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    • 2. 发明授权
    • Process for the manufacture of crystalline, crosslinked, elastomeric
epoxide resins
    • 制备结晶,交联,弹性体环氧树脂的方法
    • US4101476A
    • 1978-07-18
    • US828441
    • 1977-08-29
    • Rolf SchmidUrsula Kreibich
    • Rolf SchmidUrsula Kreibich
    • C08L63/00F24J2/48C08L91/00
    • F24J2/482C08L63/00Y02E10/40
    • The invention relates to the manufacture of crystalline epoxide resins which exhibit a marked crystallite melt temperature. The formation of the crystallites is caused by molecule blocks which are derived from polyester-polycarboxylic acids, which contain aliphatic radicals in the chain. According to the invention, two aliphatic polyester-polycarboxylic acids (A and B) are reacted under very specific quantitative conditions with epoxide compounds which contain at least 2 epoxide groups and optionally with curing agents. The polyester-polycarboxylic acids A are purely n-aliphatic in character, whereas the polyester-polycarboxylic acids B are not. They contain radicals which are derived from dimerized mono- unsaturated or di- unsaturated fatty acids during the ester formation. These crystalline synthetic resins are particularly suitable for use as material for absorbing solar energy in solar energy collectors.
    • 本发明涉及显示出明显的微晶熔融温度的结晶环氧树脂的制造。 微晶的形成是由衍生自在链中含有脂族基团的聚酯多元羧酸的分子嵌段引起的。 根据本发明,两种脂族聚酯多元羧酸(A和B)在非常特定的定量条件下与含有至少2个环氧基团和任选地与固化剂的环氧化合物反应。 聚酯多元羧酸A的性质纯粹是正脂族的,而聚酯多元羧酸B不是。 它们含有在酯形成期间衍生自二聚单不饱和或不饱和脂肪酸的基团。 这些结晶合成树脂特别适用于太阳能收集器中吸收太阳能的材料。
    • 4. 发明授权
    • Process for the manufacture of crystalline, crosslinked epoxide resins
    • 制备结晶交联环氧树脂的方法
    • US4181643A
    • 1980-01-01
    • US896276
    • 1978-04-14
    • Ursula KreibichRolf Schmid
    • Ursula KreibichRolf Schmid
    • C08L63/00C08L63/06
    • C08L63/00Y10T428/31518
    • The invention relates to the manufacture of crystalline epoxide resins which have at least two crystallite melt temperatures. The cause of the crystallites are molecule blocks which are derived from aliphatic polyesterpolycarboxylic acids. According to the invention, at least two aliphatic polyester-polycarboxylic acids (D and E), which bear a special relation to each other in respect of the number of --CH.sub.2 groups in the primary chain member, are reacted under very specific quantitative conditions with epoxide compounds which contain at least 2 epoxide groups and optionally with curing agents. The synthetic resins thereby obtained are particularly suitable for use as storage material in latent heat accumulators.
    • 本发明涉及具有至少两个微晶熔融温度的结晶环氧树脂的制造。 微晶的原因是衍生自脂族聚酯多羧酸的分子嵌段。 根据本发明,在非常特定的定量条件下,在非常特定的定量条件下使至少两种与第一链构件中的-CH 2基团数相互特别关系的脂族聚酯多元羧酸(D和E)与 含有至少2个环氧基团和任选地与固化剂的环氧化合物。 由此得到的合成树脂特别适合用作潜热蓄热器中的储存材料。
    • 6. 发明授权
    • Process for the manufacture of crystalline, crosslinked, elastomeric
epoxide resins
    • 制备结晶,交联,弹性体环氧树脂的方法
    • US4180527A
    • 1979-12-25
    • US828442
    • 1977-08-29
    • Rolf SchmidUrsula Kreibich
    • Rolf SchmidUrsula Kreibich
    • C08G59/42C08L63/00F24J2/48
    • F24J2/482C08G59/4246C08L63/00Y02E10/40Y10S126/908
    • The invention relates to the manufacture of crystalline epoxide resins which exhibit a marked crystallite melt temperature. The formation of the crystallites is caused by molecule blocks which are derived from aliphatic polyester-polycarboxylic acids. According to the invention, two aliphatic polyester-polycarboxylic acids (A and B) are reacted under very specific quantitative conditions with epoxide compounds which contain at least 2 epoxide groups and optionally with curing agents. The polyester-polycarboxylic acids A are purely n-aliphatic in character, whereas the polyester-polycarboxylic acids B are not. They contain, for example, neopentyl radicals which are derived from neopentyl alcohol during the ester formation. These crystalline synthetic resins are particularly suitable for use as material for absorbing solar energy in solar energy collectors.
    • 本发明涉及显示出明显的微晶熔融温度的结晶环氧树脂的制造。 微晶的形成是由衍生自脂肪族聚酯 - 多元羧酸的分子嵌段引起的。 根据本发明,两种脂族聚酯多元羧酸(A和B)在非常特定的定量条件下与含有至少2个环氧基团和任选地与固化剂的环氧化合物反应。 聚酯多元羧酸A的性质纯粹是正脂族的,而聚酯多元羧酸B不是。 它们含有例如在酯形成期间衍生自新戊基醇的新戊基。 这些结晶合成树脂特别适用于太阳能收集器中吸收太阳能的材料。