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1. 发明授权

US07220888B2 Method for producing hydrocarbons having a modified carbon skeleton 失效
标题翻译：具有改性碳骨架的烃的制造方法
公开(公告)号：US07220888B2
公开(公告)日：2007-05-22
申请号：US10451739
申请日：2002-01-05
申请人： Dominic Vanoppen , Ekkehard Schwab , Jean-Marie Basset , Jean Thivolle-Cazat , Mostapha Taoufik , Michael Schulz , Arthur Höhn
发明人： Dominic Vanoppen , Ekkehard Schwab , Jean-Marie Basset , Jean Thivolle-Cazat , Mostapha Taoufik , Michael Schulz , Arthur Höhn
IPC分类号： C07C6/08
CPC分类号： C07C6/10 , C07C6/08 , C07C2531/12
摘要： The invention relates to a method for producing hydrocarbons having a modified carbon skeleton by reacting aliphatic hydrocarbons a) with themselves, b) with another aliphatic hydrocarbon or c) with aromatic alkyl substituted hydrocarbons, in the presence of a metal organic catalyst or the hybrid thereof, at a temperature of between 20–400° C. and a pressure of between 0.2–100 bars, wherein the reaction takes place in the presence of hydrogen.
摘要翻译：本发明涉及一种生产具有改性碳骨架的碳氢化合物的方法，该方法通过使脂族烃a）与其自身反应，b）与另一种脂族烃或c）与芳族烷基取代的烃在金属有机催化剂或其混合物存在下反应在20-400℃的温度和0.2-100巴的压力之间，其中反应在氢的存在下进行。

2. 发明申请

US20070129584A1 Metallic compound fixed to a support, method for production and use of said compound in hydrocarbon metathesis reactions 审中-公开
标题翻译：固定在载体上的金属化合物，在烃复分解反应中生产和使用所述化合物的方法
公开(公告)号：US20070129584A1
公开(公告)日：2007-06-07
申请号：US10550628
申请日：2004-03-24
申请人： Jean-Marie Basset , Christophe Coperet , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Christophe Coperet , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： C07C2/02 , B01J23/00
CPC分类号： C07C6/10 , B01J31/121 , B01J37/0209 , B01J37/18 , C07C2521/04 , C07C2531/12 , C08L61/06
摘要： The invention relates to a supported metal compound, comprising a support made from aluminium oxide to which a tungsten hydride is grafted. The support may be selected from the homogeneous supports with a composition based on aluminum oxide and from heterogeneous supports made from aluminium oxide with aluminum oxide essentially on the surface of said support. The support may in particular comprise aluminium oxide, mixed aluminium oxides and modified aluminium oxides particularly comprising one or more elements of groups 15 to 17 of the periodic table of the elements, such as phosphorus, sulphur, fluorine or chlorine. A support made from porous, non-porous or mesoporous aluminas is preferred. The degree of oxidation of the tungsten may have a value of from 2 to 6. The tungsten atom is generally bonded to one or several hydrogen atoms and optionally to one or several hydrocarbon groups. According to the invention, the compound may be prepared by a dispersion step and grafting of a tungsten organometallic precursor to the support made from aluminium oxide then hydrogenation of the resulting product. The product may be used as catalyst in reactions of cleavage and recombination of hydrocarbons, particularly in hydrocarbon metathesis reactions most particularly of alkanes. The product has a surprising, extremely high catalytic activity in this type of reaction and in particular, a high selectivity for the formation of n-alkanes with relation to iso-alkanes.
摘要翻译：本发明涉及一种载体金属化合物，其包括由氧化铝制成的载体，钨载体与其接枝。载体可以选自具有基于氧化铝的组合物的均相载体和基本上在所述载体表面上由氧化铝与氧化铝制成的非均相载体。该载体可以特别包括氧化铝，混合的氧化铝和改性的氧化铝，特别包括元素周期表中第15至17族元素的一种或多种元素，如磷，硫，氟或氯。由多孔，无孔或中孔氧化铝制成的载体是优选的。钨的氧化度可以具有2至6的值。钨原子通常与一个或几个氢原子键合，任选地与一个或多个烃基键合。根据本发明，化合物可以通过分散步骤制备，并将钨有机金属前体接枝到由氧化铝制成的载体上，然后氢化所得产物。该产物可用作烃的裂解和重组反应的催化剂，特别是在烷烃中的烃复分解反应中。该产物在这种类型的反应中具有惊人的极高的催化活性，特别是与异烷烃相关的形成正烷烃的高选择性。

