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1. 发明授权

US4276439A Catalytic alkylation method and apparatus with hydrocarbon recycle 失效
标题翻译：催化烷基化方法和装置与烃循环
公开(公告)号：US4276439A
公开(公告)日：1981-06-30
申请号：US81290
申请日：1979-10-02
申请人： Thomas Hutson, Jr. , Donald J. Makovec , Alden E. Beckworth
发明人： Thomas Hutson, Jr. , Donald J. Makovec , Alden E. Beckworth
IPC分类号： C07C2/54 , C07C2/62 , C07C3/54
CPC分类号： C07C2/54 , C07C2/62
摘要： A process and apparatus for the catalytic alkylation of an isoparaffin with one or more olefins. Reactant hydrocarbons are passed in contact with a liquid catalyst such as hydrofluoric acid in a reaction zone. The hydrocarbon phase is allowed to separate from the catalyst phase in a settling zone, and a portion of the hydrocarbon phase is cooled and reintroduced to the reaction zone in a separate stream from that of the feed hydrocarbons. The alkylation apparatus by which the process is carried out includes a vertical reaction vessel, which in a preferred embodiment is 2 to 6 feet in height, a settling vessel, means for fluid flow from the reaction vessel to the settling vessel, a conduit for fluid flow between the upper part of the settling vessel and the reaction zone, and means for cooling fluid in this conduit.
摘要翻译：一种用一种或多种烯烃催化烷基化异链烷烃的方法和装置。反应性烃在反应区中与液体催化剂如氢氟酸接触。允许烃相在沉降区中与催化剂相分离，并且一部分烃相被冷却并以与进料烃的流分开的流重新引入反应区。进行该方法的烷基化装置包括在优选实施方案中为高度为2至6英尺的垂直反应容器，沉降容器，用于从反应容器流向沉降容器的流体的装置，用于流体的导管在沉降容器的上部和反应区之间的流动，以及用于在该导管中冷却流体的装置。

2. 发明授权

US4179475A Olefin feed in HF alkylation of isoparaffin with olefin 失效
标题翻译：异烯烃与烯烃的HF烷基化中的烯烃进料
公开(公告)号：US4179475A
公开(公告)日：1979-12-18
申请号：US905073
申请日：1978-05-11
申请人： Donald J. Makovec , Donald M. Haskell
发明人： Donald J. Makovec , Donald M. Haskell
IPC分类号： C07C2/62 , C07C3/54
CPC分类号： C07C2/62 , C07C2527/1206
摘要： In a conventional reactor into which at one end portion there are fed olefin, isoparaffin and HF acid, or other catalysts, and from which an alkylate containing product is passed to a phase separator or settling zone, there is added to the reactor to a downstream portion therein, beyond the original point of entry of the first olefin feed a second portion of olefin feed together with hydrocarbon phase recycled from the phase separator or settling zone.
摘要翻译：在一个常规的反应器中，一端加入烯烃，异链烷烃和HF酸或其它催化剂，并将含烷基化物的产物从其中通入相分离器或沉降区，将反应器加入到下游超过第一烯烃进料的原始进入点，第二部分烯烃进料与从相分离器或沉降区循环的烃相一起。

3. 发明授权

US4317795A Catalytic alkylation of hydrocarbons 失效
标题翻译：碳氢化合物的催化烷基化
公开(公告)号：US4317795A
公开(公告)日：1982-03-02
申请号：US124994
申请日：1980-02-26
申请人： Donald J. Makovec , Donald M. Haskell
发明人： Donald J. Makovec , Donald M. Haskell
IPC分类号： B01J19/00 , C07C2/54 , C07C2/62 , G01N21/00 , G05D7/00
CPC分类号： B01J19/0006 , C07C2/54 , C07C2/62 , C07C2527/1206 , Y02P20/584
摘要： A continuous process for the alkylation of an alkylatable hydrocarbon with an alkylating agent in the presence of an acid-type catalyst, including; contacting an alkylatable hydrocarbon with an alkylating agent in the presence of an acid-type catalyst at a temperature and pressure and for a time sufficient to alkylate the alkylatable hydrocarbon; separating the reaction effluent stream into an alkylate product phase and a catalyst phase containing catalyst-soluble oil; cooling the catalyst phase to a temperature essentially equal to the alkylation reaction temperature; recycling the cooled catalyst phase to the alkylation reaction; contacting a diolefinic hydrocarbon with an acid-type catalyst at a temperature and pressure sufficient to form additional catalyst-soluble oil and combining the additional catalyst-soluble oil with the circulating catalyst phase. In accordance with another aspect of the invention, a quantity selected from the amount of catalyst-soluble oil, water and/or the total of the amount of catalyst-soluble oil and water in the catalyst phase is controlled, within specific limits. A start-up procedure and apparatus for carrying out the process are also included.
摘要翻译：一种在酸型催化剂存在下用烷基化剂烷基化可烷基化烃的连续方法，包括：在酸式催化剂的存在下，在可压制烷基化烃的温度和压力下使可烷基化烃与烷基化剂接触，并持续足够的时间烷基化; 将反应流出物流分离成烷基化物产物相和含有催化剂可溶性油的催化剂相; 将催化剂相冷却至基本等于烷基化反应温度的温度; 将冷却的催化剂相再循环至烷基化反应; 在足以形成额外的催化剂可溶性油并将另外的催化剂可溶性油与循环催化剂相组合的温度和压力下使二烯烃与酸型催化剂接触。根据本发明的另一方面，在特定限度内控制选自催化剂可溶性油，水的量和/或催化剂相中催化剂可溶性油和水的总量的量。还包括用于执行该过程的启动程序和装置。

