cerous chloride.
摘要翻译：在三氧化二砷和氯化铈与乙醇反应制备的催化剂存在下，通过气态氯化氢与氧反应生成氯的方法，煅烧所得反应产物，或者通过三氧化铬与乙醇的反应制备氯的方法，并用氯化铈水溶液煅烧和浸渍所得到的氧化铬。

4. 发明授权

US06306349B1 Catalyst characterization apparatus 有权
标题翻译：催化剂表征装置
公开(公告)号：US06306349B1
公开(公告)日：2001-10-23
申请号：US09449467
申请日：1999-11-29
申请人： Dong Ju Moon , Kun You Park , Moon Jo Chung , Byoung Sung Ahn
发明人： Dong Ju Moon , Kun You Park , Moon Jo Chung , Byoung Sung Ahn
IPC分类号： G01N3110
CPC分类号： G01N15/0893 , G01N31/10 , G01N2015/0833
摘要： The present invention relates to a catalyst characterization apparatus, and in particular to an improved catalyst characterization apparatus which is capable of characterizing the surface of a catalyst more accurately by a volumetric method without requiring a pre-treatment step which may vary the characteristics of the catalyst as well as without exposing the catalyst in air, by combining a dynamic flow type reactor with a volumetric type adsorption apparatus, whereby it is possible to accurately characterize the catalyst during an actual reaction. It is possible to accurately characterize the various catalysts and to characterize the catalyst during the reaction, alternately and/or continuously, by combining a dynamic flow type reactor with a volumetric type characterization apparatus as well as a dynamic flow type characterization apparatus.
摘要翻译：本发明涉及一种催化剂表征装置，特别涉及一种改进的催化剂表征装置，其能够通过体积法更准确地表征催化剂的表面，而不需要可改变催化剂特性的预处理步骤以及通过将动态流动型反应器与体积型吸附装置组合而不使空气中的催化剂暴露，由此可以在实际反应期间精确地表征催化剂。可以通过组合动态流动型反应器与体积型表征装置以及动态流动型表征装置来交替地和/或连续地精确地表征各种催化剂并且在反应期间表征催化剂。

5. 发明授权

US5663112A Cerous chloride-chromic oxide catalyst for producing chlorine, methods for producing the same and a method for producing chlorine 失效
标题翻译：用于生产氯的氯化铈 - 氧化铬催化剂，其制备方法和氯生产方法
公开(公告)号：US5663112A
公开(公告)日：1997-09-02
申请号：US346519
申请日：1994-11-29
申请人： Byoung Sung Ahn , Dong Ju Moon , Kun You Park , Moon Jo Chung
发明人： Byoung Sung Ahn , Dong Ju Moon , Kun You Park , Moon Jo Chung
IPC分类号： B01J23/26 , B01J27/132 , B01J27/138 , B01J23/00
CPC分类号： B01J27/132 , B01J23/26 , B01J27/138 , Y10S423/12
摘要： A novel cerous chloride-chromium oxide catalyst useful for oxidizing hydrogen chloride to chlorine. The catalyst is prepared by the reaction of chromium trioxide and cerous chloride with ethanol and calcining the reaction product. The catalyst is also prepared by the reaction of chromium trioxide with ethanol, then calcination and impregnation of the resultant chromic oxide with aqueous solution of cerous chloride. The obtained catalyst exhibits high activity at low reaction temperature.
摘要翻译：一种用于将氯化氢氧化成氯的新型氯化铈 - 氧化铬催化剂。催化剂通过三氧化铬和氯化铈与乙醇的反应制备，并煅烧反应产物。催化剂也可以通过三氧化铬与乙醇的反应制备，然后用氯化铈水溶液煅烧和浸渍所得到的氧化铬。所得催化剂在低反应温度下表现出高活性。