3. 发明申请

US20050014987A1 Process for manufacturing alkanes by reacting other alkanes with methane 失效
标题翻译：通过使其他烷烃与甲烷反应制备烷烃的方法
公开(公告)号：US20050014987A1
公开(公告)日：2005-01-20
申请号：US10502845
申请日：2003-01-22
申请人： Jean-Marie Basset , Christophe Coperet , Richard Pardy , Daravong Soulivong , John Sunley , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Christophe Coperet , Richard Pardy , Daravong Soulivong , John Sunley , Jean Thivolle-Cazat
IPC分类号： B01J21/08 , B01J31/12 , B01J37/02 , C07C6/10 , C07C6/08
CPC分类号： C07C6/10 , B01J21/08 , B01J31/121 , B01J37/0209 , C07C2531/12 , Y10S585/943
摘要： The present invention relates to a process for the manufacture of alkanes comprising a catalytic reaction resulting from contacting methane with at least one other starting alkane (I) in the presence of a metal compound (C) capable of catalysing a reaction for the splitting and/or recombination of a carbon-carbon bond and/or of a carbon-hydrogen bond and/or of a carbon-metal bond, which catalytic reaction results in the formation of at least one final alkane (II) having a number of carbon atoms equal to or greater than (2). In the process, the contacting operation is carried out under a methane partial pressure equal to or greater than 0.1 MPa, preferably in the range from 0.1 to 100 MPa. The metal compound (C) can be chosen from metal compounds supported on and dispersed over a solid support, metal compounds supported on and grafted to a solid support and non-supported metal compounds. Under these conditions, it was found that the yield of the catalytic reaction was improved, ant that the catalytic stability and activity of the metal compound (C) over timer were greatly enhanced.
摘要翻译：本发明涉及一种制备烷烃的方法，其包括由甲烷与至少一种其它起始烷烃（I）在能够催化分解和/或反应的反应的金属化合物（C）存在下使甲烷接触而产生的催化反应，或碳 - 碳键和/或碳 - 氢键和/或碳 - 金属键的重组，该催化反应导致至少一个具有多个碳原子的最终烷烃（II）的形成相等至（2）以上。在该过程中，接触操作在等于或大于0.1MPa，优选在0.1至100MPa范围内的甲烷分压下进行。金属化合物（C）可以选自负载在固体载体上并分散在固体载体上的金属化合物，负载在和接枝到固体载体上的金属化合物和非负载的金属化合物。在这些条件下，发现催化反应的产率提高，催化稳定性和金属化合物（C）与定时器的活性大大提高。

