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    • 1. 发明授权
    • Silver halide light-sensitive element
    • 卤化银感光元件
    • US5683860A
    • 1997-11-04
    • US768544
    • 1996-12-18
    • Donald R. DiehlLinda J. BeattieGary N. Barber
    • Donald R. DiehlLinda J. BeattieGary N. Barber
    • G03C1/83G03C7/30G03C1/40
    • G03C1/83G03C7/3041G03C7/3029
    • A silver halide light sensitive photographic element comprising a support bearing on one side thereof at least one light-sensitive silver halide emulsion layer, wherein the emulsion layer or a separate hydrophilic colloid layer of the element comprises a soluble absorber dye of the following formula (I): ##STR1## wherein each M is H or a counterion; each R.sup.1 and R.sup.2 independently represents H or a photographically acceptable substituent; m+p equals from 1 to 4; n+q equals from 1 to 4; and each of r and t represents from 0 to 3. In preferred embodiments of the invention, the element comprises at least one red-sensitive silver halide emulsion layer, and a dye of formula (I) is coated on the same side of the support as the red-sensitive emulsion layer. In particularly preferred embodiments, the element comprises a support bearing on the same side at least one blue-sensitive silver halide emulsion yellow-image forming layer, at least one red-sensitive silver halide emulsion cyan-image forming layer, at least one green-sensitive silver halide emulsion magenta-image forming layer, and a dye of the formula (I) is coated in at least one of the emulsion layers or a separate hydrophilic colloid layer on the same side of the support. Dyes of formula (I) typically provide substantial absorption at short red wavelengths below about 630 nm, and photographic elements in accordance with the invention accordingly exhibit effective safelight performance for commonly used safelights emitting in the range of 560-630 nm, such as those using a Kodak Safelight Filter No. 8.
    • 一种卤化银感光照相材料,其包含一个支承体,该支撑体的一侧具有至少一个感光卤化银乳剂层,其中所述乳液层或所述元件的分开的亲水胶体层包含下式(I ):其中每个M是H或抗衡离子; 每个R 1和R 2独立地表示H或照相可接受的取代基; m + p等于1至4; n + q等于1至4; 并且r和t中的每一个表示0至3.在本发明的优选实施方案中,元件包含至少一种感红卤化银乳剂层,并且将式(I)染料涂覆在载体的同一侧 作为感红乳剂层。 在特别优选的实施方案中,元件包括在同一侧上承载至少一种感蓝卤化银乳剂黄色图像形成层,至少一种感红卤化银乳剂青色图像形成层,至少一种绿 - 敏感的卤化银乳剂品红色图像形成层和式(I)的染料涂覆在载体的同一侧的至少一个乳剂层或单独的亲水胶体层中。 式(I)的染料通常在低于约630nm的短红色波长下提供实质吸收,因此根据本发明的照相元件相应地显示出在560-630nm范围内发射的常用安全灯的有效安全性能,例如使用 Kodak Safelight过滤器8号。
    • 5. 发明授权
    • Solid particle dispersions of filter dyes for photographic elements
    • 用于照相元件的滤光染料的固体颗粒分散体
    • US5470695A
    • 1995-11-28
    • US289993
    • 1994-08-12
    • Donald R. DiehlGlenn M. Brown
    • Donald R. DiehlGlenn M. Brown
    • C09B23/01C09B23/04C09K3/00G03C1/83G03C1/06G03C1/815G03C1/825
    • G03C1/832C09B23/0058C09B23/0091C09B23/04
    • Solid particle dispersions of dyes according to the formula: ##STR1## wherein D is selected from the group consisting of ##STR2## are disclosed as filter dyes for photographic elements. In this formula, R.sup.1, R.sup.2, and R.sup.3 are each independently hydrogen, substituted or unsubstituted alkyl, or substituted or unsubstituted alkoxy. At least one of R.sup.1, R.sup.2 and R.sup.3 is substituted or unsubstituted alkoxy, or two of R.sup.1, R.sup.2 and R.sup.3 together consist of --O--L--O-- and form a ring condensed with the phenyl ring to which they are attached wherein L is an alkylene linking group. R.sup.4, R.sup.5, R.sup.6, and R.sup.7 are each independently hydrogen, substituted or unsubstituted alkyl, or substituted or unsubstituted aryl. R is a carboxy or sulfonamido substituent, and L.sup.1, L.sup.2 and L.sup.3 are each independently substituted or unsubstituted methine groups. The dyes of the invention are particularly useful as filter dyes for light in the ultraviolet and short blue wavelength regions of the spectrum.
