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    • 8. 发明授权
    • Process for preparing urethane-containing (meth)acrylic esters
    • 制备含氨基甲酸酯(甲基)丙烯酸酯的方法
    • US08399225B2
    • 2013-03-19
    • US12776670
    • 2010-05-10
    • Rainer StürmerDejana DrewBernhard HauerJürgen DäuwelUwe Meisenburg
    • Rainer StürmerDejana DrewBernhard HauerJürgen DäuwelUwe Meisenburg
    • C12P7/60
    • C12P13/02C12P7/62
    • The invention relates to a process for preparing urethane-containing acrylic- and (meth)acrylic esters by reacting a urethane-containing alcohol with a reactant acrylic- or (meth)acrylic ester of a saturated alcohol in the presence of at least one polymerization inhibitor and an enzyme as a catalyst within a reactor, wherein the saturated alcohol released in the process and optionally an entraining agent form an azeotrope with an excess of the reactant (meth)acrylic ester, such that the azeotrope is removed by distillation under reduced pressure and at least one substream from the bottom of the reactor is circulated through the top of the distillation column. Using this process, urethane-containing acrylic- and (meth)acrylic esters are prepared in high yields and high purities under mild conditions from economically obtainable reactants with no significant polymer formation.
    • 本发明涉及通过使含氨基甲酸酯的醇与饱和醇的反应性丙烯酸或(甲基)丙烯酸酯在至少一种聚合抑制剂的存在下反应来制备含氨基甲酸酯的丙烯酸和(甲基)丙烯酸酯的方法 和作为反应器内的催化剂的酶,其中在该方法中释放的饱和醇和任选的夹带剂与过量的反应物(甲基)丙烯酸酯形成共沸物,使得通过减压蒸馏除去共沸物, 来自反应器底部的至少一个子流通过蒸馏塔的顶部循环。 使用该方法,在温和条件下从经济可获得的反应物中以高产率和高纯度制备含氨基甲酸酯的丙烯酸酯和(甲基)丙烯酸酯,没有显着的聚合物形成。