4. 发明授权

US06469225B1 Process for manufacturing alkanes 失效
标题翻译：制备烷烃的方法
公开(公告)号：US06469225B1
公开(公告)日：2002-10-22
申请号：US09663941
申请日：2000-09-18
申请人： Jean-Marie Basset , Christophe Coperet , Laurent Lefort , Barry Martin Maunders , Olivier Maury , Guillaume Saggio , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Christophe Coperet , Laurent Lefort , Barry Martin Maunders , Olivier Maury , Guillaume Saggio , Jean Thivolle-Cazat
IPC分类号： C07C608
CPC分类号： C07C1/325 , Y10S585/931 , C07C9/00
摘要： A process for the manufacture of alkanes comprising a cross-metathesis reaction between at least one starting alkane (A) and one organometallic compound (B) fixed to an inorganic support and comprising a metal bonded to at least one hydrocarbon-comprising radical. The reaction leads to the formation of at least one other alkane (C) which is a higher or lower homologue of the starting alkane (A), by cleavage of the hydrocarbon-comprising radical with the metal of the organometallic compound (B) and recombination of the radical with at least one other radical originating from a cleavage of the starting alkane (A). The metal of the compound (B) preferably is selected from transition metals, lanthanides and actinides, and the hydrocarbon-comprising radical of the compound (B) preferably is selected from alkyl, alkylidene and alkylidyne radicals.
摘要翻译：一种制备烷烃的方法，其包括至少一种起始烷烃（A）和一种固定到无机载体上的一种有机金属化合物（B）之间的交叉复分解反应，并包含与至少一种含烃基团结合的金属。该反应通过用有机金属化合物（B）的金属裂解含有烃的自由基和复合的方式，形成起始烷烃（A）的较高或较低同系物的至少一种其它烷烃（C）的基团与至少一种源自起始烷烃（A）的裂解的其它基团反应。化合物（B）的金属优选选自过渡金属，镧系元素和锕系元素，化合物（B）的含烃基团优选选自烷基，亚烷基和亚烷基。

5. 发明授权

US08119852B2 Process for manufacturing neohexene 失效
标题翻译：制备新己烯的方法
公开(公告)号：US08119852B2
公开(公告)日：2012-02-21
申请号：US12448216
申请日：2007-12-11
申请人： Jean Marie Basset , Francois Stoffelbach , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean Marie Basset , Francois Stoffelbach , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： C07C6/04
CPC分类号： C10L1/06 , B01J21/04 , B01J31/121 , B01J37/0209 , B01J2531/66 , C07C6/04 , C07C2521/04 , C07C2531/12 , C07C11/107
摘要： The present invention relates to a process for manufacturing neohexene, comprising contacting isobutene with a supported catalyst comprising a tungsten compound chosen from tungsten hydrides, organometallic tungsten compounds and organometallic tungsten hydrides, and a support comprising an oxide of aluminum, so as to form a reaction mixture comprising neohexene, and preferably separating neohexene from the reaction mixture, so as to isolate it. The contacting leads to the direct production of neohexene, in particular in a single (reaction) stage and with a high molar selectivity for neohexene. The contacting can be performed at a temperature of 50 to 600 ° C., under a total absolute pressure of 0.01 to 100 MPa.
摘要翻译：本发明涉及一种制备新己烯的方法，包括使异丁烯与包含选自氢化钨，有机金属钨化合物和有机金属氢化钨的钨化合物的负载催化剂和包含铝氧化物的载体接触，以形成反应包含新己烯的混合物，优选从反应混合物中分离新己烯，以便将其分离。接触导致新己烯的直接生产，特别是在单一（反应）阶段和对新己烯的高摩尔选择性。接触可以在50〜600℃的温度下，在0.01〜100MPa的绝对压力下进行。

