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    • 3. 发明授权
    • Copolycondensation polymerization of fluoropolymers
    • 含氟聚合物的共聚缩聚
    • US08247614B2
    • 2012-08-21
    • US12486378
    • 2009-06-17
    • Ming-Hong HungBruno AmeduriBernard BoutevinAurelien Soules
    • Ming-Hong HungBruno AmeduriBernard BoutevinAurelien Soules
    • C08G63/44C08G73/00
    • C08G73/08C08F8/30C08F214/222C08F2800/10C08F2810/40C08F8/00
    • Fluorinated copolymers are prepared via copolycondensation polymerization in a process comprising reacting A) a telechelic fluoroazido compound of formula N3(Y)p—(CH2)n—R—(CH2)m—(Y)pN3, wherein Y is SO, SO2, C6H4, or CO, p=0 or 1, n and m are independently 1 to 4, and R is selected from the group consisting of i) a C3-C10 fluoroalkylene group, ii) a C3-C10 fluoroalkoxylene group, iii) a substituted aryl group, iv) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), v) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, vi) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and vii) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin with B) a telechelic diyne or dinitrile compound in the presence of copper halide catalyst.
    • 氟化共聚物是通过共聚缩聚反应制备的,该方法包括使A)一种式N 3(Y)p-(CH 2)n -R-(CH 2)m - (Y)pN 3的遥爪氟代叠氮化物,其中Y是SO,SO 2, C 6 H 4或CO,p = 0或1,n和m独立地为1至4,R选自i)C 3 -C 10氟亚烷基,ii)C 3 -C 10氟代亚烷基,iii) 取代的芳基,iv)包含偏二氟乙烯和全氟(甲基乙烯基醚)的共聚单元的低聚物,v)包含偏二氟乙烯和六氟丙烯的共聚单元的低聚物,vi)包含四氟乙烯和全氟(甲基乙烯基醚)共聚单元的低聚物 )和vii)包含四氟乙烯和烃烯烃的共聚单元的低聚物,B)在二卤化铜催化剂存在下的遥爪二炔或二腈化合物。
    • 5. 发明申请
    • COPOLYCONDENSATION POLYMERIZATION OF FLUOROPOLYMERS
    • 氟聚合物共聚聚合
    • US20100324234A1
    • 2010-12-23
    • US12486378
    • 2009-06-17
    • MING-HONG HUNGBruno AmeduriBernard BoutevinAurelien Soules
    • MING-HONG HUNGBruno AmeduriBernard BoutevinAurelien Soules
    • C08F4/10
    • C08G73/08C08F8/30C08F214/222C08F2800/10C08F2810/40C08F8/00
    • Fluorinated copolymers are prepared via copolycondensation polymerization in a process comprising reacting A) a telechelic fluoroazido compound of formula N3(Y)p—(CH2)n—R—(CH2)m—(Y)pN3, wherein Y is SO, SO2, C6H4, or CO, p=0 or 1, n and m are independently 1 to 4, and R is selected from the group consisting of i) a C3-C10 fluoroalkylene group, ii) a C3-C10 fluoroalkoxylene group, iii) a substituted aryl group, iv) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), v) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, vi) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and vii) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin with B) a telechelic diyne or dinitrile compound in the presence of copper halide catalyst.
    • 氟化共聚物是通过共聚缩聚反应制备的,该方法包括使A)一种式N 3(Y)p-(CH 2)n -R-(CH 2)m - (Y)pN 3的遥爪氟代叠氮化物,其中Y是SO,SO 2, C 6 H 4或CO,p = 0或1,n和m独立地为1至4,R选自i)C 3 -C 10氟亚烷基,ii)C 3 -C 10氟代亚烷基,iii) 取代的芳基,iv)包含偏二氟乙烯和全氟(甲基乙烯基醚)的共聚单元的低聚物,v)包含偏二氟乙烯和六氟丙烯的共聚单元的低聚物,vi)包含四氟乙烯和全氟(甲基乙烯基醚)共聚单元的低聚物 )和vii)包含四氟乙烯和烃烯烃的共聚单元的低聚物,B)在二卤化铜催化剂存在下的遥爪二炔或二腈化合物。