4. 发明授权

US4207423A Acid type hydrocarbon alkylation with acid-soluble oil addition 失效
标题翻译：酸型烃烷基化与酸溶性油添加
公开(公告)号：US4207423A
公开(公告)日：1980-06-10
申请号：US27425
申请日：1979-04-05
申请人： Donald J. Makovec , Donald M. Haskell
发明人： Donald J. Makovec , Donald M. Haskell
IPC分类号： B01J19/00 , C07C2/54 , C07C2/62 , C07C3/54
CPC分类号： B01J19/0006 , C07C2/54 , C07C2/62 , C07C2527/1206 , Y02P20/584 , Y10T436/12
摘要： A continuous process for the alkylation of an alkylatable hydrocarbon with an alkylating agent in the presence of an acid-type catalyst, including; contacting an alkylatable hydrocarbon with an alkylating agent in the presence of an acid-type catalyst at a temperature and pressure and for a time sufficient to alkylate the alkylatable hydrocarbon; separating the reaction effluent stream into an alkylate product phase and a catalyst phase containing catalyst-soluble oil; cooling the catalyst phase to a temperature essentially equal to the alkylation reaction temperature; recycling the cooled catalyst phase to the alkylation reaction; contacting a diolefinic hydrocabon with an acid-type catalyst at a temperature and pressure sufficient to form additional catalyst-soluble oil and combining the additional catalyst-soluble oil with the circulating catalyst phase. In accordance with another aspect of the invention, a quantity selected from the amount of catalyst-soluble oil, water and/or the total of the amount of catalyst-soluble oil and water in the catalyst phase is controlled, within specific limits. A start-up procedure and apparatus for carrying out the process are also included.
摘要翻译：一种在酸型催化剂存在下用烷基化剂烷基化可烷基化烃的连续方法，包括：在酸式催化剂的存在下，在可压制烷基化烃的温度和压力下使可烷基化烃与烷基化剂接触，并持续足够的时间烷基化; 将反应流出物流分离成烷基化物产物相和含有催化剂可溶性油的催化剂相; 将催化剂相冷却至基本等于烷基化反应温度的温度; 将冷却的催化剂相再循环至烷基化反应; 在足以形成额外的催化剂可溶性油并将另外的催化剂可溶性油与循环催化剂相组合的温度和压力下使二烯烃与酸式催化剂接触。根据本发明的另一方面，在特定限度内控制选自催化剂可溶性油，水的量和/或催化剂相中催化剂可溶性油和水的总量的量。还包括用于执行该过程的启动程序和装置。

5. 发明授权

US4383977A Catalytic alkylation apparatus with hydrocarbon recycle 失效
标题翻译：具有烃循环的催化烷基化装置
公开(公告)号：US4383977A
公开(公告)日：1983-05-17
申请号：US235484
申请日：1981-02-18
申请人： Thomas Hutson, Jr. , Donald J. Makovec , Alden E. Beckworth
发明人： Thomas Hutson, Jr. , Donald J. Makovec , Alden E. Beckworth
IPC分类号： C07C2/54 , C07C2/62 , F28D7/00
CPC分类号： C07C2/62 , C07C2/54
摘要： A apparatus for the catalytic alkylation of an isoparaffin with one or more olefins. Reactant hydrocarbons are passed in contact with a liquid catalyst such as hydrofluoric acid in a reaction zone. The hydrocarbon phase is allowed to separate from the catalyst phase in a settling zone, and a portion of the hydrocarbon phase is cooled and reintroduced to the reaction zone in a separate stream from that of the feed hydrocarbons. The alkylation apparatus by which the process is carried out includes a vertical reaction vessel, which in a preferred embodiment is 2 to 6 feet in height, a settling vessel, means for fluid flow from the reaction vessel to the settling vessel, a conduit for fluid flow between the upper part of the settling vessel and the reaction zone, and means for cooling fluid in this conduit.
摘要翻译：一种用一种或多种烯烃催化烷基化异链烷烃的装置。反应性烃在反应区中与液体催化剂如氢氟酸接触。允许烃相在沉降区中与催化剂相分离，并且一部分烃相被冷却并以与进料烃的流分开的流重新引入反应区。进行该方法的烷基化装置包括在优选实施方案中为高度为2至6英尺的垂直反应容器，沉降容器，用于从反应容器流向沉降容器的流体的装置，用于流体的导管在沉降容器的上部和反应区之间的流动，以及用于在该导管中冷却流体的装置。