6. 发明申请

US20100028735A1 PROCESS FOR CONVERTING METHANE INTO A HIGHER ALKANE MIXTURE 审中-公开
标题翻译：将甲烷转化为较高的烷烃混合物的方法
公开(公告)号：US20100028735A1
公开(公告)日：2010-02-04
申请号：US12448275
申请日：2007-12-18
申请人： Jean Marie Basset , Sudhakar Chakka , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean Marie Basset , Sudhakar Chakka , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： H01M8/04 , C07C2/76 , C01B3/02
CPC分类号： C07C6/10 , C07C2521/08 , C07C2531/12 , C07C9/10 , C07C9/14 , C07C9/08
摘要： The present invention relates to a process for converting methane into a higher alkane mixture, preferably a liquid alkane mixture, comprising (C3+) alkanes having 3 carbon atoms and more, preferably (C4+) alkanes having 4 carbon atoms, especially (C5+) alkanes having 5 carbon atoms and more. The process comprises:—a stage (1) comprising contacting methane with a metal catalyst (C1) capable of producing, in contact with alkane, reactions involving the splitting and recombining of C—C and/or C—H and/or C-metal bonds, so as to form by a non-oxidative methane coupling reaction a mixture (M1) comprising ethane and hydrogen,—preferably a stage (2) comprising fractionating the mixture (M1) so as to separate and to isolate the ethane, and—a stage (3) comprising, preferably simultaneously, (i) contacting the mixture (M1) or preferably the ethane isolated in stage (2) with a metal catalyst (C2) capable of producing, in contact with alkane, reactions involving the splitting and recombining of C—C and/or C—H and/or C-metal bonds, said catalyst being identical to or different from catalyst (C1), so as to form by simultaneous ethane self- and cross-metathesis reactions a mixture (M2) comprising methane and the higher alkane mixture, and (ii) fractionating the mixture (M2) so as to separate and to isolate said higher alkane mixture, preferably in liquid form, and particularly the methane which is preferably recycled into stage (1). The hydrogen produced in stage (1) is preferably separated and isolated in stage (2) and then used for various applications and stages, e.g. for producing thermal and/or electrical energies preferably employed to run the process.
摘要翻译：本发明涉及一种将甲烷转化成高级烷烃混合物，优选液态烷烃混合物的方法，该混合物包含具有3个碳原子的（C3 +）烷烃和更多（优选具有4个碳原子的（C4 +）烷烃），特别是（C5 +）烷烃，其具有 5个碳原子和更多。该方法包括：a阶段（1）包括使甲烷与能够与烷烃接触的金属催化剂（C1）接触涉及CC和/或CH和/或C - 金属键的分解和重组的反应，因此通过非氧化甲烷偶联反应形成包含乙烷和氢气的混合物（M1），优选地包括分级分离混合物（M1）以分离和分离乙烷的阶段（2）和阶段（ 3）优选同时包含（i）将阶段（2）中分离的混合物（M1）或优选乙烷与能够与烷烃接触的金属催化剂（C2）接触涉及CC的分解和重组的反应和/或CH和/或C - 金属键，所述催化剂与催化剂（C1）相同或不同，以便通过同时进行乙烷自身和交叉复分解反应形成包含甲烷和高级烷烃的混合物（M2）混合物，和（ii）分离混合物（M2）以分离并且优选分离所述高级烷烃混合物，优选液体形式，特别是优选循环到阶段（1）中的甲烷。在阶段（1）中产生的氢优选在阶段（2）中分离和分离，然后用于各种应用和阶段，例如，用于产生优选用于运行该过程的热能和/或电能。

7. 发明申请

US20080228020A1 Method for Converting Ethylene Into Propylene 失效
标题翻译：将乙烯转化成丙烯的方法
公开(公告)号：US20080228020A1
公开(公告)日：2008-09-18
申请号：US11571602
申请日：2005-06-27
申请人： Christophe Coperet , Jean-Marie Basset , Jean Thivolle-Cazat , Erwan Le Roux , Mostafa Taoufik
发明人： Christophe Coperet , Jean-Marie Basset , Jean Thivolle-Cazat , Erwan Le Roux , Mostafa Taoufik
IPC分类号： C07C2/02
CPC分类号： C07C6/04 , C07C2531/12 , Y02P20/584 , C07C11/06
摘要： The invention relates to a method for converting ethylene into propylene consisting in reacting said ethylene with a supported metal compound comprising an aluminium oxide based support to which a tungsten hydride is grafted. Said reaction is carried out at a temperature ranging from 20 to 600° C., preferably between 50 and 350° C., at an absolute pressure ranging from 0.01 to 8 MPa, preferably between 0.01 and 1 MPa. A catalyst is regeneratable by introducing hydrogen at a temperature of 50-300° C.
摘要翻译：本发明涉及一种将乙烯转化成丙烯的方法，该方法是使所述乙烯与负载型金属化合物反应，该金属化合物包含接枝有氢化钨的氧化铝基载体。所述反应在20〜600℃，优选50〜350℃的温度下进行，绝对压力为0.01〜8MPa，优选为0.01〜1MPa。催化剂可以通过在50-300℃的温度下引入氢气来再生