6. 发明授权

US5841007A Process for manufacturing 1,1,1,2-tetrafluoroethane 失效
标题翻译：制备1,1,1,2-四氟乙烷的方法
公开(公告)号：US5841007A
公开(公告)日：1998-11-24
申请号：US630678
申请日：1996-04-12
申请人： Byoung Sung Ahn , Young Soo Kwon , Kun You Park , Moon Jo Chung
发明人： Byoung Sung Ahn , Young Soo Kwon , Kun You Park , Moon Jo Chung
IPC分类号： C07C17/20 , C07C17/21 , C07C19/08 , C07C17/00
CPC分类号： C07C19/08 , C07C17/206 , C07C17/21
摘要： The present invention relates to a process for manufacturing 1,1,1,2-tetrafluoroethane (HFC-134a) from trichloroethylene (TCE) and hydrogen fluoride (HF) by reacting the HCFC-133a with the HF to produce the HFC-134a and reacting the TCE with the HF to produce 1-choro-2,2,2-trifluoroethane (HCFC-133a), characterized by that a part of said HF is mixed with the mixture containing the HFC-134a and the remaining portion of said HF is fed with said TCE in portions to at least two sections of a reactor for producing said HCFC-133a. According the present process, the temperature change in the reactor for producing HCFC-133a is maintained within a narrow range over the whole reaction procedures, and the catalytic activity is well maintained. Further, the formation of by-products is considerably prevented and thus the productivity is remarkably enhanced.
摘要翻译：本发明涉及通过使HCFC-133a与HF反应生成HFC-134a，从三氯乙烯（TCE）和氟化氢（HF）制备1,1,1,2-四氟乙烷（HFC-134a）使TCE与HF反应以产生1-氯-2,2,2-三氟乙烷（HCFC-133a），其特征在于，将所述HF的一部分与含有HFC-134a和所述HF的剩余部分的混合物混合与所述TCE一起供给至用于生产所述HCFC-133a的反应器的至少两个部分。根据本方法，生产HCFC-133a的反应器中的温度变化在整个反应过程中保持在窄范围内，并且催化活性得到很好的维持。此外，可以显着地防止副产物的形成，从而显着提高生产率。

7. 发明授权

US6075167A Method for preparing cycloaliphatic diamines from aromatic diamines 有权
标题翻译：从芳族二胺制备脂环族二胺的方法
公开(公告)号：US6075167A
公开(公告)日：2000-06-13
申请号：US160821
申请日：1998-09-25
申请人： Hoon Sik Kim , Kun Yu Park , Young Soo Kwon , Moon Jo Chung , Byung Gwon Lee
发明人： Hoon Sik Kim , Kun Yu Park , Young Soo Kwon , Moon Jo Chung , Byung Gwon Lee
IPC分类号： C07C211/18 , C07C209/72 , C07C211/36 , C07C209/00
CPC分类号： C07C209/72
摘要： This invention relates to a method for preparing cycloaliphatic diamines by hydrogenating aromatic diamines in the presence of a supported ruthenium catalyst and a metal nitrite as a catalyst promoter to increase the rate of the hydrogenation reaction and decrease the amount of higher boiler by-products.
摘要翻译：本发明涉及一种通过在负载型钌催化剂和亚硝酸金属作为催化剂促进剂的存在下将芳族二胺加氢来制备脂环族二胺的方法，以提高氢化反应速率并减少较高的锅炉副产物的量。

8. 发明授权

US5959166A Method for concurrently producing different hydrofluoro carbons 失效
标题翻译：同时生产不同氢氟碳的方法
公开(公告)号：US5959166A
公开(公告)日：1999-09-28
申请号：US966093
申请日：1997-11-07
申请人： Hoon Sik Kim , Moon Jo Chung , Kun You Park , Young Soo Kwon
发明人： Hoon Sik Kim , Moon Jo Chung , Kun You Park , Young Soo Kwon
IPC分类号： B01J23/26 , B01J27/125 , B01J27/132 , B01J27/138 , C07B61/00 , C07C17/20 , C07C17/21 , C07C19/08 , C07C19/10 , C07C17/08
CPC分类号： C07C17/206 , C07C17/21 , Y02P20/582
摘要： A method for concurrently producing different hydrofluoro carbons, comprising the reaction of halocarbon or hydrohalocarbon with hydrogen fluoride in a reaction system consisting of a series of at least two discrete reactors, in the presence of catalysts, said reactors each being provided with different reactant materials and differing in reaction conditions including the catalysts and/or reaction temperature, thereby flexibly controlling their production rates in accordance with fluctuations in their demand, and eliminating the risk of constructing large scale plants responsible for individual hydrofluorocarbons.
摘要翻译：一种同时生产不同氢氟碳的方法，包括在由一系列至少两个不连续的反应器组成的反应体系中，在催化剂存在下，卤代烃或氢卤化碳与氟化氢的反应，所述反应器各自具有不同的反应物料和包括催化剂和/或反应温度在内的反应条件不同，从而根据其需求的波动灵活地控制其生产率，并消除构建负责单个氢氟碳化物的大型设备的风险。