6. 发明授权

US4320233A Dialkyl ether production 失效
标题翻译：二烷基醚生产
公开(公告)号：US4320233A
公开(公告)日：1982-03-16
申请号：US232791
申请日：1981-02-09
申请人： Donald J. Makovec , Paul D. Hann
发明人： Donald J. Makovec , Paul D. Hann
IPC分类号： C07C41/05 , C07C2/60
CPC分类号： C07C41/06
摘要： Dialkyl ether is produced by passing isoolefin, alkanol and diluent through a series of catalyst zones, cooling the effluent between zones and adding isoolefin and/or alkanol between zones.
摘要翻译：二烷基醚通过使异烯烃，链烷醇和稀释剂通过一系列催化剂区域，冷却区域之间的流出物并在区域之间加入异烯烃和/或链烷醇来制备。

7. 发明授权

US4205196A Acid-type hydrocarbon alkylation with acid recycle streams at spaced points of a vertically-disposed elongated reactor 失效
标题翻译：在垂直设置的细长反应器的间隔点处用酸循环物流进行酸式烃烷基化
公开(公告)号：US4205196A
公开(公告)日：1980-05-27
申请号：US27426
申请日：1979-04-05
申请人： Donald J. Makovec , Donald M. Haskell
发明人： Donald J. Makovec , Donald M. Haskell
IPC分类号： C07C2/54 , C07C2/58 , C07C3/54 , B01J8/00 , G01N25/00
CPC分类号： C07C2/54 , C07C2/58 , Y02P20/584 , Y10S585/911 , Y10S585/926 , Y10T436/12
摘要： A method of alkylating an alkylatable hydrocarbon with different alkylating agents, at different reaction temperatures and in a single reaction zone, in which an alkylatable hydrocarbon is contacted with an acid-type catalyst and at different points in an elongated reaction zone, the reaction zone effluent is separated into a hydrocarbon phase and a catalyst recycle phase and the reaction temperatures of the various alkylating agents are maintained at different temperatures by splitting the recycle catalyst phase into an equal number of streams and adjusting the reaction temperatures by adjusting the temperatures of the recycle catalyst phase streams, the relative proportions of the recycle catalyst phase streams or both. A method of starting-up the process and apparatus for conducting the process are also disclosed.
摘要翻译：在不同的反应温度下和在单一反应区域中使烷基化烃与不同烷基化剂烷基化的方法，其中可烷基化的烃与酸型催化剂接触，并且在细长的反应区中的不同点，反应区流出物被分离成烃相和催化剂循环相，并且各种烷基化剂的反应温度通过将再循环催化剂相分成相等数量的流并通过调节循环催化剂的温度来调节反应温度而保持在不同的温度相流，循环催化剂相流或两者的相对比例。还公开了启动该过程的方法和进行该方法的装置。