8. 发明申请

US20110071331A1 PROCESS FOR CONVERTING ETHANE INTO LIQUID ALKANE MIXTURES 审中-公开
标题翻译：将乙醇转化成液体醇混合物的方法
公开(公告)号：US20110071331A1
公开(公告)日：2011-03-24
申请号：US12451951
申请日：2008-06-10
申请人： Jean-Marie Basset , Sudhakar Chakka , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Sudhakar Chakka , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： C07C2/00
CPC分类号： C10L3/10 , B01J21/04 , B01J21/08 , B01J31/121 , B01J2531/58 , B01J2531/66 , C07C2/76 , C07C6/10 , C07C9/00 , C07C2521/04 , C07C2531/12 , C10G50/00 , C10G2300/1025 , C10G2300/703 , C07C9/06
摘要： The invention relates to a process for converting ethane into liquid mixture of (C4+) alkanes having 4 carbon atoms and more, preferably (C5+) alkanes having 5 carbon atoms and more. The process comprises a stage (1) comprising simultaneous ethane self- and cross-metathesis reactions carried out by contacting ethane with a metal catalyst (C1) capable of producing, in contact with alkane, reactions involving the splitting and recombining of C—C and/or C—H and/or C-metal bonds, so as to form a reaction mixture (MI) comprising methane and a mixture of the (C4+), preferably the (C5+) alkanes, a stage (2) comprising separating and isolating methane from the reaction mixture (MI), a stage (3) comprising a non-oxidative methane coupling reaction carried out by contacting the methane thus isolated with a metal catalyst (C2) capable of producing, in contact with alkane, reactions involving the splitting and recombining of C—C and/or C—H and/or C-metal bonds, said catalyst (C2) being identical to or different from the catalyst (C1), so as to form a mixture (M2) comprising ethane and hydrogen, optionally a stage (4) comprising separating and isolating ethane from the mixture (M2), a stage (5) comprising recycling the ethane thus isolated or the mixture (M2) into stage (1) for going on with the simultaneous ethane self- and cross-metathesis reactions and continuing forming said reaction mixture (MI), and a stage (6) comprising separating and isolating.
摘要翻译：本发明涉及一种将乙烷转化成具有4个碳原子的（C 4+）烷烃和更多的（C 5+）烷烃，具有5个碳原子和更多的（C 5+）烷烃的液体混合物的方法。该方法包括阶段（1），其包括同时进行的乙烷自交联和交叉复分解反应，其通过使乙烷与能够与烷烃接触的金属催化剂（C1）接触进行，所述反应涉及C-C的分解和重组以及 /或C-H和/或C - 金属键，以形成包含甲烷和（C4 +），优选（C5 +）烷烃的混合物的反应混合物（MI），包括分离和分离的级（2）来自反应混合物（MI）的甲烷，包含非氧化性甲烷偶联反应的阶段（3），其通过使如此分离的甲烷与能够与烷烃接触的金属催化剂（C2）接触涉及分裂的反应和C-C和/或C-H和/或C-金属键的重组，所述催化剂（C2）与催化剂（C1）相同或不同，从而形成包含乙烷和氢的混合物（M2），任选地包括从所述分离和分离乙烷的阶段（4）混合物（M2），阶段（5），其包括将如此分离的乙烷或混合物（M2）循环到阶段（1）中，以进行同时进行的乙烷自交联和交叉复分解反应并连续形成所述反应混合物（MI），以及包括分离和分离的阶段（6）。