9. 发明授权

US5659094A Process for co-producing 1,1,1,2-tetrafluoroethane pentafluoroethane and 1,1,1-trifluoroethane 失效
标题翻译：共1,1,1,2-四氟乙烷五氟乙烷和1,1,1-三氟乙烷共生产方法
公开(公告)号：US5659094A
公开(公告)日：1997-08-19
申请号：US591705
申请日：1996-01-25
申请人： Hoon Sik Kim , Byung Gwon Lee , Honggon Kim , Moon Jo Chung
发明人： Hoon Sik Kim , Byung Gwon Lee , Honggon Kim , Moon Jo Chung
IPC分类号： B01J23/26 , B01J27/12 , B01J27/132 , B01J27/138 , C07B61/00 , C07C17/20 , C07C17/21 , C07C17/23 , C07C19/08
CPC分类号： C07C17/21 , B01J27/132 , B01J27/138 , C07C17/206 , C07C17/23
摘要： A process for co-production of 1,1,1,2-tetrafluoroethane (HFC-134a;CF.sub.3 CH.sub.2 F), pentafluoroethane (HFC-125; CF.sub.3 CHF.sub.2) and 1,1,1 -trifluoroethane (HFC-143a; CF.sub.3 CH.sub.3) by a two-step gaseous reaction comprising the steps of a) reacting 1,1,1-trifluoro-2-chloroethane (CFCH.sub.2 Cl, HCFC-133a) with HF in a first reactor to prepare 1,1,1,2-tetrafluoroethane (HFC-134a; CF.sub.3 CH.sub.2 F), pentafluoroethane (HFC-125; CF.sub.3 CHF.sub.2) and 1,1,1-trifluoroethane (HFC-143a; CF.sub.3 CH.sub.3); b) adding trichloroethylene (TCE:CCl.sub.2 CHCl) to the reaction product of step a) in a second reactor to prepare HCFC-133a; separating HCl, HFC-134a, HFC-125 and HFC-143a from the reaction product of step b) and recycling HCFC-133a to the first reactor, and the stages being performed in the presence of fluorization catalyst obtained by calcining a reaction product which is obtained by reacting ethanol with a mixture of calcium fluoride(CaF.sub.2) with an aqueous solution of chromium trioxide, zinc chloride and ferrous chloride is provided.
摘要翻译：一种通过两个共同生产1,1,1,2-四氟乙烷（HFC-134a; CF3CH2F），五氟乙烷（HFC-125; CF3CHF2）和1,1,1-三氟乙烷（HFC-143a; CF3CH3）的方法包括以下步骤：a）在第一反应器中使1,1,1-三氟-2-氯乙烷（CFCH2Cl，HCFC-133a）与HF反应制备1,1,1,2-四氟乙烷（HFC-134a ; CF 3 CH 2 F），五氟乙烷（HFC-125; CF 3 CHF 2）和1,1,1-三氟乙烷（HFC-143a; CF 3 CH 3）; b）在第二反应器中将三氯乙烯（TCE：CCl 2 CHCl）加入到步骤a）的反应产物中以制备HCFC-133a; 从步骤b）的反应产物中分离出HCl，HFC-134a，HFC-125和HFC-143a，并将HCFC-133a再循环到第一反应器中，这些阶段在通过煅烧反应产物得到的氟化催化剂存在下进行，通过乙醇与氟化钙（CaF 2）与三氧化铬的水溶液，氯化锌和氯化亚铁的混合物反应获得。

10. 发明授权

US5571770A Catalyst for fluorination of 1,1,1,-trifluoro-2,2-dichloroethane and method for preparing the same 失效
标题翻译：用于氟化1,1,1-三氟-2,2-二氯乙烷的催化剂及其制备方法
公开(公告)号：US5571770A
公开(公告)日：1996-11-05
申请号：US490726
申请日：1995-06-15
申请人： Hoon Sik Kim , Moon Jo Chung , Byung Gwon Lee , Hyun Joo Lee
发明人： Hoon Sik Kim , Moon Jo Chung , Byung Gwon Lee , Hyun Joo Lee
IPC分类号： B01J27/138 , B01J23/26 , B01J23/86 , C07B61/00 , C07C17/20 , C07C19/08 , C07C19/12
CPC分类号： B01J23/26 , B01J23/866 , C07C17/206
摘要： There are a catalyst for fluorination production of 1,1,1-trifluoro-2,2-dichloroethane comprises chromium, one compound selected from the group consisting of Mg and Ca and at least one metal component selected from the group consisting of Zn, Ce and Ni, wherein the molar ratio of Cr to Mg or Ca ranges from 1:1 to 1:32 and the molar ratio Cr to the metal component is not more than 1:0.5, and method for preparing the same comprising the steps of; producing an admixture of a composition comprising chromium, one compound selected from the group consisting of magnesium fluoride and calcium fluoride and at least one metal compound selected from a group consisting of cerium fluoride, zinc fluoride and nickel fluoride with water and refluxing the admixture in methanol or ethanol.
摘要翻译：具有1,1,1-三氟-2,2-二氯乙烷的氟化生产催化剂包括铬，一种选自Mg和Ca的化合物和至少一种选自Zn，Ce 和Ni，其中Cr与Mg或Ca的摩尔比范围为1：1至1:32，并且金属组分的摩尔比Cr不大于1:0.5，及其制备方法包括以下步骤：制备包含铬的组合物的混合物，一种选自氟化镁和氟化钙的化合物和至少一种选自氟化铈，氟化锌和氟化镍的金属化合物与水并将该混合物在甲醇中回流或乙醇。

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