    • 公开了根据下式的染料的固体颗粒分散体:其中D选自 作为照相元件的滤光染料。 在该式中,R 1,R 2和R 3各自独立地为氢,取代或未取代的烷基或取代或未取代的烷氧基。 R 1,R 2和R 3中的至少一个是取代或未取代的烷氧基,或者R 1,R 2和R 3中的两个由-OLO-组成,并形成与它们所连接的苯环稠合的环,其中L是亚烷基连接基团 。 R 4,R 5,R 6和R 7各自独立地为氢,取代或未取代的烷基或取代或未取代的芳基。 R是羧基或磺酰氨基取代基,L1,L2和L3各自独立地是取代或未取代的次甲基。 本发明的染料特别可用作用于光谱的紫外和短蓝色波长区域中的光的滤光染料。
    • 7. 发明授权
    • Filter dyes for photographic elements
    • 用于照相元件的滤色染料
    • US5399690A
    • 1995-03-21
    • US15775
    • 1993-02-10
    • Donald R. DiehlGlenn M. BrownMargaret J. Helber
    • Donald R. DiehlGlenn M. BrownMargaret J. Helber
    • C09B23/01C09B23/14G03C1/83C09B23/02C09B23/04C09B23/06
    • G03C1/832C09B23/0008C09B23/0066C09B23/0091C09B23/14
    • Solid particle dispersions of dyes according to the formula: ##STR1## wherein D is selected from the group consisting of ##STR2## and ketomethylene nuclei are disclosed as filter dyes for photographic elements.In this formula, E.sup.1 and E.sup.2 are each independently electron withdrawing groups. R.sup.1 and R.sup.6 are each independently R or NHR, where R is aryl. R.sup.2 and R.sup.3 are each independently alkyl or aryl, or represent the carbon atoms necessary to form a fused ring with the phenyl ring to which the N atom is attached. R.sup.4 and R.sup.7 are each independently hydrogen, alkyl or aryl. R.sup.5 is alkyl. Z represents the atoms necessary to complete a 5 or 6 memebered heterocyclic nucleus. M.sup.+ is a cation. L.sup.1 through L.sup.7 are each independently methine groups. m is 0, 1, 2, or 3. n is 0 or 1. p is 0, 1, 2, 3, or 4. q is 0, 1, 2, or 3. At least one of R.sup.1 or D includes an aryl ring substituted with a carboxy or sulfonamido substituent.
    • 公开了根据下式的染料的固体颗粒分散体:其中D选自由下列组成的组:IMA图像和酮亚甲基核,作为照相元件的滤光染料。 在该式中,E1和E2各自独立地是吸电子基团。 R 1和R 6各自独立地为R或NHR,其中R为芳基。 R2和R3各自独立地为烷基或芳基,或代表与N原子连接的苯环形成稠环所必需的碳原子。 R4和R7各自独立地为氢,烷基或芳基。 R5是烷基。 Z表示完成5或6个杂芳核所必需的原子。 M +是阳离子。 L1至L7各自独立为次甲基。 m为0,1,2或3.n为0或1.p为0,1,2,3或4.q为0,1,2或3.R 1或D中的至少一个包括 被羧基或磺酰氨基取代基取代的芳环。
    • 8. 发明授权
    • Pyrrolinone dyes
    • 吡咯啉酮染料
    • US5283165A
    • 1994-02-01
    • US995436
    • 1992-12-23
    • Donald R. DiehlMargaret J. HelberLouis J. Rossi
    • Donald R. DiehlMargaret J. HelberLouis J. Rossi
    • C09B23/00C09B23/01C09B23/02C09B57/00G03C1/83G03C1/84
    • G03C1/832C09B23/0066C09B23/0091C09B23/02
    • Pyrrolinone dyes, and photographic materials containing them, which dyes have the formula: ##STR1## wherein; E.sup.1 represents an electron withdrawing group;R.sup.1 represents an aryl group of 6 to 14 carbon atoms or an alkyl group of from 1 to 12 carbon atoms;R.sup.2 represents an alkyl or alkylthio group of 1 to 20 carbon atoms, or an alkenyl group of 2 to 20 carbon atoms, or an aryl, aralkyl, heterocyclic or cycloalkyl group any of which have 5 to 14 carbon atoms, or R2 represents a hydroxy, cyano, chloro, nitro or hydrogen;M.sup.+ is a cation;each L represents a methine group;m is 0, 1, 2, or 3; and D is a moiety in conjugation with the oxygen of the pyrollinone ring.The dyes are particularly useful as solid particle filter dye dispersions in photographic elements.
    • 吡咯啉酮染料和含有它们的照相材料,该染料具有下式:其中: E1表示吸电子基团; R1表示6〜14个碳原子的芳基或1〜12个碳原子的烷基; R 2表示碳原子数为1〜20的烷基或烷硫基,或碳原子数2〜20的烯基,或者具有5〜14个碳原子的芳基,芳烷基,杂环或环烷基,或者R 2表示羟基 ,氰基,氯,硝基或氢; M +是阳离子; 每个L代表次甲基; m为0,1,2或3; 而D是与吡罗环酮环的氧共轭的部分。 这些染料特别可用作照相元件中的固体颗粒过滤染料分散体。