9. 发明申请

US20100030003A1 PROCESS FOR MANUFACTURING NEOHEXENE 失效
标题翻译：制造NEOHEXENE的工艺
公开(公告)号：US20100030003A1
公开(公告)日：2010-02-04
申请号：US12448216
申请日：2007-12-11
申请人： Jean-Marie Basset , Francois Stoffelbach , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Francois Stoffelbach , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： C07C6/00
CPC分类号： C10L1/06 , B01J21/04 , B01J31/121 , B01J37/0209 , B01J2531/66 , C07C6/04 , C07C2521/04 , C07C2531/12 , C07C11/107
摘要： The present invention relates to a process for manufacturing neohexene, comprising contacting isobutene with a supported catalyst comprising a tungsten compound chosen from tungsten hydrides, organometallic tungsten compounds and organometallic tungsten hydrides, and a support comprising an oxide of aluminium, so as to form a reaction mixture comprising neohexene, and preferably separating neohexene from the reaction mixture, so as to isolate it. The contacting leads to the direct production of neohexene, in particular in a single (reaction) stage and with a high molar selectivity for neohexene. The contacting can be performed at a temperature of 50 to 600° C., under a total absolute pressure of 0.01 to 100 MPa.
摘要翻译：本发明涉及一种制备新己烯的方法，包括使异丁烯与包含选自氢化钨，有机金属钨化合物和有机金属氢化钨的钨化合物的负载催化剂和包含铝氧化物的载体接触，以形成反应包含新己烯的混合物，优选从反应混合物中分离新己烯，以便将其分离。接触导致新己烯的直接生产，特别是在单一（反应）阶段和对新己烯的高摩尔选择性。接触可以在50〜600℃的温度下，在0.01〜100MPa的绝对压力下进行。

10. 发明授权

US07378564B2 Process for manufacturing alkanes by reacting other alkanes with methane 失效
标题翻译：通过使其他烷烃与甲烷反应制备烷烃的方法
公开(公告)号：US07378564B2
公开(公告)日：2008-05-27
申请号：US10502845
申请日：2003-01-22
申请人： Jean-Marie Basset , Christophe Coperet , Richard Pardy , Daravong Soulivong , John Glenn Sunley , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Christophe Coperet , Richard Pardy , Daravong Soulivong , John Glenn Sunley , Jean Thivolle-Cazat
IPC分类号： C07C6/08
CPC分类号： C07C6/10 , B01J21/08 , B01J31/121 , B01J37/0209 , C07C2531/12 , Y10S585/943
摘要： The present invention relates to a process for the manufacture of alkanes comprising a catalytic reaction resulting from contacting methane with at least one other starting alkane (I) in the presence of a metal compound (C) capable of catalysing a reaction for the splitting and/or recombination of a carbon-carbon bond and/or of a carbon-hydrogen bond and/or of a carbon-metal bond, which catalytic reaction results in the formation of at least one final alkane (II) having a number of carbon atoms equal to or greater than (2). In the process, the contacting operation is carried out under a methane partial pressure equal to or greater than 0.1 MPa, preferably in the range from 0.1 to 100 MPa. The metal compound (C) can be chosen from metal compounds supported on and dispersed over a solid support, metal compounds supported on and grafted to a solid support and non-supported metal compounds. Under these conditions, it was found that the yield of the catalytic reaction was improved, and that the catalytic stability and activity of the metal compound (C) over timer were greatly enhanced.
摘要翻译：本发明涉及一种制备烷烃的方法，其包括由甲烷与至少一种其它起始烷烃（I）在能够催化分解和/或反应的反应的金属化合物（C）存在下使甲烷接触而产生的催化反应，或碳 - 碳键和/或碳 - 氢键和/或碳 - 金属键的重组，该催化反应导致至少一个具有多个碳原子的最终烷烃（II）的形成相等至（2）以上。在该过程中，接触操作在等于或大于0.1MPa，优选在0.1至100MPa范围内的甲烷分压下进行。金属化合物（C）可以选自负载在固体载体上并分散在固体载体上的金属化合物，负载在和接枝到固体载体上的金属化合物和非负载的金属化合物。在这些条件下，发现催化反应的产率提高，金属化合物（C）超过定时器的催化稳定性和活性大大提高。

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