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    • 3. 发明授权
    • Catalytic alkylation of hydrocarbons
    • 碳氢化合物的催化烷基化
    • US4317795A
    • 1982-03-02
    • US124994
    • 1980-02-26
    • Donald J. MakovecDonald M. Haskell
    • Donald J. MakovecDonald M. Haskell
    • B01J19/00C07C2/54C07C2/62G01N21/00G05D7/00
    • B01J19/0006C07C2/54C07C2/62C07C2527/1206Y02P20/584
    • A continuous process for the alkylation of an alkylatable hydrocarbon with an alkylating agent in the presence of an acid-type catalyst, including; contacting an alkylatable hydrocarbon with an alkylating agent in the presence of an acid-type catalyst at a temperature and pressure and for a time sufficient to alkylate the alkylatable hydrocarbon; separating the reaction effluent stream into an alkylate product phase and a catalyst phase containing catalyst-soluble oil; cooling the catalyst phase to a temperature essentially equal to the alkylation reaction temperature; recycling the cooled catalyst phase to the alkylation reaction; contacting a diolefinic hydrocarbon with an acid-type catalyst at a temperature and pressure sufficient to form additional catalyst-soluble oil and combining the additional catalyst-soluble oil with the circulating catalyst phase. In accordance with another aspect of the invention, a quantity selected from the amount of catalyst-soluble oil, water and/or the total of the amount of catalyst-soluble oil and water in the catalyst phase is controlled, within specific limits. A start-up procedure and apparatus for carrying out the process are also included.
    • 一种在酸型催化剂存在下用烷基化剂烷基化可烷基化烃的连续方法,包括: 在酸式催化剂的存在下,在可压制烷基化烃的温度和压力下使可烷基化烃与烷基化剂接触,并持续足够的时间烷基化; 将反应流出物流分离成烷基化物产物相和含有催化剂可溶性油的催化剂相; 将催化剂相冷却至基本等于烷基化反应温度的温度; 将冷却的催化剂相再循环至烷基化反应; 在足以形成额外的催化剂可溶性油并将另外的催化剂可溶性油与循环催化剂相组合的温度和压力下使二烯烃与酸型催化剂接触。 根据本发明的另一方面,在特定限度内控制选自催化剂可溶性油,水的量和/或催化剂相中催化剂可溶性油和水的总量的量。 还包括用于执行该过程的启动程序和装置。
    • 4. 发明授权
    • Acid type hydrocarbon alkylation with acid-soluble oil addition
    • 酸型烃烷基化与酸溶性油添加
    • US4207423A
    • 1980-06-10
    • US27425
    • 1979-04-05
    • Donald J. MakovecDonald M. Haskell
    • Donald J. MakovecDonald M. Haskell
    • B01J19/00C07C2/54C07C2/62C07C3/54
    • B01J19/0006C07C2/54C07C2/62C07C2527/1206Y02P20/584Y10T436/12
    • A continuous process for the alkylation of an alkylatable hydrocarbon with an alkylating agent in the presence of an acid-type catalyst, including; contacting an alkylatable hydrocarbon with an alkylating agent in the presence of an acid-type catalyst at a temperature and pressure and for a time sufficient to alkylate the alkylatable hydrocarbon; separating the reaction effluent stream into an alkylate product phase and a catalyst phase containing catalyst-soluble oil; cooling the catalyst phase to a temperature essentially equal to the alkylation reaction temperature; recycling the cooled catalyst phase to the alkylation reaction; contacting a diolefinic hydrocabon with an acid-type catalyst at a temperature and pressure sufficient to form additional catalyst-soluble oil and combining the additional catalyst-soluble oil with the circulating catalyst phase. In accordance with another aspect of the invention, a quantity selected from the amount of catalyst-soluble oil, water and/or the total of the amount of catalyst-soluble oil and water in the catalyst phase is controlled, within specific limits. A start-up procedure and apparatus for carrying out the process are also included.
    • 一种在酸型催化剂存在下用烷基化剂烷基化可烷基化烃的连续方法,包括: 在酸式催化剂的存在下,在可压制烷基化烃的温度和压力下使可烷基化烃与烷基化剂接触,并持续足够的时间烷基化; 将反应流出物流分离成烷基化物产物相和含有催化剂可溶性油的催化剂相; 将催化剂相冷却至基本等于烷基化反应温度的温度; 将冷却的催化剂相再循环至烷基化反应; 在足以形成额外的催化剂可溶性油并将另外的催化剂可溶性油与循环催化剂相组合的温度和压力下使二烯烃与酸式催化剂接触。 根据本发明的另一方面,在特定限度内控制选自催化剂可溶性油,水的量和/或催化剂相中催化剂可溶性油和水的总量的量。 还包括用于执行该过程的启动程序和装置。