8. 发明授权

US4214115A Alkylation process utilizing plural olefinic reactants 失效
标题翻译：使用多种烯属反应物的烷基化方法
公开(公告)号：US4214115A
公开(公告)日：1980-07-22
申请号：US904149
申请日：1978-05-09
申请人： Donald J. Makovec , Thomas Hutson, Jr.
发明人： Donald J. Makovec , Thomas Hutson, Jr.
IPC分类号： C07C2/62 , C07C3/54
CPC分类号： C07C2/62 , C07C2527/1206 , Y02P20/584
摘要： A cyclic system for the alkylation of an isoparaffin, e.g., isobutane, wherein a first olefinic reactant, e.g., butylene, is used to alkylate the isoparaffin for a first period of time in an alkylation reactor and then a second olefinic reactant, e.g., propylene, is used to alkylate the isoparaffin for a second period of time in the same alkylation reactor. During the period that the isoparaffin is alkylated with the first olefinic reactant, the reactor effluent stream is continuously separated into a liquid hydrocarbon phase comprising alkylation products and unreacted isoparaffin and a liquid acid alkylation catalyst phase. The acid catalyst is continuously recycled to the reactor and the hydrocarbon phase is passed to a first surge zone or holding tank. During the second period of time, the isoparaffin-rich hydrocarbon phase from the first surge zone and the second olefinic reactant, along with continuously recycled catalyst, are charged to the same alkylation reactor so that, preferably, feed to the reactor is continuously effected. The reactor effluent is continuously separated into a liquid hydrocarbon phase containing unreacted isoparaffin and a liquid catalyst phase. The hydrocarbon phase is charged in part to fractionation and in part to a second surge zone. During the first period of time, hydrocarbon from the second surge zone is charged to this fractionation so the fractionation is continuously in operation. Isoparaffin is continuously removed from the fractionation to a third surge zone. Isoparaffin can be charged from the third surge zone to the alkylation reactor.
摘要翻译：用于烷基化异链烷烃（例如异丁烷）的环状体系，其中第一烯烃反应物（例如丁烯）用于在烷基化反应器中将异链烷烃烷基化第一段时间，然后是第二烯烃反应物，例如丙烯，用于在同一烷基化反应器中将异链烷烃烷基化第二段时间。在用第一烯属反应物烷基化异构烷烃的期间，将反应器流出物流连续分离成包含烷基化产物和未反应的异链烷烃和液体酸烷基化催化剂相的液体烃相。酸催化剂连续地再循环到反应器中，烃相通过到第一冲击区或储罐。在第二时间段内，将来自第一浪涌区和第二烯烃反应物的富含异构链烷烃的烃相以及连续循环的催化剂装入相同的烷基化反应器中，使得优选连续进料到反应器中。将反应器流出物连续分离成含有未反应的异链烷烃和液体催化剂相的液体烃相。烃相部分地进行分馏，部分地加入到第二浪涌区。在第一时间段内，将来自第二喘振区的碳氢化合物加入到该分馏中，使分馏继续运行。将异链烷烃从分馏物连续地除去至第三冲击区。可以将异链烷烃从第三缓冲区带入烷基化反应器。

9. 发明授权

US4161497A HF alkylation introducing separate olefins in vertically extended reactor 失效
标题翻译：在垂直延伸的反应器中引入单独的烯烃的HF烷基化
公开(公告)号：US4161497A
公开(公告)日：1979-07-17
申请号：US840424
申请日：1977-10-07
申请人： Donald J. Makovec , Thomas Hutson, Jr.
发明人： Donald J. Makovec , Thomas Hutson, Jr.
IPC分类号： C07C2/62 , C07C3/54
CPC分类号： C07C2/62 , C07C2527/1206
摘要： An improved HF alkylation process comprising, in series, HF and isoparaffin flow and parallel injection of at least two different olefins into a vertically extended reaction zone coupled with recycle of some of the alkylation hydrocarbon effluent to each point of olefin introduction into the alkylation zone. The improved alkylation system allows minimum sized fractionation and extremely high isoparaffin/olefin ratios with temperature control of the reaction at each olefin injection.
摘要翻译：一种改进的HF烷基化方法，其包括串联的HF和异链烷烃流，并且将至少两种不同的烯烃平行注入到垂直延伸的反应区中，与一些烷基化烃流出物循环到每个烯烃引入到烷基化区中。改进的烷基化系统允许在每种烯烃注入下温度控制反应的最小尺寸分馏和极高的异链烷烃/烯烃比例。

10. 发明授权

US5237115A Integrated olefin processing 失效
标题翻译：综合烯烃加工
公开(公告)号：US5237115A
公开(公告)日：1993-08-17
申请号：US899820
申请日：1992-06-16
申请人： Donald J. Makovec , Robert O. Dunn , Martyn E. Pfile , Gary R. Patton , Larry E. Lew
发明人： Donald J. Makovec , Robert O. Dunn , Martyn E. Pfile , Gary R. Patton , Larry E. Lew
IPC分类号： C10L1/02
CPC分类号： C10L1/023
摘要： A novel integrated olefin processing scheme is provided where olefins and paraffins are processed to produce high octane gasoline blending components. The integrated process involves the dehydrogenation of paraffin compounds to olefin compounds and the processing of olefins by hydroisomerization to produce hydroisomerate streams which are subsequently etherified. Those olefin compounds which are not etherified pass to an alkylation process where they are alkylated with branched chain paraffin compounds to produce an alkylate product.
摘要翻译：提供了一种新型的烯烃加工方案，其中加工烯烃和链烷烃以产生高辛烷值汽油调和组分。一体化方法包括将链烷烃化合物脱氢成烯烃化合物，并通过加氢异构化处理烯烃以产生随后醚化的加氢异构体物流。未醚化的那些烯烃化合物通过烷基化方法，其中它们用支链烷烃化合物烷基化以产生烷基化产物。

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